Heterocyclic compound and composition containing same

ABSTRACT

A heterocyclic compound is represented by formula (I): 
     
       
         
         
             
             
         
       
     
     in which R 2  represents a C1-C6 alkyl group optionally having one or more halogen atoms, n is 0, R 3  represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group B, q is 0, Het represents a group represented by the formulae Het 1 or Het 2, A 1  represents a nitrogen atom, and Q 2  represents an oxygen atom. The compound has excellent efficacy for controlling harmful arthropods. A composition is provided which contains the compound of formula (I) and one or more additional ingredients.

TECHNICAL FIELD

This application claims priority to and the benefit of Japanese Patent Application Nos. 2017-108998 filed Jun. 1, 2017, 2017-245956 filed Dec. 22, 2017, and 2018-70879 filed Apr. 2, 2018, the entire contents of which are incorporated herein by reference.

The present invention is related to a certain class of heterocyclic compound, an intermediate compound thereof, and an agent for controlling harmful arthropods comprising the same.

BACKGROUND ART

To date, in order to control harmful arthropods, some compounds have been studied and come into practical use.

Also, a certain class of compound has been known to have an effect on controlling pests (see Patent Document 1).

CITATION LIST Patent Document

Patent Document 1: WO 2013/018928 pamphlet

SUMMARY OF THE INVENTION Problems to be Solved by Invention

An object of the present invention is to provide a compound having an excellent efficacy for controlling harmful arthropods.

Means to Solve Problems

The present invention includes the followings.

[1] A compound represented by formula (I):

wherein,

R² represents a C1-C6 alkyl group optionally having one or more halogen atoms, a cyclopropyl group or a cyclopropylmethyl group,

n is 0, 1 or 2,

R³ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group B, a C3-C7 cycloalkyl group optionally having one or more substituents selected from group E, a C3-C7 cycloalkenyl group optionally having one or more substituents selected from Group J, a phenyl group optionally having one or more substituents selected from Group H, a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group H, OR¹², NR¹¹R¹², NR^(11a)R^(12a), NR²⁴NR¹¹R¹², NR²⁴OR¹¹, NR¹¹C(O)R¹³, NR²⁴NR¹¹C(O)R¹³, NR¹¹C(O)OR¹⁴, NR²⁴NR¹¹C(O)OR¹⁴, NR¹¹C(O)NR¹⁵R¹⁶, NR²⁴NR¹¹C(O) NR¹⁵R¹⁶, N═CHNR¹⁵R¹⁶, N═S(O)_(x)R¹⁵R¹⁶ , C(O)R¹⁷, C(O)OR¹⁷, C(O)NR¹⁵R¹⁶, CR²⁴═NOR¹⁷, NR¹¹CR²⁴═NOR¹⁷, a cyano group, a nitro group, or a halogen atom,

q is 0, 1, 2 or 3, and when q is 2 or 3, a plurality of R³ may be identical to or different from each other,

When two R³ are adjacent to each other, said two R³ may combined together with a carbon atom to which they are attached to form benzene ring, pyrrole ring, furan ring, thiophene ring, pyrazole ring, imidazole ring, triazole ring, oxazole ring, isoxazole ring, thiazole ring, oxadiazole ring, thiadiazole ring, pyridine ring, pyridazine ring, pyrimidine ring, or pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the triazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring, and the pyrazine ring each independently may optionally have one or more substituents selected from Group H},

Het represents a group represented by the following formula Het 1 or a group represented by the following formula Het 2:

A¹ represents a nitrogen atom or CR⁶,

A² represents a nitrogen atom or CR^(4a),

A³ represents a nitrogen atom or CR^(4b),

A⁴ represents a nitrogen atom or CR^(4c),

Q¹ represents an oxygen atom or a sulfur atom,

Q² represents an oxygen atom, N—CN, N—NO₂, NR²⁰, N—C(O)R²⁰ , or N—C(O)OR¹⁵, and when n is 2, two Q² may be identical to or different from each other,

R²⁰ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a hydrogen atom,

R⁵ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from group F, a C3-C6 cycloalkyl group optionally having one or more substituents selected from Group J, a phenyl group optionally having one or more substituents selected from Group H, or a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group H,

R^(4a), R^(4b) and R^(4c) are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a nitro group, OR¹⁸, NR¹⁸R¹⁹, a cyano group, an amino group, a halogen atom, or a hydrogen atom,

R⁶ represents a hydrogen atom or a halogen atom,

T represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C1-C5 alkylsulfanyl)C2-C5 alkyl group, the (C1-C5 alkylsulfinyl)C2-C5 alkyl group, and the (C1-C5 alkylsulfonyl)C2-C5 alkyl group each independently have one or more substituents selected from the group consisting of a cyano group and a halogen atom}, a (C3-C7 cycloalkyl)C1-C3 alkyl group, a C3-C7 cycloalkyl group {the (C3-C7 cycloalkyl)C1-C3 alkyl group and the C3-C7 cycloalkyl group each independently have one or more substituents selected from the group consisting of a cyano group, a halogen atom and a C1-C6 haloalkyl group}, OR¹, S(O)_(v)R¹, OS(O)₂R¹, CH₂OR¹, NR¹R²⁹, C(O)R¹, C(O)NR¹R²⁹, NR²⁹C(O)R¹, N═CR¹R³⁰, a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, a group represented by formula T-8, a group represented by formula T-9, a group represented by formula T-10, a group represented by formula T-11, or a group represented by formula T-12:

X¹ represents a nitrogen atom or CR^(1a),

X² represents a nitrogen atom or CR^(1b),

X³ represents a nitrogen atom or CR^(1c),

X⁴ represents a nitrogen atom or CR^(1d),

X⁵ represents a nitrogen atom or CR^(1e),

R^(1x) represents a C1-C5 chain hydrocarbon group having one or more halogen atoms, OR⁷, OS(O)₂R⁷, S(O)_(m)R⁷, NR⁸S(O)₂R⁷, or a halogen atom,

R^(1a), R^(1b), R^(1c), R^(1d), and R^(1e) are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a halogen atom, or a hydrogen atom,

Y² represents NR²⁵, an oxygen atom or a sulfur atom,

Y² represents a nitrogen atom or CR²⁶,

Y³ represents a nitrogen atom or CR²⁷,

Y⁴ represents a nitrogen atom or CR²⁸,

R²⁵, R²⁶, R²⁷ and R²⁸ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a halogen atom or a hydrogen atom,

R^(1y) represents a C1-C5 chain hydrocarbon group having one or more halogen atoms, OR⁷, OS(O)₂R⁷, S(O)_(m)R⁷, NR⁸S(O)₂R⁷, a cyano group, or a halogen atom,

R^(1ay) and R⁷ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group having one or more halogen atoms,

m and v are identical to or different from each other and each is 0, 1 or 2,

R¹ represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C1-C5 alkylsulfanyl)C2-C5 alkyl group, the (C1-C5 alkylsulfinyl)C2-C5 alkyl group, and the (C1-C5 alkylsulfonyl)C2-C5 alkyl group each independently have one or more substituents selected from the group consisting of a cyano group and a halogen atom}, a (C3-C7 cycloalkyl)C1-C3 alkyl group, or a C3-C7 cycloalkyl group {the (C3-C7 cycloalkyl)C1-C3 alkyl group and the C3-C7 cycloalkyl group each independently have one or more substituents selected from the group consisting of a cyano group, a halogen atom and a C1-C6 haloalkyl group},

R³⁰ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a halogen atom, OR³⁵, NR³⁶R³⁷, or a hydrogen atom,

R¹⁸ and R³⁵ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms,

R¹⁷ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a phenyl group optionally having one or more substituents selected from Group D, or a hydrogen atom,

R⁸, R¹¹, R¹⁹, R²⁴, R²⁹, R³⁶, and R³⁷ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a hydrogen atom,

R¹² represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally having one or more substituents selected from. Group J, a C3-C7 cycloalkenyl group optionally having one or more substituents selected from Group J, a phenyl group, a six membered heterocyclic group {the phenyl group, and the six membered heterocyclic group each independently may optionally have one or more substituents selected from Group D}, a hydrogen atom, or a S(O)₂R²³,

R²³ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a phenyl group optionally having one or more substituents selected from Group D,

R^(11a) and R^(12a) combine together with the nitrogen atom to which they are attached to form a three to seven membered nonaromatic heterocyclic group optionally having one or more substituents selected from group E,

R¹³ represents a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally having one or more halogen atoms, a phenyl group optionally having one or more substituents selected from Group D, or a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group D,

R¹⁴ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally having one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may optionally have one or more substituents selected from Group D},

R¹⁵ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a hydrogen atom,

R¹⁶ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally having one or more substituents selected from Group J, S(O)₂R²³ or a hydrogen atom,

x is 0 or 1,

Group B: a group consisting of a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom,

Group D: a group consisting of a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, an amino group, NR⁹R¹⁰, C(O)R¹⁰, OC(O)R⁹, C(O)OR⁹, a cyano group, a nitro group, and a halogen atom,

R⁹ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a C3-C6 cycloalkyl group optionally having one or more halogen atoms,

R¹⁰ represents a C1-C6 alkyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, or a hydrogen atom,

Group E; a group consisting of a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group;

Group F: a group consisting of a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a phenyl group or a six membered aromatic heterocyclic group {the phenyl group and the six membered aromatic heterocyclic group each independently may optionally have one or more substituents selected from Group D}, OR¹⁰, an amino group, NR⁹R¹⁰, a halogen atom, a nitro group, and a cyano group;

Group H: a group consisting of a five or six membered aromatic heterocyclic group, a C1-C6 alkyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, OR¹⁰, an amino group, NR⁹R¹⁰, C(O)R¹⁰, C(O)NR⁹R¹⁰, OC(O)R⁹, OC(O)OR⁹ , NR¹⁰C(O)R⁹, NR¹⁰C(O)OR⁹, C(O)OR¹⁰, a halogen atom, a nitro group, and a cyano group;

Group J; a group consisting of a C1-C6 alkyl group optionally having one or more halogen atoms, a halogen atom, a cyano group, a triazolyl group, and NR¹⁰C(O)R⁹. (hereinafter, referred to as “Present compound Z” or “Compound Z of the present invention”).

-   [2] The compound according to [1] wherein

T represents a C1-C10 chain hydrocarbon group having one or more halogen atoms, a (C1-C5 alkoxy)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group having one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C3 alkyl group having one or more substituents selected from Group G, a C3-C7 cycloalkyl group having one or more substituents selected from Group G, OR¹, S(O)_(v)R¹, OS(O)₂R¹, CH₂OR¹, NR¹R²⁹, C(O)R¹, C(O)NR¹R²⁹, NR²⁹C(O)R¹, N═CR¹R³⁰, a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, a group represented by formula T-8, a group represented by formula T-9, a group represented by formula T-10, a group represented by formula T-11, or a group represented by formula T-12, and

R¹ represents a C1-C10 chain hydrocarbon group having one or more halogen atoms, a (C1-C5 alkoxy)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group having one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C3 alkyl group having one or more substituents selected from Group G, or a C3-C7 cycloalkyl group having one or more substituents selected from Group G.

-   (hereinafter, referred to as “Present compound” or “Compound of the     present invention”). -   [3] The compound according to [1] or [2] wherein A¹ represents CH. -   [4] The compound according to [1] or [2] wherein A¹ represents a     nitrogen atom. -   [5] The compound according to any one of [1] to [4] wherein Het     represents Het 1. -   [6] The compound according to any one of [1] to [4] wherein Het     represents Het 2. -   [7] The compound according to any one of [1] to [4] wherein Het     represents Het 1, A² represents CR^(4a), and A³ represents CR^(4b). -   [8] The compound according to any one of [1] to [4] wherein Het     represents Het 2, A² represents CR^(4a), and A⁴ represents CR^(4c). -   [9] The compound according to any one of [1] to [8] wherein Q¹     represents an oxygen atom, T represents a C1-C10 chain hydrocarbon     group having one or more halogen atoms, OR¹, S(O)_(v)R¹, OS(O)₂R¹,     NR¹R²⁹, a group represented by formula T-1, a group represented by     formula T-2, a group represented by formula T-3, a group represented     by formula T-4, or a group represented by formula T-8. -   [10] The compound according to any one of [1] to [8] wherein Q¹     represents an oxygen atom, T represents a C1-C5 chain hydrocarbon     group having one or more halogen atoms, OR¹, S(O)_(v)R¹, OS(O)₂R¹,     NR¹R²⁹, a group represented by formula T-1, a group represented by     formula T-2, a group represented by formula T-3, a group represented     by formula T-4, or a group represented by formula T-8, R¹, R^(1x)and     R^(1y) are identical to or different from each other and each     represents independently a C1-C5 chain hydrocarbon group having one     or more halogen atoms, and q is 0 or 1. -   [11] The compound according to any one of [1] to [8] wherein Q¹     represents an oxygen atom, T represents a C1-C5 chain hydrocarbon     group having one or more halogen atoms, or OR¹, R¹ represents a     C1-C5 chain hydrocarbon group having one or more halogen atoms, and     q is 0 or 1. -   [12] The compound according to any one of [1] to [11] wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a five aromatic heterocyclic group containing one to     four nitrogen atoms, a six aromatic heterocyclic group {the phenyl     group, the five aromatic heterocyclic group containing one to four     nitrogen atoms, and the six aromatic heterocyclic group each     independently may optionally have one or more substituents selected     from Group J}, NR¹¹R¹², NR¹¹C(O)OR¹⁴, OR¹², or a halogen atom. -   [13] The compound according to any one of [1] to [12] wherein R²     represents an ethyl group. -   [14] The compound according to any one of [1] to [13] wherein Q²     represents an oxygen atom. -   [15] A composition for controlling harmful arthropod comprising the     compound according to any one of [1] to [14] and an inert carrier. -   [16] A method for controlling harmful arthropod which comprises     applying an effective amount of the compound according to any one of     [1] to [14] to a harmful arthropod or a habitat where a harmful     arthropod lives. -   [17] A method for controlling harmful arthropod which comprises     applying an effective amount of the compound according to any one of     [1] to [14] to a plant or a soil where a plant grows. -   [18] A method for controlling harmful arthropod which comprises     applying an effective amount of the compound according to any one of     [1] to [14] to a seed or a bulb. -   [19] A composition comprising one or more ingredients selected from     the group consisting of the following Group (a), Group (b), Group     (c), Group (d) and Group (e), and the compound according to any one     of [1] to [14] (hereinafter, referred to as “Present composition” or     “Composition of the present invention”),

Group (a): one or more ingredients selected from the group consisting of insecticidal ingredients, miticidal ingredients, and nematicidal ingredients;

Group (b): fungicidal ingredients;

Group (c): plant growth modulating ingredients;

Group (d): phytotoxicity-reducing ingredients; and

Group (e): synergist ingredients.

-   [20] A composition for controlling pest comprising the composition     according to [19] and an inert carrier. -   [21] A method for controlling pest which comprises applying an     effective amount of the composition according to [19] to a pest or a     habitat where a pest lives. -   [22] A method for controlling pest which comprises applying an     effective amount of the composition according to [19] to a plant or     a soil where a plant grows. [23] A method for controlling pest which     comprises applying an effective amount of the compound according to     [19] to a seed or a bulb. -   [24] A seed or bulb carrying an effective amount of the compound     according to any one of [1] to [14] or an effective amount of the     composition according to [19]. -   [25] A compound represented by formula (II):

[wherein,

R² represents a C1-C6 alkyl group optionally having one or more halogen atoms, a cyclopropyl group or a cyclopropylmethyl group,

n is 0, 1 or 2,

A² represents a nitrogen atom or CR^(4a),

a combination of A³ and A⁴ represents a combination where A³ represents a nitrogen atom, A⁴ represents a nitrogen atom or CR^(4c), or a combination where A³ represents CR^(4b), and A⁴ represents a nitrogen atom,

R^(4a), R^(4b) and R^(4c) are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a nitro group, OR¹⁸, NR¹⁸R¹⁹, a cyano group, an amino group, a halogen atom, or a hydrogen atom,

R¹⁹ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a hydrogen atom,

R^(w) represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a benzyl group optionally having one or more substituents selected from Group A, a C2-C7 alkylcarbonyl group, a (C1-C3 alkoxy)methyl group, or a hydrogen atom,

T^(w) represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C1-C5 alkylsulfanyl)C2-C5 alkyl group, the (C1-C5 alkylsulfinyl)C2-C5 alkyl group, and the (C1-C5 alkylsulfonyl)C2-C5 alkyl group each independently have one or more substituents selected from the group consisting of a cyano group and a halogen atom}, a (C3-C7 cycloalkyl)C1-C3 alkyl group or a C3-C7 cycloalkyl group {the (C3-C7 cycloalkyl)C1-C3 alkyl group and the C3-C7 cycloalkyl group each independently have one or more substituents selected from the group consisting of a cyano group, a halogen atom and a C1-C6 haloalkyl group}, OR¹, S(O)_(v)R¹, OS(O)₂R¹, CH2OR¹, NR¹R²⁹, C(O)R¹, C(O)NR¹R²⁹, NR²⁹C(O)R¹, N═CR¹R³⁰, a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, a group represented by formula T-8, a group represented by formula T-9, a group represented by formula T-10, a group represented by formula T-11, or a group represented by formula T-12, a halogen atom, a C1-C6 alkylsulfanyl group, a C1-C6 alkylsulfinyl group, a C1-C6 alkylsulfonyl group {the C1-C6 alkylsulfanyl group, the C1-C6 alkylsulfinyl group, and the C1-C6 alkylsulfonyl group each may optionally have a C3-C6 cycloalkyl group}, a C3-C6 cycloalkylsulfanyl group, a C3-C6 cycloalkylsulfinyl group, a C3-C6 cycloalkylsulfonyl group, a benzyloxy group optionally having one or more substituents selected from Group A, a C2-C7 alkylcarbonyloxy group optionally having one or more halogen atoms, a (C1-C3 alkoxy)methoxy group, or a hydroxy group,

X¹ represents a nitrogen atom or CR^(1a),

X² represents a nitrogen atom or CR^(1b),

X³ represents a nitrogen atom or CR^(1c),

X⁴ represents a nitrogen atom or CR^(1d),

X⁵ represents a nitrogen atom or CR^(1e),

R^(1x) represents a C1-C5 chain hydrocarbon group having one or more halogen atoms, OR⁷, OS(O)₂R⁷, S(O)_(m)R⁷, NR⁸S(O)₂R⁷, or a halogen atom,

R^(1a), R^(1b), R^(1c), R^(1d), and R^(1e) are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a halogen atom, or a hydrogen atom,

Y¹ represents NR²⁵, an oxygen atom or a sulfur atom,

Y² represents a nitrogen atom or CR²⁶,

Y³ represents a nitrogen atom or CR²⁷,

Y⁴ represents a nitrogen atom or CR²⁸,

R²⁵, R²⁶, R²⁷ and R²⁹ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a halogen atom or a hydrogen atom,

R^(1y) represents a C1-C5 chain hydrocarbon group having one or more halogen atoms, OR⁷, OS(O)₂R⁷, S(O)_(m)R⁷, NR⁸S(O)₂R⁷, a cyano group, or a halogen atoms,

R^(1ay) and R⁷ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group having one or more halogen atoms,

m and v are identical to or different from each other and each is 0, 1 or 2,

R¹ represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C1-C5 alkylsulfanyl)C2-C5 alkyl group, the (C1-C5 alkylsulfinyl)C2-C5 alkyl group, and the (C1-C5 alkylsulfonyl)C2-C5 alkyl group each independently have one or more substituents selected from the group consisting of a cyano group and a halogen atom}, a (C3-C7 cycloalkyl)C1-C3 alkyl group, or a C3-C7 cycloalkyl group {the (C3-C7 cycloalkyl)C1-C3 alkyl group and the C3-C7 cycloalkyl group each independently have one or more substituents selected from the group consisting of a cyano group, a halogen atom and a C1-C6 haloalkyl group},

R³⁰ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a halogen atom, OR³⁵, NR³⁵R³⁷, or a hydrogen atom,

R¹⁸ and R³⁵ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms,

R⁸, R²⁹, R³⁶, and R³⁷ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a hydrogen atom,

Group A: a group consisting of a C1-C6 alkyl group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, a halogen atom, a cyano group and a nitro group.]

-   (hereinafter, referred to as “Intermediate compound D”). -   [26] A compound represented by formula (III):

[wherein,

R² represents a C1-C6 alkyl group optionally having one or more halogen atoms, a cyclopropyl group or a cyclopropylmethyl group,

n is 0, 1 or 2,

A¹ represents a nitrogen atom or CR⁶,

A² represents a nitrogen atom or CR^(4a),

a combination of A³ and A⁴ represents a combination where A³ represents a nitrogen atom, A⁴ represents a nitrogen atom or CR^(4c), or a combination where A³ represents CR^(4b), and A⁴ represents a nitrogen atom,

R^(4a), R^(4b) and R^(4c) are identical to or different from each other and each represents independently a C1-C6, chain hydrocarbon group optionally having one or more halogen atoms, a nitro group, OR¹⁸, NR¹⁸R¹⁹, a cyano group, an amino group, a halogen atom, or a hydrogen atom,

R⁶ represents a hydrogen atom or a halogen atom,

R^(w) represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a benzyl group optionally having one or more substituents selected from Group A, a C2-C7 alkylcarbonyl group, a (C1-C3 alkoxy)methyl group, or a hydrogen atom,

T^(W2) represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C1-C5 alkylsulfanyl)C2-C5 alkyl group, the (C1-C5 alkylsulfinyl)C2-C5 alkyl group, and the (C1-C5 alkylsulfonyl)C2-C5 alkyl group each independently have one or more substituents selected from the group consisting of a cyano group and a halogen atom}, a (C3-C7 cycloalkyl)C1-C3 alkyl group or a C3-C7 cycloalkyl group {the (C3-C7 cycloalkyl)C1-C3 alkyl group and the C3-C7 cycloalkyl group each independently have one or more substituents selected from the group consisting of a cyano group, a halogen atom and a C1-C6 haloalkyl group), OR¹, S(O)_(v)R¹, OS(O)₂R¹, CH₂OR¹, NR¹R²⁹, C(O)R¹, C(O)NR¹R²⁹, NR²⁹C(O)R¹, N═CR¹R³⁰, a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, a group represented by formula T-8, a group represented by formula T-9, a group represented by formula T-10, a group represented by formula T-11, or a group represented by formula T-12, a halogen atom, a C1-C6 alkoxy group, a C1-C6 alkylsulfanyl group, a C1-C6 alkylsulfinyl group, a C1-C6 alkylsulfonyl group {the C1-C6 alkylsulfanyl group, the C1-C6 alkylsulfinyl group, and the C1-C6 alkylsulfonyl group each independently may optionally have a C3-C6 cycloalkyl group}, a C3-C6 cycloalkylsulfanyl group, a C3-C6 cycloalkylsulfinyl group, a C3-C6 cycloalkylsulfonyl group, a benzyloxy group optionally having one or more substituents selected from Group A, a C2-C7 alkylcarbonyloxy group optionally having one or more halogen atoms, a (C1-C3 alkoxy)methoxy group, or a hydroxy group,

X¹represents a nitrogen atom or CR^(1a),

X² represents a nitrogen atom or CR^(1b),

X³ represents a nitrogen atom or CR^(1c),

X⁴ represents a nitrogen atom or CR^(1d),

X⁵ represents a nitrogen atom or CR^(3e),

R^(1x) represents a C1-C5 chain hydrocarbon group having one or more halogen atoms, OR⁷, OS(O)₂R⁷, S(O)_(m)R⁷, NR⁸S(O)₂R⁷, or a halogen atom,

R^(1a), R^(1b), R^(1c), R^(1d), and R^(1e) are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a halogen atom, or a hydrogen atom,

Y¹ represents NR²⁵, an oxygen atom or a sulfur atom,

Y² represents a nitrogen atom or CR²⁶,

Y³ represents a nitrogen atom or CR²⁷,

Y⁴ represents a nitrogen atom or CR²⁸,

R²⁵, R²⁶, R²⁷ and R²⁸ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a halogen atom or a hydrogen atom,

R^(1y) represents a C1-C5 chain hydrocarbon group having one or more halogen atoms, OR⁷, OS(O)₂R⁷, S(O)_(m)R⁷, NR⁸S(O)₂R⁷, a cyano group, or a halogen atom,

R^(1ay) and R⁷ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group having one or more halogen atoms,

m and v are identical to or different from each other and each is 0, 1 or 2,

R¹ represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C1-C5 alkylsulfanyl)C2-C5 alkyl group, the (C1-C5 alkylsulfinyl)C2-C5 alkyl group, and the (C1-C5 alkylsulfonyl)C2-C5 alkyl group each independently have one or more substituents selected from the group consisting of a cyano group and a halogen atom}, a (C3-C7 cycloalkyl)C1-C3 alkyl group, or a C3-C7 cycloalkyl group {the (C3-C7 cycloalkyl)C1-C3 alkyl group and the C3-C7 cycloalkyl group each independently have one or more substituents selected from the group consisting of a cyano group, a halogen atom and a C1-C6 haloalkyl group},

R³⁰ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a halogen atom, OR³⁵, NR³⁶R³⁷, or a hydrogen atom,

R¹⁸ and R³⁵ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms,

R³ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group B, a C3-C7 cycloalkyl group optionally having one or more substituents selected from group E, a C3-C7 cycloalkenyl group optionally having one or more substituents selected from Group J, a phenyl group optionally having one or more substituents selected from Group H, a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group H, OR¹², NR¹¹R¹², NR^(11a)R^(12a), NR²⁴NR¹¹R¹², NR²⁴OR¹¹, NR¹¹C(O)R¹³, NR²⁴NR¹¹C(O)R¹³, NR¹¹C(O)OR¹⁴, NR²⁴NR¹¹C(O)OR¹⁴, NR¹¹C(O)NR¹⁵R¹⁶, NR²⁴NR¹¹C(O)NR¹⁵R¹⁶, N+CHNR¹⁵R¹⁶, N═S(O)_(x)R¹⁵R¹⁶, C(O)R¹⁷, C(O)OR¹⁷, C(O)NR¹⁵R¹⁶, CR²⁴═NOR¹⁷, NR¹¹CR²⁴═NOR¹⁷, a cyano group, a nitro group, or a halogen atom,

q is 0, 1, 2 or 3, and when q is 2 or 3, a plurality of R³ may be identical to or different from each other,

When two R³ are adjacent to each other, said two R³ may combined together with a carbon atom to which they are attached to form benzene ring, pyrrole ring, furan ring, thiophene ring, pyrazole ring, imidazole ring, triazole ring, oxazole ring, isoxazole ring, thiazole ring, oxadiazole ring, thiadiazole ring, pyridine ring, pyridazine ring, pyrimidine ring, or pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the triazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring, and the pyrazine ring each independently may optionally have one or more substituents selected from Group H},

R¹⁷ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a phenyl group optionally having one or more substituents selected from Group D, or a hydrogen atom,

R⁸, R¹¹, R¹⁹, R²⁴, R²⁹, R³⁶, and R³⁷ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a hydrogen atom,

R¹² represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally having one or more substituents selected from Group J, a C3-C7 cycloalkenyl group optionally having one or more substituents selected from Group J, a phenyl group, a six membered heterocyclic group {the phenyl group, and the six membered heterocyclic group each independently may optionally have one or more substituents selected from Group D}, a hydrogen atom, or a S(O)₂R²³,

R²³ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a phenyl group optionally having one or more substituents selected from Group D,

R^(11a) and R^(12a) combine together with the nitrogen atom to which they are attached to form a three to seven membered nonaromatic heterocyclic group optionally having one or more substituents selected from group E,

R¹³ represents a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally having one or more halogen atoms, a phenyl group optionally having one or more substituents selected from Group D, or a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group D,

R¹⁴ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally having one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may optionally have one or more substituents selected from Group D},

R¹⁵ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a hydrogen atom,

R¹⁶ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally having one or more substituents selected from Group J, S(O)₂R²³ or a hydrogen atom,

x is 0 or 1,

Group A: a group consisting of a C1-C6 alkyl group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, a halogen atom, a cyano group and a nitro group,

Group B: a group consisting of a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom,

Group D: a group consisting of a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, an amino group, NR⁹R¹⁰, C(O)R¹⁰, OC(O)R⁹, C(O)OR⁹, a cyano group, a nitro group, and a halogen atom,

R⁹ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a C3-C6 cycloalkyl group optionally having one or more halogen atoms,

R¹⁰ represents a C1-C6 alkyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, or a hydrogen atom,

Group E: a group consisting of a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group;

Group F: a group consisting of a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a phenyl group or a six membered aromatic heterocyclic group {the phenyl group and the six membered aromatic heterocyclic group each independently may optionally have one or more substituents selected from Group D}, OR¹⁰, an amino group, NR⁹R¹⁰, a halogen atom, a nitro group, and a cyano group;

Group H: a group consisting of a five or six membered aromatic heterocyclic group, a C1-C6 alkyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, OR¹⁰, an amino group, NR⁹R¹⁰, C(O)R¹⁰, C(O)NR⁹R¹⁰, OC(O)R⁹, OC(O)OR⁹, NR¹⁰C(O)R⁹, NR¹⁰C(O)OR⁹, C(O)OR¹⁰, a halogen atom, a nitro group, and a cyano group.

Group J: a group consisting of a C1-C6 alkyl group optionally having one or more halogen atoms, a halogen atom, a cyano group, a triazolyl group, and NR¹⁰C(O)R⁹. (hereinafter, referred to as “Intermediate compound E”).

-   [27] A compound represented by formula (IV):

[wherein,

R² represents a C1-C6 alkyl group optionally having one or more halogen atoms, a cyclopropyl group or a cyclopropylmethyl group,

n is 0, 1 or 2,

R³ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group B, a C3-C7 cycloalkyl group optionally having one or more substituents selected from group E, a C3-C7 cycloalkenyl group optionally having one or more substituents selected from Group J, a phenyl group optionally having one or more substituents selected from Group H, a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group H, OR¹², NR¹¹R¹², NR^(11a)R^(12a), NR²⁴NR¹¹R¹², NR²⁴OR¹¹, NR¹¹C(O)R¹³, NR²⁴NR¹¹C(O)R¹³, NR¹¹C(O)OR¹⁴, NR²⁴NR¹¹C(O)OR¹⁴, NR¹¹C(O)NR¹⁵R¹⁶, NR²⁴NR¹¹C(O)NR¹⁵R¹⁶, N═CHNR¹⁵R¹⁶, N═S(O)_(x)R¹⁵R¹⁶, C(O)R¹⁷, C(O)OR¹⁷, C(O)NR¹⁵R¹⁶, CR²⁴═NOR¹⁷, NR¹¹CR²⁴═NOR¹⁷, a cyano group, a nitro group, or a halogen atom,

q is 0, 1, 2 or 3, and when q is 2 or 3, a plurality of R³ may be identical to or different from each other,

When two R³ are adjacent to each other, said two R³ may combined together with a carbon atom to which they are attached to form benzene ring, pyrrole ring, furan ring, thiophene ring, pyrazole ring, imidazole ring, triazole ring, oxazole ring, isoxazole ring, thiazole ring, oxadiazole ring, thiadiazole ring, pyridine ring, pyridazine ring, pyrimidine ring, or pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the triazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring, and the pyrazine ring each independently may optionally have one or more substituents selected from Group H},

Het^(W) represents a group represented by the following formula Het 3 or a group represented by the following formula Het 4:

A¹ represents a nitrogen atom or CR⁶,

A² represents a nitrogen atom or CR^(4a),

A³ represents a nitrogen atom or CR^(4b),

A⁴ represents a nitrogen atom or CR^(4c),

Q¹ represents an oxygen atom or a sulfur atom,

R²⁰ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a hydrogen atom,

R⁵ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from group F, a C3-C6 cycloalkyl group optionally having one or more substituents selected from Group J, a phenyl group optionally having one or more substituents selected from Group H, or a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group H,

R^(4a), R^(4b) and R^(4c) are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally one or more halogen atoms, a nitro group, OR¹⁸, NR¹⁸R¹⁹, a cyano group, an amino group, a halogen atom, or a hydrogen atom,

R⁶ represents a hydrogen atom or a halogen atom,

X^(L) represents a halogen atom, a C1-C6 alkoxy group, a C1-C6 alkylsulfanyl group, a C1-C6 alkylsulfinyl group, a C1-C6 alkylsulfonyl group {the C1-C6 alkylsulfanyl group, the C1-C6 alkylsulfinyl group, and the C1-C6 alkylsulfonyl group each independently may optionally have a C3-C6 cyaloalkyl group}, a C3-C6 cycloalkylsulfanyl group, a C3-C6 cycloalkylsulfinyl group, a C3-C6 cycloalkylsulfonyl group, a benzyloxy group optionally having one or more substituents selected from Group A, a C2-C7 alkylcarbonyloxy group optionally having one or more halogen atoms, a (C1-C3 alkoxy)methoxy group, or a hydroxy group,

R¹⁸ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms,

R¹⁷ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a phenyl group optionally having one or more substituents selected from Group D, or a hydrogen atom,

R¹¹, R¹⁹ and R²⁴ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally one or more halogen atoms, or a hydrogen atom,

R¹² represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally having one or more substituents selected from Group J, a C3-C7 cycloalkenyl group optionally having one or more substituents selected from Group J, a phenyl group, or six membered heterocyclic group {the phenyl group, and the six membered heterocyclic group each independently may have optionally one or more substituents selected from Group D}, a hydrogen atom, or S(O)₂R²³,

R²³ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a phenyl group optionally having one or more substituents selected from Group D,

R^(11a) and R^(12a) combine together with the nitrogen atom to which they are attached to form a three to seven membered nonaromatic heterocyclic group optionally having one or more substituents selected from group E,

R¹³ represents a hydrogen atom, a C1-C6 Chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally having one or more halogen atoms, a phenyl group optionally having one or more substituents selected from Group D, or a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group D,

R¹⁴ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally having one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may optionally have one or more substituents selected from Group D},

R¹⁵ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a hydrogen atom,

R¹⁶ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally having one or more substituents selected from Group J, S(O)₂R²³ or a hydrogen atom,

x is 0 or 1,

Group A; a group consisting of a C1-C6 alkyl group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, a halogen atom, a cyano group and a nitro group,

Group B: a group consisting of a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a cyano group, a hydroxy group, and a halogen at

Group D: a group consisting of a C1-C6 chain hydrocarbon group optionally having one or lore halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, an amino group, NR⁹R¹⁰, C(O)R¹⁰, OC(O)R⁹, C(O)OR⁹, a cyano group, a nitro group, and a halogen atom,

R⁹ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a C3-C5 cycloalkyl group optionally having one or more halogen atoms,

R¹⁰ represents a C1-C6 alkyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, or a hydrogen atom,

Group E: a group consisting of a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group;

Group F: a group consisting of a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a phenyl group or a six membered aromatic heterocyclic group {the phenyl group and the six membered aromatic heterocyclic group each independently may optionally have one or more substituents selected from Group n}, OR¹⁰, an amino group, NR⁹R¹⁰, a halogen atom, a nitro group, and a cyano group;

Group H: a group consisting of a five or six membered aromatic heterocyclic group, a C1-C6 alkyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, OR¹⁰, an amino group, NR⁹R¹⁰, C(O)R¹⁰, C(O)NR⁹R¹⁰, OC(O)R⁹, OC(O)OR⁹, NR¹⁰C(O)R⁹, NR¹⁰C(O)OR⁹, c(O)OR¹⁰, a halogen atom, a nitro group, and a cyano group.

Group J: a group consisting of a C1-C6 alkyl group optionally having one or more halogen atoms, a halogen atom, a cyano group, a triazolyl group, and NR¹⁰C(O)R⁹].

-   (hereinafter, referred to as “Intermediate compound F”).

Effect of Invention

The present invention can control harmful arthropods.

MODE FOR CARRYING OUT THE INVENTION

The substituent(s) as described herein is/are explained.

The term “halogen atom” represents fluorine atom, chlorine atom, bromine atom, or iodine atom.

When the substituents have two or more halogen atoms, these halogen atoms may be identical to or different from each other.

The expression of “CX-CY” as used herein represents that the number of carbon atom is from X to Y. For example, the expression of “C1-C6” represents that the number of carbon atom is from 1 to 6,

The term of “chain hydrocarbon group” represents an alkyl group, an alkenyl group, or an alkynyl group.

Example of the term of “alkyl group” include methyl group, ethyl group, propyl group, isopropyl group, 1,1-dimethylpropyl group, 1,2-dimethylpropyl group, 1-ethylpropyl group, butyl group, sec-butyl group, tert-butyl group, pentyl group, hexyl group, octyl group, nonyl group, and decyl group.

Example of the term of “alkenyl group” include vinyl group, 1-propenyl group, 2-propenyl group, 1-methyl-1-propenyl group, 1-methyl-2-propenyl group, 1,2-dimethyl-1-propenyl group, 1-ethyl-2-propenyl group, 3-butenyl group, 4-pentenyl group, 5-hexenyl group, 7-octenyl group, 8-nonenyl group, and 9-decenyl group.

Example of the term of “alkynyl group” includes ethynyl group, 1-propynyl group, 2-propynyl group, 1-methyl-2-propynyl group, 1,1-dimethyl-2-propynyl group, 1-ethyl-2-propynyl group, 2-butynyl group, 4-pentynyl group, 5-hexynyl group, 7-octynyl group, 8-nonynyl group, and 9-decynyl group.

Example of the term of “C1-C6 alkyl group optionally having one or more halogen atoms” or “C1-C6 haloalkyl group” include trifluoromethyl group, 2,2,2-trifluoroethyl group, 2-bromo-1,1,2,2-tetrafluoroethyl group, 2,2,3,3-tetrafluoropropyl group, 1-methyl-2,2,3,3-tetrafluoropropyl group, and perfluorohexyl group.

Example of the term of “cycloalkyl group” includes cyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group and cycloheptyl group.

Example of the term of “cycloalkenyl group” includes cyclopropenyl group, cyclobutenyl group, cyclopentenyl group, cyclohexenyl group, and cycloheptenyl group. Examples of the term of “C3-C6 cycloalkyl group optionally having one or more halogen atoms” includes 2,2-difluorocyclopropyl group, 1-(2,2,2-trifluoroethyl)cyclopropyl group, and 4-(trifluoromethyl)cyclohexyl group.

Examples of the term of “alkoxy group” includes methoxy group, ethoxy group, propoxy group, butoxy group, pentoxy group, and hexyloxy group.

The term of “C1-C6 alkoxy group optionally having one or more halogen atoms” represents a C1-C6 alkoxy group wherein one or more halogen atoms are replaced by a halogen atom, and includes, for example, trifluoromethoxy group, difluoromethoxy group, 2,2,2-trichloroethoxy group, and 2,2,2-trifluoroethoxy group.

The terms of “alkylsulfanyl”, “alkylsulfinyl”, and “alkylsulfonyl” represent an alkyl group containing a S(O)_(z) moiety, respectively.

For example, examples of the “alkylsulfanyl” when z is 0 include methylsulfanyl group, ethylsulfanyl group, propylsulfanyl group, and isopropylsulfanyl group.

For example, examples of the “alkylsulfinyl” when z is 1 include methylsulfinyl group, ethylsulfinyl group, propylsulfinyl group, and isopropylsulfinyl group.

For example, examples of the “alkylsulfonyl” when z is include methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, and isopropylsulfonyl group.

Examples of the term of “three (3) to seven (7) membered nonaromatic heterocyclic group” include aziridine ring, azetidine ring, pyrrolidine ring, imidazoline ring, imidazolidine ring, piperidine ring, tetrahydropyrimidine ring, hexahydropyrimidine ring, piperazine ring, azepane ring, oxazolidine ring, isoxazolidine ring, 1,3-oxazinane ring, morpholine ring, 1,4-oxazepane ring, thiazolidine ring, isothiazolidine ring, 1,3-thiazinane ring, thiomorpholine ring, and 1,4-thiazepane ring. Examples of the three to seven membered nonaromatic heterocyclic group optionally having one or more substituents selected from Group E include the followings:

The term of “(C1-C5 alkoxy)C2-C5 alkyl group having one or mare halogen atom” represents a group wherein the (C1-C5 alkoxy) and/or the (C2-C5 alkyl) has/have one or more halogen atoms, and includes, for example, 2-(trifluoromethoxy)ethyl group, 2,2-difluoro-3-methoxypropyl group, 2,2-difluoro-3-(2,2,2-trifluoroethoxy)propyl group, and 3-(2-chloroethoxy)propyl group.

The term of “(C1-C5 alkylsulfanyl)C2-C5 alkyl group having one or more halogen atoms” represents a group wherein the (C1-C5 alkylsulfanyl) and/or the (C2-C5 alkyl) has/have one or more halogen atoms, and includes, for example, 2,2-difluoro-2-(trifluoromethylthio)ethyl group.

The term of “(C1-C5 alkylsulfinyl)C2-C5 alkyl group having one or more halogen atoms” represents a group wherein the (C1-C5 alkylsulfinyl) and/or the (C2-C5 alkyl) has/have one or more halogen atoms, and includes, for example, 2,2-difluoro-2-(trifluoromethansulfinyl)ethyl group.

The term of “(C1-C5 alkylsulfonyl)C2-C5 alkyl group having one or more halogen atoms” represents a group wherein the (C1-C5 alkylsulfonyl) and/or the (C2-C5 alkyl) has/have one or more halogen atoms, and includes, for example, 2,2-difluoro-2-(trifluoromethansulfonyl) ethyl group.

The term of “(C3-C7 cycloalkyl)C1-C3 alkyl group optionally having one or more halogen atoms” represents a group wherein the (C3-C7 cycloalkyl) and/or the (C1-C3 alkyl) has/have one car more halogen atoms, and includes, for example, (2,2-difluorocyclopropyl)methyl group, 2-cyclopropyl-1,1,2,2-tetrafluoroethyl group, and 2-(2,2-difluorocyclopropyl)-1,1,2,2-tetrafluoroethyl group.

The term of “(C3-C7 cycloalkyl)C1-C3 alkyl group having one or tore substituents selected from Group G” represents a group wherein the (C3-C7 cycloalkyl) and/or the (C1-C3 alkyl) has/have one or more substituents selected from Group G, and includes, example, (2,2-difluorocyclopropyl)methyl group, [1-(trifluoromethyl)cyclopropyl]methyl group, [2-(trifluoromethyl)cyclopropyl]methyl group, 2-cyclopropyl-1,1,2,2-tetrafluoroethyl group, 2-cyclopropyl-3,3,3-trifluoropropyl group, and 1,1,2,2, tetrafluoro-2-[2-(trifluoromethyl)cyclopropyl]ethyl group.

Examples of the term of “phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may optionally have one or more substituents selected from Group D}” include benzyl group, 2-fluorobenzyl group, 4-chlorobenzyl group, 4-(trifluoromethyl)benzyl group, and 2-[4-(trifluoromethyl)phenyl]ethyl group.

The term of “five (5) or six (6)membered aromatic heterocyclic group” represents a five membered aromatic heterocyclic group or a six membered aromatic heterocyclic group, and examples of the five membered aromatic heterocyclic group include pyrrolyl group, furyl group, thienyl group, pyrazolyl group, imidazolyl group, triazolyl group, tetrazolyl group, oxazolyl group, isoxazolyl group, thiazolyl group, isothiazolyl group, oxadiazolyl group, and thiadiazolyl group. As the five membered aromatic heterocyclic group, a five membered aromatic heterocyclic group containing 1 to 4 nitrogen atoms, that is, pyrrolyl group, pyrazolyl group, imidazolyl group, 1,2,4-triazolyl group, 1,2,3-triazolyl group, or tetrazolyl group is preferably included. Examples of the six membered aromatic heterocyclic group include pyridyl group, pyridazinyl group, pyrimidinyl group, pyrazinyl group, and triazinyl group.

The term of “when two R³ are adjacent to each other, said two R³ combine together with a carbon atom to which they are attached to form benzene ring, pyrrole ring, furan ring, thiophene ring, pyrazole ring, imidazole ring, triazole ring, oxazole ring, isoxazole ring, thiazole ring, oxadiazole ring, thiadiazole ring, pyridine ring, pyridazine ring, pyrimidine ring, or pyrazine ring” represents, for example, the following compounds when pyrrole ring is formed.

(wherein, R^(Ha), R^(Hb), and R^(Hc) are identical to or different from each other and each represents independently a five or six membered aromatic heterocyclic group, a C1-C6 alkyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, OR¹⁰, an amino group, NR⁹R¹⁰, C(O)R¹⁰, C(O)NR⁹R¹⁰, OC(O)R⁹, OC(O)CR⁹, NR¹⁰C(O)R⁹, NR¹⁰C(O)OR⁹, C(O)OR¹⁰, a halogen atom, a nitro group, or a cyano group, and the other symbols are the same as defined above.]

Examples of the embodiment of the compound of the present invention include the following compounds.

When “Present compound Z of the present invention” is described herein, encompasses “Present compound of the present invention” unless specified otherwise.

-   [Embodiment 1] A compound of the present invention wherein A¹     represents a nitrogen atom or CH. -   [Embodiment 2] The compound described in Embodiment 1 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴ or a halogen atom, R^(4a), R^(4b) and R^(4c) represent     a hydrogen atom, R⁵ represents a C1-C6 alkyl group optionally having     one or more halogen atoms, q is 0 or 1, and Q¹ and Q² represent an     oxygen atom. -   [Embodiment 3] A compound of the present invention wherein A¹     represents a nitrogen atom. -   [Embodiment 4] The compound described in Embodiment 3 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or a halogen atom. -   [Embodiment 5] The compound described in Embodiment 3 wherein R²     represents a C1-C6 alkyl group, R^(4a), R^(4b) and R^(4c) represent     a hydrogen atom or a halogen atom, q is 0 or 1, and Q¹ and Q²     represent an oxygen atom. -   [Embodiment 6] The compound described in Embodiment 5 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴ or a halogen atom, and R⁵     represents a C1-C6 alkyl group optionally having one or more halogen     atoms. -   [Embodiment 7] The compound described in Embodiment 3 wherein R²     represents a C1-C6 alkyl group, R³ represents a C1-C6 alkyl group,     C3-C7 cycloalkyl group {the C1-C6 alkyl group and the C3-C7     cycloalkyl group each independently may optionally have one or more     substituents selected from the group consisting of a halogen atom     and a cyano group}, a phenyl group, a pyridyl group {the phenyl     group and the pyridyl group each independently may optionally have     one or more substituents selected from Group G}, or a halogen atom,     R^(4a), R^(4b) and R^(4c) represent a hydrogen atom, R⁵ represents a     C1-C6 alkyl group optionally having one or more halogen atoms, q is     0 or 1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 8] A compound of the present invention wherein A¹     represents CH. -   [Embodiment 9] The compound described in Embodiment 8 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴, or a halogen atom, R^(4a), R^(4b) and R^(4c) represent     a hydrogen atom, R⁵ represents a C1-C6 alkyl group optionally having     one or more halogen atoms, q is 0 or 1, and Q¹ and Q² represent an     oxygen atom. -   [Embodiment 10] A compound of the present invention wherein Het     represents Het 1. -   [Embodiment 11] The compound described in Embodiment 10 wherein A¹     represents a nitrogen atom or CH. -   [Embodiment 12] The compound described in Embodiment 11 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O) OR¹⁴, or a halogen atom, R^(4a) and R^(4b) represent a     hydrogen atom, R⁵ represents a C1-C6 alkyl group optionally having     one or more halogen atoms, q is 0 or 1, and Q¹ and Q² represent an     oxygen atom. -   [Embodiment 13] The compound described in Embodiment 10 wherein A¹     represents a nitrogen atom. -   [Embodiment 14] The compound described in Embodiment 13 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O) OR¹⁴ or a halogen atom. -   [Embodiment 15] The compound described in Embodiment wherein R²     represents a C1-C6 alkyl group, R^(4a) and R^(4b) represent a     hydrogen atom or a halogen atom, q is 0 or 1, and Q¹ and Q²     represent an oxygen atom. -   [Embodiment 16] The compound described in Embodiment 15 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, pyrimidinyl group, a pyrazolyl group,     a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituent: selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or a halogen atom, and     R⁵ represents a C1-C6 alkyl group optionally having one or more     halogen atoms. -   [Embodiment 17] The compound described in Embodiment 13 wherein R²     represents a C1-C6 alkyl group, R³ represents a C1-C6 alkyl group, a     C3-C7 cycloalkyl group {the C1-CG alkyl group and the C3-C7     cycloalkyl group each independently may optionally have one or more     substituents selected from the group consisting of a halogen atom     and a cyano group}, a phenyl group, a pyridyl group {the phenyl     group, and the pyridyl group each independently may optionally have     one or more substituents selected from Group G}, or a halogen atom,     R^(4a) and R^(4b) represent a hydrogen atom, R⁵ represents a C1-C6     alkyl group optionally having one or more halogen atoms, q is 0 or     1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 18] The compound described in Embodiment 10 wherein A¹     represents CH. -   [Embodiment 19] The compound described in Embodiment 18 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl optionally     having one or more substituents selected from group B, a C3-C7     cycloalkyl group optionally having one or more substituents selected     from Group E, a phenyl group, a pyridyl group, a pyrimidinyl group,     a pyrazolyl group, a triazolyl group {the phenyl group, the pyridyl     group, the pyrimidinyl group, the pyrazolyl group, and the triazolyl     group each independently may optionally have one or more     substituents selected from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or     a halogen atom, R^(4a) and R^(4b) represent a hydrogen atom, R⁵     represents a C1-C6 alkyl group optionally having one or more halogen     atoms, q is 0 or 1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 20] The compound described in Embodiment 10 wherein A²     represents CR^(4a), and A³ represents CR^(4b). -   [Embodiment 21] The compound described in Embodiment 11 wherein A²     represents CR^(4a) and A³ represents CR^(4b). -   [Embodiment 22] The compound described in Embodiment 12 wherein A²     represents CR^(4a) and A³ represents CR^(4b). -   [Embodiment 23] The compound described in Embodiment 13 wherein A²     represents CR^(4a) and A³ represents CR^(4b). -   [Embodiment 24] The compound described in Embodiment 14 wherein A²     represents CR^(4a) and A³ represents CR^(4b). -   [Embodiment 25] The compound described in Embodiment 15 wherein A²     represents CR^(4a) and A³ represents CR^(4b). -   [Embodiment 26] The compound described in Embodiment 16 wherein A²     represents CR^(4a) and A³ represents CR^(4b). -   [Embodiment 27] The compound described in Embodiment 17 wherein A²     represents CR^(4a) and A³ represents CR^(4b). -   [Embodiment 28] The compound described in Embodiment 18 wherein A²     represents CR^(4a) and A³ represents CR^(4b). -   [Embodiment 29] The compound described in Embodiment 19 wherein A²     represents CR^(4a) and A³ represents CR^(4b). -   [Embodiment 30] A compound of the present invention wherein Het     represents a group represented by formula Het 1, A² represents     CR^(4a), and A³ represents a nitrogen atom. -   [Embodiment 31] The compound described in Embodiment 30 wherein A¹     represents a nitrogen atom or CH. -   [Embodiment 32] The compound described in Embodiment 31 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴, or a halogen atom, R^(4a) represents a hydrogen atom,     R⁵ represents a C1-C6 alkyl group optionally having one or more     halogen atoms, q is 0 or 1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 33] The compound described in Embodiment 30 wherein A¹     represents a nitrogen atom. -   [Embodiment 34] The compound described in Embodiment 33 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a 03-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or a halogen atom. -   [Embodiment 35] The compound described in Embodiment 33 wherein R²     represents a C1-C6 alkyl group, R^(4a) represents a hydrogen atom or     a halogen atom, q is 0 or 1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 36] The compound described in Embodiment 35 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from group J}, OR¹², NR¹¹R¹², NR¹¹C(O) OR¹⁴, or a halogen atom, and     R⁵ represents a C1-C6 alkyl group optionally having one or more     halogen atoms. -   [Embodiment 37] The compound described in Embodiment 33 wherein R²     represents a C1-C6 alkyl group, R³ represents a C1-C6 alkyl group, a     C3-C7 cycloalkyl group {the C1-C6 alkyl group and the C3-C7     cycloalkyl group each independently may optionally have one or more     substituents selected from the group consisting of a halogen atom     and a cyano group}, a phenyl group, a pyridyl group {the phenyl     group and the pyridyl group each independently may optionally have     one or more substituents selected from Group G}, or a halogen atom,     R^(4a) represents a hydrogen atom, R⁵ represents a C1-C6 alkyl group     optionally having one or more halogen atoms, q is 0 or 1, and Q¹ and     Q² represent an oxygen atom. -   [Embodiment 38] The compound described in Embodiment 30 wherein A¹     represents CH. -   [Embodiment 39] The compound described in Embodiment 38 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, triazolyl group the {the     phenyl group, the pyridyl group, the pyrimidinyl group, the     pyrazolyl group, and the triazolyl group each independently may     optionally have one or more substituents selected from group J},     OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or a halogen atom, R^(4a) represents a     hydrogen atom, R⁵ represents a C1-C6 alkyl group optionally having     one or more halogen atoms, q is 0 or 1, and Q¹ and Q² represent an     oxygen atom. -   [Embodiment 40] A compound of the present invention wherein Het     represents a group represented by formula Het1, A² represents a     nitrogen atom, and A³ represents CR^(4b). -   [Embodiment 41] The compound described in Embodiment 40 wherein A¹     represents a nitrogen atom or a CH. -   [Embodiment 42] The compound described in Embodiment 41 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴, or a halogen atom, R^(4b) represents a hydrogen atom,     R⁵ represents a C1-C6 alkyl group optionally having one or more     halogen atoms, q is 0 or 1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 43] The compound described in Embodiment 40 wherein A¹     represents a nitrogen atom. -   [Embodiment 44] The compound described in Embodiment 43 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B., a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or a halogen atom. -   [Embodiment 45] The compound described in Embodiment 43 wherein R²     represents a C1-C6 alkyl group, R^(4b) represents a hydrogen atom or     a halogen atom, q is 0 or 1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 46] The compound described in Embodiment 45 wherein R³     represents a C1-C6 alkyl group optionally having one or ore     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O) OR¹⁴, or a halogen atom, and     R⁵ represents a C1-C6 alkyl group optionally having one or more     halogen atoms. -   [Embodiment 47] The compound described in Embodiment 43 wherein R²     represents a C1-C6 alkyl group, R³ represents a C1-C6 alkyl group, a     C3-C7 cycloalkyl group {the C1-C6 alkyl group and the C3-C7     cycloalkyl group each independently may optionally have one or more     substituents selected from the group consisting of a halogen atom     and a cyano group}, a phenyl group, a pyridyl group {the phenyl     group and the pyridyl group each independently may optionally have     one or more substituents selected from Group G}, or a halogen atom,     R^(4b) represents a hydrogen atom, R⁵ represents a C1-C6 alkyl group     optionally having one or more halogen atoms, q is 0 or 1, and Q¹ and     Q² represent an oxygen atom. -   [Embodiment 48] The compound described in Embodiment 40 wherein A¹     represents CH. -   [Embodiment 49] The compound described in Embodiment 48 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴, or halogen atom, R^(4b) represents a hydrogen atom, R⁵     represents a C1-C6 alkyl group optionally having one or more halogen     atoms, q is 0 or 1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 50] A compound of the present invention wherein Het     represents a group represented by formula Het1, and A² and A³     represent a nitrogen atom. -   [Embodiment 51] The compound described in Embodiment 50 wherein A¹     represents a nitrogen atom or CH. -   [Embodiment 52] The compound described in Embodiment 51 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group L}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴, or a halogen atom, R⁵ represents a C1-C6 alkyl group     optionally having one or more halogen atoms, q is 0 or 1, and Q¹ and     Q² represent an oxygen atom. -   [Embodiment 53] The compound described in Embodiment 50 wherein A¹     represent a nitrogen atom. -   [Embodiment 54] The compound described in Embodiment 53 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyi group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or a halogen atom. -   [Embodiment 55] The compound described in Embodiment 53 wherein R²     represent, a C1-C6 alkyl group, q is 0 or 1, and Q¹ and Q² represent     an oxygen atom. -   [Embodiment 56] The compound described in Embodiment 55 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, or a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR-¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or a halogen atom, and     R⁵ represents a C1-C6 alkyl group optionally having one or more     halogen atoms. -   [Embodiment 57] The compound described in Embodiment 53 wherein R²     represents a C1-C6 alkyl group, R³ represents a C1-C6 alkyl group, a     C3-C7 cycloalkyl group {the C1-C6 alkyl group and the C3-C7     cycloalkyl group each independently may optionally have one or more     substituents selected from the group consisting of a halogen atom     and a cyano group}, a phenyl group, a pyridyl group {the phenyl     group and the pyridyl group each independently may optionally have     one or more substituents selected from Group G}, or a halogen atom,     R⁵ represents a C1-C6 alkyl group optionally having one or more     halogen atoms, q is 0 or 1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 58] The compound described in Embodiment 50 wherein A¹     represents CH. -   [Embodiment 59] The compound described in Embodiment 58 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴, or a halogen atom, R⁵ represents a C1-C6 alkyl group     optionally having one or more halogen atoms, q is 0 or 1, and Q¹ and     Q² represent an oxygen atom. -   [Embodiment 60] A compound of the present invention wherein Het     represents a group represented by formula Het2. -   [Embodiment 61] The compound described in Embodiment 60 wherein A¹     represents a nitrogen atom or CH. -   [Embodiment 62] The compound described in Embodiment 61 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴, or a halogen atom, R^(4a) and R^(4c) represent a     hydrogen atom, R⁵ represents a C1-C6 alkyl group optionally having     one or more halogen atoms, q is 0 or 1, and Q¹ and Q² represent an     oxygen atom. -   [Embodiment 63] The compound described in Embodiment 60 wherein A¹     represents a nitrogen atom. -   [Embodiment 64] The compound described in Embodiment 63 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, pyrimidinyl group, a pyrazolyl group,     a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or a halogen atom. -   [Embodiment 65] The compound described in Embodiment 63 wherein R²     represents a C1-C6 alkyl group, R^(4a) and R^(4c) represent a     hydrogen atom or a halogen atom, q is 0 or 1, and Q¹ and Q²     represent an oxygen atom. -   [Embodiment 66] The compound described in Embodiment 65 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or pore substituents selected from Group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or a halogen atom, and     R⁵ represents a C1-C6 alkyl group optionally having one or more     halogen atoms. -   [Embodiment 67] The compound described in Embodiment 63 wherein R²     represents a C1-C6 alkyl group, R³ represents a C1-C6 alkyl group, a     C3-C7 cycloalkyl group {the C1-C6 alkyl group and the C3-C7     cycloalkyl group each independently may optionally have one or more     substituents selected from the group consisting of a halogen atom     and a cyano group}, a phenyl group, a pyridyl group {the phenyl     group and the pyridyl group each independently may optionally have     one or more substituents selected from Group G}, or a halogen atom,     R^(4a) and R^(4c) represent a hydrogen atom, R⁵ represents a C1-C6     alkyl group optionally having one or more halogen atoms, q is 0 or     1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 68] The compound described in Embodiment 60 wherein A¹     represents a CH. -   [Embodiment 69] The compound described in Embodiment 68 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴, or a halogen atom, R^(4a) and R^(4c) represent a     hydrogen atom, R⁵ represents a C1-C6 alkyl group optionally having     one or more halogen atoms, q is 0 or 1, and Q¹ and Q² represent an     oxygen atom. -   [Embodiment 70] The compound described in Embodiment 60 wherein A²     represents CR^(4a) and A⁴ represents CR^(4c). -   [Embodiment 71] The compound described in Embodiment 61 wherein A²     represents CR^(4a) and A⁴ represents CR^(4c). -   [Embodiment 72] The compound described in Embodiment 62 wherein A²     represents CR^(4a) and A⁴ represents CR^(4c). -   [Embodiment 73] The compound described in Embodiment 63 wherein A²     represents CR^(4a) and A⁴ represents CR^(4c). -   [Embodiment 74] The compound described in Embodiment 64 wherein A²     represents CR^(4a) and A⁴ represents CR^(4c). -   [Embodiment 75] The compound described in Embodiment 65 wherein A²     represents CR^(4a) and A⁴ represents CR^(4c). -   [Embodiment 76] The compound described in Embodiment 66 wherein A²     represents CR^(4a) and A⁴ represents CR^(4c). -   [Embodiment 77] The compound described in Embodiment 67 wherein A²     represents CR^(4a) and A⁴ represents CR^(4c). -   [Embodiment 78] The compound described in Embodiment 68 wherein A²     represents CR^(4a) and A⁴ represents CR^(4c). -   [Embodiment 79] The compound described in Embodiment 69 wherein A²     represents CR^(4a) and A⁴ represents CR^(4c). -   [Embodiment 80] A compound of the present invention wherein Het     represents a group represented by formula Het2, A² represents     CR^(4a) and A⁴ represents a nitrogen atom. -   [Embodiment 81] The compound described in Embodiment 80 wherein A¹     represents a nitrogen atom or CH. -   [Embodiment 82] The compound described in Embodiment 81 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴, or a halogen atom, R^(4a) represents a hydrogen atom,     R⁵ represents a C1-C6 alkyl group optionally having one or more     halogen atoms, q is 0 or 1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 83] The compound described in Embodiment 80 wherein A¹     represents a nitrogen atom. -   [Embodiment 84] The compound described in Embodiment 83 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or a halogen atom. -   [Embodiment 85] The compound described in Embodiment 83 wherein R²     represents a C1-C6 alkyl group, R^(4a) represents a hydrogen atom or     a halogen atom, q is 0 or 1, Q¹ and Q² represent an oxygen atom. -   [Embodiment 86] The compound described in Embodiment 85 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or a halogen atom, R⁵     represents a C1-C6 alkyl group optionally having one or more halogen     atoms. -   [Embodiment 87] The compound described in Embodiment 83 wherein R²     represents a C1-C6 alkyl group, R³ represents a C1-C6 alkyl group, a     C3-C7 cycloalkyl group {the C1-C6 alkyl group and the C3-C7     cycloalkyl group each independently may optionally have one or more     substituents selected from the group consisting of a halogen atom     and a cyano group}, a phenyl group, a pyridyl group {the phenyl     group and the pyridyl group each independently may optionally have     one or more substituents selected from Group G}, or a halogen atom,     R^(4a) represents a hydrogen atom, R⁵ represents a C1-C6 alkyl group     optionally having one or more halogen atoms, q is 0 or 1, and Q¹ and     Q² represent an oxygen atom. -   [Embodiment 88] The compound described in Embodiment 80 wherein A¹     represents CH. -   [Embodiment 89] The compound described in Embodiment 88 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, pyridyl group, a pyrimidinyl     group, a pyrazolyl group, a triazolyl group {the phenyl group, the     pyridyl group, the pyrimidinyl group, the pyrazolyl group, and the     triazolyl group each independently may optionally have one or more     substituents selected from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or     a halogen atom, R^(4a) represents a hydrogen atom, R⁵ represents a     C1-C6 alkyl group optionally having one or more halogen atoms, q is     0 or 1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 90] A compound of the present invention wherein Het     represents a group represented by formula Het2, A² represents a     nitrogen atom, and A⁴ represents CR^(4c). -   [Embodiment 91] The compound described in Embodiment 90 wherein A¹     represents a nitrogen atom or CH. -   [Embodiment 92] The compound described in Embodiment 91 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴, or a halogen atom, R^(4c) represents a hydrogen atom,     R⁵ represents a C1-C6 alkyl group optionally having one or more     halogen atoms, q is 0 or 1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 93] The compound described in Embodiment 90 wherein A¹     represents a nitrogen atom. -   [Embodiment 94] The compound described in Embodiment 93 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or a halogen atom. -   [Embodiment 95] The compound described in Embodiment 93 wherein R²     represents a C1-C6 alkyl group, R^(4c) represents a hydrogen atom or     a halogen atom, q is 0 or 1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 96] The compound described in Embodiment 95 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or a halogen atom, R⁵     represents a C1-C6 alkyl group optionally having one or more halogen     atoms, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 97] The compound described in Embodiment 93 wherein R²     represents a C1-C6 alkyl group, R³ represents a C1-C6 alkyl group, a     C3-C7 cycloalkyl group {the C1-C6 alkyl group and the C3-C7     cycloalkyl group each independently may optionally have one or more     substituents selected from the group consisting of a halogen atom     and a cyano group}, a phenyl group, a pyridyl group {the phenyl     group and the pyridyl group each independently may optionally have     one or more substituents selected from Group G}, or a halogen atom,     R^(4c) represents a hydrogen atom, R⁵ represents a C1-C6 alkyl group     optionally having one or more halogen atoms, q is 0 or 1, and Q¹ and     Q² represent an oxygen atom. -   [Embodiment 98] The compound described in Embodiment 90 wherein A¹     represents CH. -   [Embodiment 99] The compound described in Embodiment 98 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴, or a halogen atom, R^(4c) represents a hydrogen atom,     R⁵ represents a C1-C6 alkyl group optionally having one or more     halogen atoms, q is 0 or 1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 100] A compound of the present invention wherein Het     represents a group represented by formula Het2 and A² and A⁴     represent a nitrogen atom. -   [Embodiment 101] The compound described in Embodiment 100 wherein A¹     represents a nitrogen atom or CH. -   [Embodiment 102] The compound described in Embodiment 101 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴, or a halogen atom, R⁵ represents a C1-C6 alkyl group     optionally having one or more halogen atoms, q is 0 or 1, and Q¹ and     Q² represent an oxygen atom. -   [Embodiment 103] The compound described in Embodiment 100 wherein A¹     represents a nitrogen atom. -   [Embodiment 104] The compound described in Embodiment 103 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O) OR¹⁴, or a halogen atom. -   [Embodiment 105] The compound described in Embodiment 103 wherein R²     represents a C1-C6 alkyl group, q is 0 or 1, and Q¹ and Q² represent     an oxygen atom. -   [Embodiment 106] The compound described in Embodiment 105 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group B, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or a halogen atom, and     R⁵ represents a C1-C6 alkyl group optionally having one or more     halogen atoms. -   [Embodiment 107] The compound described in Embodiment 103 wherein R²     represents a C1-C6 alkyl group, R³ represents a C1-C6 alkyl group, a     C3-C7 cycloalkyl group {the C1-C6 alkyl group and the C3-C7     cycloalkyl group each independently may optionally have one or more     substituents selected from the group consisting of a halogen atom     and a cyano group}, phenyl group, a pyridyl group {the phenyl group     and the pyridyl group each independently may optionally have one or     more substituents selected from Group G}, or a halogen atom, R⁵     represents a C1-C6 alkyl group optionally having one or more halogen     atoms, q is 0 or 1, and Q¹ and Q² represent an oxygen atom. -   [Embodiment 108] The compound described in Embodiment 100 wherein A¹     represents CH. -   [Embodiment 109] The compound described in Embodiment 108 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O) OR¹⁴, or a halogen atom, R⁵ represents a C1-C6 alkyl group     optionally having one or more halogen atoms, q is 0 or 1, and Q¹ and     Q² represent an oxygen atom. -   [Embodiment 110] A compound of the present invention wherein Het     represents a group represented by formula Het1, A² represents     CR^(4a), A³ represents CR^(4b), and when Het represent a group     represented by Het2, A² represents CR^(4a) and A⁴ represents     CR^(4c). -   [Embodiment 111] The compound described in Embodiment 110 wherein A¹     represents a nitrogen atom or CH. -   [Embodiment 112] The compound described in Embodiment 111 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituent selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴, or a halogen atom, R^(4a), R^(4b) and R^(4c) represent     a hydrogen atom, R⁵ represents a C1-C6 alkyl group optionally having     one or more halogen atoms, q is 0 or 1, and Q¹ and Q² represent an     oxygen atom. -   [Embodiment 113] The compound described in Embodiment 110 wherein A¹     represents a nitrogen atom. -   [Embodiment 114] The compound described in Embodiment 113 wherein R³     representsa C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴ , or a halogen atom. -   [Embodiment 115] The compound described in Embodiment 113 wherein R²     represents a C1-C6 alkyl group, R^(4a), R^(4b) and R^(4c) represent     a hydrogen atom or a halogen atom, q is 0 or 1, and Q¹ and Q²     represent an oxygen atom. -   [Embodiment 116] The compound described in Embodiment 115 wherein R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, a C3-C7 cycloalkyl group     optionally having one or more substituents selected from Group E, a     phenyl group, a pyridyl group, a pyrimidinyl group, a pyrazolyl     group, a triazolyl group {the phenyl group, the pyridyl group, the     pyrimidinyl group, the pyrazolyl group, and the triazolyl group each     independently may optionally have one or more substituents selected     from Group J}, OR¹², NR¹¹R¹², NR¹¹C(O)OR¹⁴, or a halogen atom, and     R⁵ represents a C1-C6 alkyl group optionally having one or more     halogen atoms. -   [Embodiment 117] The compound described in Embodiment 113 wherein R²     represents a C1-C6 alkyl group, R³ represents a C1-C6 alkyl group, a     C3-C7 cycloalkyl group {the C1-C6 alkyl group and the C3-C7     cycloalkyl group each independently may optionally have one or more     substituents selected from the group consisting of a halogen atom     and a cyano group}, a phenyl group, a pyridyl group {the phenyl     group and the pyridyl group each independently may optionally have     one or more substituents selected from Group G}, or a halogen atom,     R^(4a), R^(4b), R^(4c) represent a hydrogen atom, R⁵ represents a     C1-C6 alkyl group optionally having one or more halogen atoms, q is     0 or 1, and Q¹and Q² represent an oxygen atom. -   [Embodiment 118] The compound described in Embodiment 113 wherein R²     represents an ethyl group, R³, R^(4a), R^(4b) and R^(4c) represent a     hydrogen atom, R⁵ represents a C1-C6 alkyl group, q is 0, n is 2,     and Q¹ and Q² represent an oxygen atom. -   [Embodiment 119] The compound described in Embodiment 110 wherein A¹     represents CH. -   [Embodiment 120] The compound described in Embodiment 119 wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, a pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴, or a halogen atom, R^(4a), R^(4b) and R^(4c) represent     a hydrogen atom, R⁵ represents a C1-C6 alkyl group optionally having     one or more halogen atoms, q is 0 or 1, and Q¹ and Q² represent an     oxygen atom. -   [Embodiment 121] A compound of the present invention wherein A¹     represents a nitrogen atom or CH, R² represents an ethyl group, R³     represents a C1-C5 alkyl group, a C3-C7 cycloalkyl group {the C1-C6     alkyl group and the C3-C7 cycloalkyl group each independently may     optionally have one or more substituents selected from the group     consisting of a halogen atom and a cyano group}, a phenyl group, a     pyrazolyl group, a pyridyl group {the phenyl group, the pyrazolyl     group, and the pyridyl group each independently may optionally have     one or more substituents selected from Group G}, or a halogen atom,     R^(4a), R^(4b) and R^(4c) represent a hydrogen atom, R⁵ represents a     C1-C6 alkyl group or a C3-C6 cycloalkyl group, q is 0 or 1, n is 2,     and Q¹ and Q² represent an oxygen atom. -   [Embodiment 122] A compound of the present invention wherein A¹     represents a nitrogen atom or CH, R² represents an ethyl group, R³     represents a C1-C6 alkyl group, a C3-C7 cycloalkyl group {the C1-C6     alkyl group and the C3-C7 cycloalkyl group each independently may     optionally have one or more substituents selected from the group     consisting a halogen atom and a cyano group}, a phenyl group, a     pyridyl group {the phenyl group, the pyrimidinyl group, and the     pyridyl group each independently may optionally have one or more     substituents selected from Group G}, or a halogen atom, R^(4a),     R^(4b) and R^(4c) represent a hydrogen atom, R⁵ represents a C1-C6     alkyl group, q is 0 or 1, n is 2, and Q² and Q² represent an oxygen     atom. -   [Embodiment 123] A compound of the present invention wherein T     represents a C1-C5 chain hydrocarbon group having one or more     halogen atoms, OR¹, S(O)_(v)R¹, OS(O)₂R¹, CH₂OR¹, NR¹R²⁹, C(O)R¹,     C(O)NR¹R²⁹, NR²⁹C(O)R¹, N═CR¹R³⁰, a group represented by formula     T-1, a group represented by formula T-2, a group represented by     formula T-3, a group represented by formula T-4, a group represented     by formula T-5, a group represented by formula T-6, a group     represented by formula T-7, a group represented by formula T-8, a     group represented by formula T-9, a group represented by formula     T-10, a group represented by formula T-11, or a group represented by     formula T-12, and R¹, R^(1x), R^(1y) and R^(1ay) are identical to or     different from each other and each represents independently a C1-C5     chain hydrocarbon group having one more halogen atoms. -   [Embodiment 124] A compound of the present invention wherein T     represents a C1-C5 alkyl group having three or more fluorine atoms,     OR¹, S(O)_(v)R¹, OS(O)₂R¹, CH₂OR¹, NR¹R²⁹, C(O)R¹, C(O)NR¹R²⁹,     NR²⁹C(O)R¹, N═CR¹R³⁰, a group represented by formula T-1, a group     represented by formula T-2, a group represented by formula T-3, a     group represented by formula T-4, a group represented by formula     T-5, a group represented by formula T-6, a group represented by     formula T-7, a group represented by formula T-8, a group represented     by formula T-9, a group represented by formula T-10, a group     represented by formula T-11, or a group represented by formula T-12,     and R¹, R^(1x), R^(1y) and R^(1ay) are identical to or different     from each other and each represents independently a C1-C5 alkyl     group having three or more fluorine atoms. -   [Embodiment 125] A compound of the present invention wherein T     represents a C1-C5 chain hydrocarbon group having one or more     halogen atoms, OR¹, S(O)_(v)R¹, OS(O)₂R¹, NR¹R²⁹, a group     represented by formula T-1, a group represented by formula T-2, a     group represented by formula T-3, a group represented by formula     T-4, or a group represented by formula T-8, and R¹, R^(1x) and     R^(1y) are identical to or different from each other and each     represents independently a C1-C5 chain hydrocarbon group having one     or more halogen atoms. -   [Embodiment 126] A compound of the present invention wherein T     represents a C1-C5 alkyl group having three or more fluorine atoms,     OR¹, S(O)_(v)R¹, OS(O)₂R¹, NR¹R²⁹, a group represented by formula     T-1, a group represented by formula T-2, a group represented by     formula T-3, a group represented by formula T-4, or a group     represented by formula T-8, and R¹, R^(1x) and R^(1y) are identical     to or different from each other and each represents independently a     C1-C5 alkyl group having three or more fluorine atoms. -   [Embodiment 127] A compound of the present invention wherein T     represents a C1-C5 chain hydrocarbon group having one or more     halogen atoms, OR¹, S(O)_(v)R¹, OS(O)₂R¹, NR¹R²⁹, and R¹ represents     a C1-C5 chain hydrocarbon group having one more halogen atoms. -   [Embodiment 128] A compound of the present invention wherein T     represents a C1-C5 alkyl group having three or more fluorine atoms,     OR¹, S(O)_(v)R¹, OS(O)₂R¹, NR¹R²⁹, and R¹ represents a C1-C5 alkyl     group having three or more fluorine atoms. -   [Embodiment 129] A compound of the present invention wherein T     represents OR¹. -   [Embodiment 130] The compound described in Embodiment 129 wherein R¹     represents a C1-C5 chain hydrocarbon group having one or more     halogen atoms. -   [Embodiment 131] The compound described in Embodiment 129 wherein R¹     represents a C1-C5 alkyl group having three or more fluorine atoms. -   [Embodiment 132] A compound of the present invention wherein T     represents a group represented by formula T-1, a group represented     by formula T-2, a group represented by formula T-3, a group     represented by formula T-4, or a group represented by formula T-8. -   [Embodiment 133] The compound described in Embodiment 132 wherein     R^(1x) and R^(1y) are identical to or different from each other and     each represents independently a C1-C5 chain hydrocarbon group having     one or more halogen atoms. -   [Embodiment 134] The compound described in Embodiment 132 wherein     R^(1x) and R^(1y) are identical to or different from each other and     each represents independently a C1-C5 alkyl group having three or     more fluorine atoms. -   [Embodiment 135] The compound described in anyone of Embodiments 1     to 121 or 122 wherein T represents a C1-C5 chain hydrocarbon group     having one or more halogen atoms, OR¹, S(O)_(v)R¹, OS(O)₂R¹, CH₂OR¹,     NR¹R²⁹, C(O)R¹, C(O)NR¹R²⁹, NR²⁹C(O)R¹, N═CR¹R³⁰, a group     represented by formula T-1, a group represented by formula T-2, a     group represented by formula T-3, a group represented by formula     T-4, a group represented by formula T-5, a group represented by     formula T-6, a group represented by formula T-7, a group represented     by formula T-8, a group represented by formula T-9, a group     represented by formula T-10, a group represented by formula T-11, or     a group represented by formula T-12, and R¹, R^(1x), R^(1y) and     R^(1ay) are identical to or different from each other and each     represents independently a C1-C5 chain hydrocarbon group having one     or more halogen atoms. -   [Embodiment 136] The compound described in Embodiments 1 to 121 or     122 wherein T represents a C1-C5 alkyl group having three or more     fluorine atoms, OR¹, S(O)_(v)R¹, OS(O)₂R¹, CH₂OR¹, NR¹R²⁹, C(O)R¹,     C(O)NR¹R²⁹, NR²⁹C(O)R¹, N═CR¹R³⁰, a group represented by formula     T-1, a group represented by formula T-2, a group represented by     formula T-3, a group represented by formula T-4, a group represented     by formula T-5, a group represented by formula T-6, a group     represented by formula T-74 a group represented by formula T-8, a     group represented by formula T-9, a group represented by formula     T-10, a group represented by formula T-11, or a group represented by     formula T-12, and R¹, R^(1x), R^(1y) and R^(1ay) are identical to or     different from each other and each represents independently a C1-C5     alkyl group having three or more fluorine atoms. -   [Embodiment 137] The compound described in anyone of Embodiments 1     to 121 or 122 wherein T represents a C1-C5 chain hydrocarbon group     having one or more halogen atoms, OR¹, S(O)_(v)R¹, OS(O)₂R¹, NR¹R²⁹,     a group represented by formula T-1, a group represented by formula     T-2, a group represented by formula T-3, a group represented by     formula T-4, or a group represented by formula T-8, and R¹, R^(1x),     and R^(1y) are identical to or different from each other and each     represents independently a C1-C5 chain hydrocarbon group having one     or more halogen atoms. -   [Embodiment 138] The compound described in anyone of Embodiments 1     to 121 or 122 wherein T represents a C1-C5 alkyl group having three     or more fluorine atoms, OR¹, S(O)_(v)R¹, OS(O)₂R¹, NR¹R²⁹ , a group     represented by formula T-1, a group represented by formula T-2, a     group represented by formula T-3, a group represented by formula     T-4, or a group represented by formula T-8, and R¹, R^(1x), and     R^(1y) are identical to or different from each other and each     represents independently a C1-C5 alkyl group having three or more     fluorine atoms. -   [Embodiment 139] The compound described in anyone or more     Embodiments 1 to 121 or 122 wherein T represents a C1-C5 chain     hydrocarbon group having one or more halogen atoms, OR¹, S(O)_(v)R¹,     OS(O)₂R¹, NR¹R²⁹, anal R¹ represents a C1-C5 chain hydrocarbon group     having one or more halogen atoms. -   [Embodiment 140] The compound described in anyone of Embodiments 1     to 121 or 122 wherein T represents a C1-C5 alkyl group having three     or more fluorine atoms, OR¹, S(O)_(v)R¹, OS(O)₂R¹, or NR¹R²⁹, and R¹     represents a C1-C5 alkyl group having three or more fluorine atoms. -   [Embodiment 141] The compound described in anyone of Embodiments 1     to 121 or 122 wherein T represents OR¹. -   [Embodiment 142] The compound described in anyone of Embodiments 1     to 121 or 122 wherein T represents OR¹, and R¹ represents a C1-C5     chain hydrocarbon group having one or more halogen atoms. -   [Embodiment 143] The compound described in anyone of Embodiments 1     to 121 or 122 wherein T represents OR¹⁰, and R¹ represents a C1-C5     alkyl group having three or more fluorine atoms. -   [Embodiment 144] The compound described in anyone of Embodiments 1     to 121 or 122 wherein T represents a group represented by formula     T-1, a group represented by formula T-2, a group represented by     formula T-3, a group represented by formula T-4, or a group     represented by formula T-8. -   [Embodiment 145] The compound described in anyone of Embodiments 1     to 121 or 122 wherein T represents a group represented by formula     T-1, a group represented by formula T-2, a group represented by     formula T-3, a group represented by formula T-4, or a group     represented by formula T-8, and R^(1x) and R^(1y) are identical to     or different from each other and each represents independently a     C1-C5 chain hydrocarbon group having one or more halogen atoms. -   [Embodiment 146] The compound described in anyone of Embodiments 1     to 121 or 122 wherein T represents a group represented by formula     T-1, a group represented by formula T-2, a group represented by     formula T-3, a group represented by formula T-4, or a up represented     by formula T-8, and R^(1x) and R^(1y) are identical to or different     from each other and each represent independently a C1-C5 alkyl group     having three or more fluorine atoms. -   [Embodiment 147] The compound described in Embodiments 1 to 121 or     122 wherein T represents OR¹, a group represented by formula T-1, a     group represented by formula T-2, or a group represented by formula     T-8, R¹, R^(1x) and R^(1y) are identical to or different from each     other and each represents independently a C1-C5 alkyl group having     one or more fluorine atoms, X¹ represents CR^(1a), X² represents     CR^(1b), X³ represents CR^(1c) and X⁵ represents CR^(1e).

Examples of the embodiment of the compound Z of the present invention include the following compounds.

-   [Embodiment 148] A compound Z of the present invention wherein R²     represents an ethyl group, R³ represents a C1-C6 alkyl group     optionally having one or more substituents selected from Group B, a     C3-C7 cycloalkyl group optionally having one or more substituents     selected from Group E, a phenyl group, a pyridyl group, a     pyrimidinyl group, pyrazolyl group, a triazolyl group {the phenyl     group, the pyridyl group, the pyrimidinyl group, the pyrazolyl     group, and the triazolyl group each independently may optionally     have one or more substituents selected from Group J}, OR¹², NR¹¹R¹²,     NR¹¹C(O)OR¹⁴, or a halogen atom, R^(4a), R^(4b) and R^(4c) represent     a hydrogen atom, R⁵ represents a C1-C6 alkyl group optionally having     one or more halogen atoms, q is 0 or 1, n is 2, and Q¹ and Q²     represent an oxygen atom. -   [Embodiment 149] The compound described in Embodiment 148 wherein A¹     represents a nitrogen atom, T represents a C1-C5 alkyl group having     one or more substituents selected from the group consisting of a     cyano group and a halogen atom, OR¹, S(O)_(v)R¹, OS(O)₂R¹, NR¹R²⁹, a     group represented by formula T-1, a group represented by formula     T-2, a group represented by formula T-3, a group represented by     formula T-4, or a group represented by formula T-8, and R¹, R^(1x)     and R^(1y) are identical to or different from each other and each     represents independently a C1-C5 alkyl group optionally having one     or more substituents selected from the group consisting of a cyano     group and a halogen atom. -   [Embodiment 150] The compound described in Embodiment 148 wherein A¹     represents a nitrogen atom or CH, T represents a C1-C5 alkyl group     having one or more substituents selected from the group consisting     of a cyano group and a halogen atom, OR¹, S(O)_(v)R¹, OS(O)₂R¹, or     NR¹R²⁹, and R¹ represent a C1-C5 alkyl group having one or more     substituents selected from the group consisting of a cyano group and     a halogen atom. -   [Embodiment 151] The compound described in Embodiment 148 wherein A¹     represents a nitrogen atom, T represents a group represented by     formula T-1, a group represented by formula T-2, a group represented     by formula T-3, a group represented by formula T-4, or a group     represented by formula T-8, and R^(1x) and R^(1y) are identical to     or different from each other and each represents independently a     C1-C5 alkyl group optionally having one or more substituents     selected from the group consisting of a cyano group and a halogen     atom. -   [Embodiment 152] The compound described in Embodiment 148 wherein A¹     represents a nitrogen atom, and T represents a C1-C5 alkoxy group     having one or more substituents selected from the group consisting     of a cyano group and a halogen atom. -   [Embodiment 153] The compound described in Embodiment 148 wherein R⁵     represents a C1-C6 alkyl group optionally having one or more halogen     atoms. -   [Embodiment 154] The compound described in Embodiment 153 wherein A¹     represents a nitrogen atom or CH, T represents a C1-C5 alkyl group     having one or more substituents selected from the group consisting     of a cyano group and a halogen atom, OR¹, S(O)_(v)R¹, OS(O)₂R¹,     NR¹R²⁹, a group represented by formula T-1, a group represented by     formula T-2, a group represented by formula T-3, a group represented     by formula T-4, or a group represented by formula T-8, and R¹,     R^(1x) and R^(1y) are identical to or different from each other and     each represents independently a C1-C5 alkyl group optionally having     one or more substituents selected from the group consisting of a     cyano group and a halogen atom. -   [Embodiment 155] The compound described in Embodiment 154 wherein A¹     represents a nitrogen atom. -   [Embodiment 156] The compound described in Embodiment 153 wherein A¹     represents a nitrogen atom or CH, T represents a C1-C5 alkyl group     having one or more substituents selected from the group consisting     of a cyano group and a halogen atom, OR¹, S(O)_(v)R¹, OS(O)₂R¹, or     NR¹R²⁹, and R¹ represents C1-C5 alkyl group optionally having one or     more substituents selected from the group consisting of a cyano     group and a halogen atom. -   [Embodiment 157] The compound described in Embodiment 156 wherein A¹     represents a nitrogen atom. -   [Embodiment 158] The compound described in Embodiment 153 wherein A¹     represents a nitrogen atom or CH, T represents a group represented     by formula T-1, a group represented by formula T-2, a group     represented by formula T-3, a group represented by formula T-4, or a     group represented by formula T-8, and R^(1x) and R^(1y) are     identical to or different from each other and each represents     independently a C1-C5 alkyl group optionally having one or more     substituents selected from the group consisting of a cyano group and     a halogen atom. -   [Embodiment 159] The compound described in Embodiment 158 wherein A¹     represents a nitrogen atom. -   [Embodiment 160] The compound described in Embodiment 153 wherein A¹     represents a nitrogen atom or CH, and T represents a C1-C5 alkoxy     group having one or more substituents selected from the group     consisting of a cyano group and a halogen atom. -   [Embodiment 161] The compound described in Embodiment 160 wherein A¹     represents a nitrogen atom.

Examples of the embodiment of the intermediate compound D include the following compounds.

-   [Embodiment 162] An intermediate compound D wherein R² represents a     C1-C6 alkyl group optionally having one or more halogen atoms, n is     2, R^(w) represents C1-C6 chain hydrocarbon group optionally having     one or more halogen atoms, T^(W) represents a halogen atom, a C1-C6     alkylsulfanyl group, a C1-C6 alkylsulfinyl group, a C1-C6     alkylsulfonyl group, and R^(4a), R^(4b) and R^(4c) each represents a     hydrogen atom. -   [Embodiment 163] The compound described in Embodiment 162 wherein A²     represents CH, A³ represents a nitrogen atom or CH, and A⁴     represents a nitrogen atom or CH. -   [Embodiment 164] The compound described in Embodiment 162 wherein A²     represents CH, A³ represents CH, and A⁴ represents a nitrogen atom. -   [Embodiment 165] The compound described in Embodiment 162 wherein A²     represents CH, A³ represents a nitrogen atom, and A⁴ represents CH. -   [Embodiment 166] The compound described in Embodiments 162 to 165     wherein R² represents an ethyl group, R^(w) represents a C1-C3 alkyl     group, and T^(W) represents a halogen atom or a C1-C3 alkylsulfanyl     group. -   [Embodiment 167] The compound described in Embodiments 162 to 165     wherein R² represents an ethyl group, R^(w) represents a C1-C3 alkyl     group, and T^(W) represents a halogen atom.

Examples of the embodiment of the intermediate compound E include the following compounds.

-   [Embodiment 168] An intermediate compound E wherein R² represents a     C1-C6 alkyl group optionally having one or more halogen atoms, n is     0 or 2, R^(w) represents a C1-C6 chain hydrocarbon group optionally     having one or more halogen atoms, a benzyl group optionally having     one or more substituents selected from Group A, or a hydrogen atom,     T^(W2) represents a halogen atom, a C1-C6 alkylsulfanyl group, a     C1-C6 alkylsulfinyl group, or a C1-C6 alkylsulfonyl group, R³     represents a C1-C6 alkyl group optionally having one or more     substituents selected from Group B, or a hydrogen atom, and R^(4a),     R^(4b) and R^(4c) each represents a hydrogen atom. -   [Embodiment 169] The compound described in Embodiment 168 wherein A²     represents CH, A³ represents a nitrogen atom or CH, and A⁴     represents a nitrogen atom or CH. -   [Embodiment 170] The compound described in Embodiment 168 wherein A²     represents CH, A³ represents CH, and A⁴ represents a nitrogen atom. -   [Embodiment 171] The compound described in Embodiment 168 wherein A²     represents CH, A³ represents a nitrogen atom, and A⁴ represents CH. -   [Embodiment 172] The compound described in Embodiments 168 to 171     wherein R² represents an ethyl group, R^(W) represents a C1-C3 alkyl     group or a benzyl group, T^(W2) represents a halogen atom or a C1-C3     alkylsulfanyl group, and q is 0 or 1. -   [Embodiment 173] The compound described in Embodiments 168 to 171     wherein R² represents an ethyl group, R^(W) represents a C1-C3 alkyl     group or a benzyl group, T^(W2) represents a halogen atom, and q is     0 or 1.

Examples of the embodiment of the intermediate compound F include the following compounds.

-   [Embodiment 174] An intermediate compound F wherein A¹ represents a     nitrogen atom or CH, R² represents a C1-C6 alkyl group optionally     having one or more halogen atoms, n is 0 or 2, X^(L) represents a     halogen atom, a hydroxy group, a C1-C6 alkylsulfanyl group, a C1-C6     alkylsulfinyl group, a C1-C6 alkylsulfonyl group, R³ represents a     C1-C6 alkyl group optionally having one or more substituents     selected from Group B, a halogen atom or NR¹¹R¹¹, and R^(4a), R^(4b)     and R^(4c) each represents a hydrogen atom. -   [Embodiment 175] The compound described in Embodiment 175 wherein A²     represents CH, A³ represents a nitrogen atom or CH, and A⁴     represents a nitrogen atom or CH. -   [Embodiment 176] The compound described in Embodiment 174 wherein A²     represents CH, A³ represents CH, and A⁴ represents a nitrogen atom. -   [Embodiment 177] The compound described in Embodiment 174 wherein A²     represents CH, A³ represents a nitrogen atom, and A⁴ represents CH. -   [Embodiment 178] The compound described in Embodiments 174 to 177     wherein R² represents an ethyl group, X^(L) represents a halogen     atom, a C1-C3 alkylsulfanyl group or a C1-C3 alkylsulfonyl group,     and q is 0 or 1. -   [Embodiment 179] The compound described in Embodiments 174 to 177     wherein Q represents an oxygen atom. -   [Embodiment 180] The compound described in Embodiments 174 to 177     wherein R⁵ represents a C1-C6 chain hydrocarbon group {the C1-C6     chain hydrocarbon group have one or more substituents selected from     the group consisting of a halogen atom, a cyclopropyl group, a     phenyl group, and a cyclothiazolyl group} or a C3-C6 cycloalkyl     group.

Next, a process for preparing the compound Z of the present invention is explained.

Process 1

A compound represented by formula (Ib) (hereinafter, referred to as Compound (Ib)) or a compound represented by formula (Ic) (hereinafter, referred to as Compound (Ic)) may be prepared by oxidizing a compound represented by formula (Ia) (hereinafter, referred to as Compound (Ia)).

[wherein the symbols are the same as defined above]

First, a process for preparing the Compound (Ib) from the Compound (Ia) is described.

The reaction is usually carried out in a solvent.

Examples of the solvent to be used in the reaction include halogenated hydrocarbons such as dichloromethane and chloroform (hereinafter, collectively referred to as halogenated hydrocarbons); nitriles such as acetonitrile (hereinafter collectively referred to nitriles); alcohols such as methanol and ethanol (hereinafter, collectively referred to as alcohols); acetic acid; water; and mixed solvents thereof.

Examples of the oxidizing agent to be used in the reaction include sodium periodate, m-chloroperoxybenzoic acid (hereinafter, referred to as mCPBA) and hydrogen peroxide. When hydrogen peroxide is used as an oxidizing agent, sodium carbonate or a catalyst may be added as needed.

Examples of the catalyst to be used in the reaction include tungstic acid, and sodium tungstate.

In the reaction, the oxidizing agent is used usually within a range of 1 to 1.2 molar ratio(s), the base is used usually within a range of 0.01 to 1 molar ratio(s), and the catalyst is used usually within a range of 0.01 to 0.5 molar ratios, as opposed to 1 mole of the compound (Ia).

The reaction temperature of the reaction is usually within a range of −20 to 80° C. The reaction period of the reaction is usually within a range of 0.1 to 12 hours.

When the reaction is completed, water is added to reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and if necessary, the organic layers are washed with an aqueous solution of a reducing agent (such as sodium sulfite, and sodium thiosulfate) and an aqueous solution of a base (such as sodium hydrogen carbonate). The resulting organic layers are worked up (for example, drying and concentration) to give the compound (Ib).

Next, a process for preparing the compound (IC) from the compound (Ib) is described.

The reaction is usually carried out in a solvent. Examples of the solvent to be used in the reaction include halogenated hydrocarbons, nitriles, alcohols, acetic acid, water, and mixed solvents thereof.

Examples of the oxidizing agent to be used in the reaction include mCPBA and peroxide hydrogen. When peroxide hydrogen is used as an oxidizing agent, a base or a catalyst may be added as needed.

Examples of the base to be used in the reaction include sodium carbonate.

Examples of the catalyst to be used in the reaction include sodium tungstate.

In the reaction, the oxidizing agent is used usually within a range of 1 to 2 molar ratio(s), the base is used usually within a range of 0.01 to 1 molar ratio(s), and the catalyst is used usually within a range of 0.01 to 0.5 molar ratios, as opposed to 1 mole of the compound (Ib).

The reaction temperature of the reaction is usually within a range of −20 to 120° C. The reaction period of the reaction is usually within a range of 0.1 to 12 hours.

When the reaction is completed, water is added to reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and if necessary, the organic layers are washed with an aqueous solution of a reducing agent (such as sodium sulfite, and sodium thiosulfate) and an aqueous solution of a base (such as sodium hydrogen carbonate). The resulting organic layers are worked up (for example, drying and concentration) to give the compound (Ic).

Also, the compound (Ic) may be prepared by reacting the compound (Ia) with an oxidizing agent in one step (one pot).

The reaction may be carried out by using the oxidizing agent in a ratio of usually 2 to 5 molar ratios as opposed to 1 mole of the compound (Ia) according to the method for preparing the compound (Ic) from the compound (Ib).

Process 2

A compound represented by formula (Id-2) (hereinafter, referred to as Compound (Id-2)) may be prepared by reacting a compound represented by formula (M-2) (hereinafter, referred to as Compound (M-2)) and a compound represented by formula (R-1) (hereinafter, referred to as Compound (R-1)) in the presence of a base.

[wherein X^(b) represents a chlorine atom or a bromine atom, T¹ represents OR¹, NR¹R²⁹ a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, or a group represented by formula T-8, and the other symbols are the same as defined above.]

The reaction is usually carried out in the presence of a solvent. Examples of the solvents to be used in the reaction include ethers such as tetrahydrofuran (hereinafter, sometimes referred to as THF) and methyl tert-butyl ether (hereinafter, referred to as MTBE) (hereinafter, collectively referred to as ethers); aromatic hydrocarbons such as toluene and xylene (hereinafter, collectively referred to as aromatic hydrocarbons); nitriles; N-methyl pyrrolidone (hereinafter, referred to as NMP); and aprotic polar solvents such as dimethylformamide (hereinafter, referred to as DMF) and dimethyl sulfoxide (hereinafter, referred to DMSO) (hereinafter, collectively referred to as polar aprotic solvent); and mixed solvents thereof.

Examples of the base to be used in the reaction include alkali metal carbonates (such as potassium carbonate) (hereinafter, collectively referred to as alkali metal carbonates); and alkali metal hydrides such as sodium hydride (hereinafter, collectively referred to as alkali metal hydrides).

In the reaction, the compound (R-1) is used usually within a range of 1 to 2 molar ratio(s), and the base is used usually within a range of 1 to 10 molar ratio(s), as opposed to 1 mole of the compound (M-2)

The reaction temperature of the reaction is usually within a range of −20 to 150° C. The reaction period the reaction is usually within a range of 0.5 to 24 hours.

When the reaction is completed, water is added to reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and the organic layers are worked up (for example, drying and concentration) to give the compound (Id-2).

Process 3

A compound represented by formula (Id-4) maybe Prepared by reacting a compound represented by formula (M-3) (hereinafter, referred to as Compound (M-3)) with the compound (R-1) in the presence of a base.

-   [wherein the symbols are the same as defined above]

The reaction may be carried out according to the method described in Process 2.

Process 4

A compound represented by formula (Ie-2) (hereinafter, referred to Compound (Ie-2)) may be prepared by reacting the compound (M-2) with a compound represented by formula (R-2) (hereinafter, referred to Compound (R-2)) in the presence of a metal catalyst.

[wherein T² represents a group represented by formula T-1, a group represented by formula T-2, group represented by formula T-3, a group represented by formula T-4, a group represented by formula T-9, a group represented by formula T-10, a group represented by formula T-11, or a group represented by formula T-12, M represents 9-borabiclo[3,3,1]nonan-9-yl, a borono group, a 4,4,5,5,-tetramethyl-1,3,2-dioxaborolan-2-yl, a tributylstannyl group, ZnCl, MgCl, or MgBr; and the other symbols are the same as defined above]

The reaction is usually carried out in the presence of a solvent. Examples of the solvent to be used in the reaction include ethers, aromatic hydrocarbons, aprotic polar solvents, water, and mixed solvents thereof.

Examples of the metal catalyst to be used in the reaction include palladium catalysts such as tetrakis(triphenylphosphine)palladium(0), 1,1′-bis(diphenylphosphino)ferrocene palladium(II) dichloride, tris(dibenzylideneacetone)dipalladium(0), and palladium(II) acetate; nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel (II) chloride; and copper catalyst such as copper (I) iodide and copper(I) chloride.

A ligand, a base and/or an inorganic halogenated compound may be added to the reaction as needed.

Examples of the ligand to be used in the reaction include triphenylphosphine, Xantphos, 2,2′-bis(diphenylphoshino)-1,1′-binaphthyl, 1,1′-bis(diphenylphoshino)ferrocene, 2-dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl, 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2′-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, and 1,10-phenanthroline.

Examples of the base to be used in the reaction include alkali metal hydrides; alkali metal carbonates; and organic bases such as triethylamine, diisopropylethylamine, pyridine, and 4-(dimethylanino)pyridine.

Examples of the inorganic halogenated compounds include alkali metal fluorides such as potassium fluoride, and sodium fluoride; and alkali metal chlorides such as lithium chloride, and sodium chloride.

In the reaction, the compound (R-2) is usually used within a range of 1 to 10 molar ratio(s), the metal catalyst is usually used within a range of 0.01 to 0.5 molar ratios, the ligand is usually used within a range of 0.01 to 1 molar ratio(s), the base is usually used within a range of 0.1 to 1 molar ratio(s), and the inorganic halogenated compound is usually used within a range of 0.1 to 5 molar ratios, as opposed to 1 mole of the compound (M-2).

The reaction temperature is usually within a range of −20 to 200° C. The reaction period of the reaction is usually within a range of 0.1 to 24 hours.

When the reaction is completed, water is added to the reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and the organic solvents are worked up (for example, drying and concentration) to give the compound (Ie-2).

The compound (R-2) is a commercially available compound, or can be prepared by using a known method.

Process 5

A compound represented by formula (Ie-4) maybe prepared by reacting the compound (M-3) with the compound (R-2) in the presence of a metal catalyst.

[wherein the symbols are the same as defined above.]

The reaction may be carried out according to the method described in Process 4.

Process 6

A compound represented by formula (If-2) may be prepared by reacting a compound represented by formula (M-4) (hereinafter, referred to as Compound (M-4)) with a compound represented by formula (R-3) (hereinafter, referred to as Compound (R-3)) in the presence of a base.

[wherein X^(c) represents a chlorine atom, a bromine atom or an iodine atom, T³ represents a C1-C10 chain hydrocarbon group having one or more halogen atoms, a (C1-C5 alkoxy)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group having one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C3 alkyl group having one or more substituents selected from Group G, a C3-C7 cycloalkyl group having one or more substituents selected from Group G, or S(O)₂R¹, and the other symbols are the same as defined above.]

The reaction may be carried out by using the compound (M-4) in place of the compound (R-1), and the compound (R-3) in place of the compound (M-2) according to the method described in Process 2.

The compound (R-3) is a commercially available compound, or can be prepared by using a known method.

Process 7

A compound represented by formula (If-4) may be prepared by reacting a compound represented by formula (M-5) (hereinafter, referred to Compound (M-5)) with the compound (R-3) in the presence of a base.

[wherein the symbols are the same as defined above.]

The reaction may be carried out according to the method described in Process 6.

Process 8

A compound represented by formula (Ig-2) (hereinafter, referred to as Compound (Ig-2)) may be prepared by reacting the compound (M-2) with a compound represented by formula (R-4) (hereinafter, referred to as Compound (R-4)) in the presence of a copper.

[wherein, T⁴ represents a C1-C10 chain hydrocarbon group having one or more halogen atoms, a (C1-C5 alkoxy)C2-C5 alkyl group having one or more halogen atoms, (C1-C5 alkylsulfanyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group having one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C3 alkyl group having one or more substituents selected from Group G, or a C3-C7 cycloalkyl group having one or more substituents selected from Group G, and the other symbols are the same as defined above.]

The compound (R-4) is a commercially available compound, or can be prepared by using a known method.

The reaction is usually carried out in the presence of a solvent. Examples of the solvent to be used in the reaction include aromatic hydrocarbons, aprotic polar solvents, and mixed solvents thereof.

In the reaction, the compound (R-4) is usually used within a range of 1 to 10 molar ratio (s), and the copper is usually used within a range of 1 to 10 molar ratio(s), as opposed to 1 mole of the compound (M-2).

The reaction temperature is usually within a range of 40 to 200° C. The reaction period of the reaction is usually within a range of 0.1 to 24 hours.

When the reaction is completed, water is added to the reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and the organic solvents are worked up (for example, drying and concentration) to give the compound (Ig-2).

Process 9

The compound represented by formula (Ig-4) may be prepared by reacting the compound (M-3) with the compound (R-4) in the presence of a copper.

[wherein the symbols are the same as defined above.]

The reaction may be carried out according to the method described in Process 8.

Process 10

A compound represented by formula (Ih-2) (hereinafter, referred to Compound (Ih-2)) may be prepared by reacting the compound (M-2) with a compound represented by formula (R-5) (hereinafter, referred to as Compound (R-5)) in the presence of a base.

[wherein, R⁴⁰ represents a methoxy group, an ethoxy group, a phenoxy group, or N(CH₃)CH₃, and the other symbols are the same as defined above.]

The compound (R-5) is a commercially available compound, or can be prepared by using a known method.

The reaction is usually carried out in the presence of a solvent. Examples of the solvent to be used in the reaction include ethers, and aromatic hydrocarbons.

Examples of the base to be used in the reaction include butyl lithium, lithium diisopropylamide, lithium tetramethylpiperidide, lithium bis(trimethylsilyl)amide and the like.

In the reaction, the compound (R-5) is usually used within a range of 1 to 10 molar ratio(s), and the base is usually used within a range of 1.0 to 2.0 molar ratio(s), as opposed to 1 mole of the compound (M-2).

The reaction temperature is usually within a range of −100 to 60° C. The reaction period of the reaction is usually within a range of 0.1 to 24 hours.

When the reaction is completed, water is added to the reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and the organic solvents are worked up (for example, drying and concentration) to give the compound (Ih-2).

Process 11

A compound represented by formula (Ih-4) may be prepared by reacting the compound (M-3) with the compound (R-5) in the presence of a base.

[wherein the symbols are the same as defined above.]

The reaction may be carried out according to the method described in Process 10.

Process 12

A compound represented by formula (Ii-2) (hereinafter, referred to as Compound (Ii-2)) may be prepared by reacting compound represented by formula (M-6) (hereinafter, referred to as Compound (M-6)) with a compound represented by formula (R-6) (hereinafter, referred to as Compound (R-6)) in the presence of a condensing agent.

[wherein the symbols are the same as defined above.]

The compound (R-6) is a commercially available compound, or can be prepared by using a known method.

The reaction is usually carried out in a solvent. Examples of the solvent to be used in the reaction include ethers, halogenated hydrocarbons, aromatic hydrocarbons, aprotic polar solvents, and mixed solvents thereof.

Examples of the condensing agent to be used in the reaction include 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride and the like.

A base may be added to the reaction as needed, and examples of the bases include organic bases.

In the reaction, the compound (R-6) is used usually within a range of 1 to 10 molar ratio(s), the condensing agent is used usually within a range of 1 to 5 molar ration(s), and the base is used usually within a range of 0.1 to 10 molar ratios, as opposed to 1 mole of the compound (M-6).

The reaction temperature of the reaction is usually within a range of −20 to 120° C. The reaction period of the reaction is usually within a range of 0.1 to 24 hours.

When the reaction is completed, water is added to the reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and the organic solvents are worked up (for example, drying and concentration) to give the compound (Ii-2).

Process 13

A compound represented by formula (Ii-4) maybe prepared by reacting a compound represented by formula (M-7) (hereinafter, referred to as Compound (M-7)) with the compound (R-6) in the presence a condensing agent.

[wherein the symbols are the same as defined above.]

The reaction may be carried out according to the method described in Process 12.

Process 14

A compound represented by formula (Ij-2) (hereinafter, referred to as Compound (Ij-2)) may be prepared by reacting a compound represented by formula (M-8) (hereinafter, referred to as Compound (M-8)) with a compound represented by formula (R-7) (hereinafter, referred to as Compound (R-7)) in the presence of a base.

[wherein the symbols are the same as defined above.]

The compound (R-7) is a commercially available compound, or can be prepared by a known method.

The reaction is usually carried out in a solvent. Examples of the solvent to be used in the reaction include ethers, aromatic hydrocarbons, aprotic polar solvents, and mixed solvents thereof.

Examples of the base to be used in the reaction include organic bases, alkali metal hydrides, and alkali metal carbonates.

In the reaction, the compound (R-7) is used usually within a range of 1 to 10 molar ratio(s), and the base is used usually within a range of 0.1 to 5 molar ratios, as opposed to 1 mole of the compound (M-8).

The reaction temperature of the reaction is usually within a range of −20 to 120° C. The reaction period of the react usually within a range of 0.1 to 24 hours.

When the reaction is completed, water is added to the reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and the organic solvents are worked up (for example, drying and concentration) to give the compound (Ij2)

Process 15

A compound represented by formula (Ij-4) may be prepared by reacting a compound represented by formula (M-9) (hereinafter, referred to as Compound (M-9)) with the compound (R-7) in the presence of a base.

[wherein the symbols are the same as defined above.]

The reaction may be carried out according to the method described in Process 14.

Process 16

A compound represented by formula (Ik-2) (hereinafter, referred to as Compound (Ik-2)) may be prepared by reacting a compound represented by formula (M-10) (hereinafter, referred to as Compound (M-10)) with a compound represented by formula (R-8) (hereinafter, referred to as Compound (R-8)).

[wherein the symbols are the same as defined above.]

The compound (R-8) is a commercially available compound, or can be prepared by using a known method.

The reaction is usually carried out in the presence of a solvent. Examples of the solvent to be used in the reaction include ethers, halogenated hydrocarbons, aromatic hydrocarbons, aprotic polar solvents, and mixed solvents thereof.

An acid may be added to the reaction as needed, and examples of the acid include p-toluenesulfonic acid and 10-camphorsulfonic acid and the others.

In the reaction, the compound (R-8) is used usually within a range of 1 to 10 molar ratio(s), and the acid is used usually within a range of 0.1 to 10 molar ratios, as opposed to 1 mole of the compound (M-10).

The reaction temperature is usually within a range of −20 to 180° C. The reaction period of the reaction is usually within a range of 0.1 to 24 hours.

When the reaction is completed, water is added to the reaction mixtures, and the reaction mixtures are extracted with organic solvent (s), and the organic solvents are worked up (for example, drying and concentration) to give the compound (Ik-2).

Process 17

The compound (Ik-4) may be prepared by reacting compound represented by formula (M-11) (hereinafter, referred to as Compound (M-11)) with the compound (R-8).

[wherein the symbols are the same as defined above.]

The reaction may be carried out according to the method described in Process 16.

Process 18

A compound represented by formula (Im-2) (hereinafter, referred to as Compound (Im-2)) may be prepared by reaction a compound represented by formula (M-12) (hereinafter, referred to as Compound (M-12)) with a compound represented by formula (R-9) (hereinafter, referred to as Compound (R-9).

[wherein the symbols are the same as defined above.]

The compound (R-9) is a commercially available compound, or can be prepared by using a known method.

The reaction is usually carried out in the presence of a solvent. Examples of the solvent to be used in the reaction include ethers, halogenated hydrocarbons, aromatic hydrocarbons, aprotic polar solvents, and mixed solvents thereof.

A base may be added to the reaction as needed, and examples of the base include organic bases.

In the reaction, the compound (R-9) is used usually within a range of 1 to 10 molar ratio(s), and the base is used usually within a range of 0.1 to 10 molar ratios, as opposed to 1 mole of the compound (M-12).

The reaction temperature is usually within a range of −20 to 120° C. The reaction period of the reaction is usually within a range of 0.1 to 24 hours.

When the reaction is completed, water is added to the reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and the organic solvents are worked up (for example, drying and concentration) to give the compound (Im-2).

Process 19

The compound represented by formula (Im-4)) may be prepared by reacting a compound represented by formula (M-13) (hereinafter, referred to as Compound (M-13)) with the compound (R-9).

[wherein the symbols are the same as defined above.]The reaction nay be carried out according to the method described in Process 18.

Process 20

A compound represented by formula (In-2) (hereinafter, referred to as Compound (In-2)), a compound represented by formula (Io-2) (hereinafter, referred to as Compound (Io-2)) and a compound represented by formula (Ip-2) (hereinafter, referred to as Compound (Ip-2)) may be prepared according to the following method.

[wherein the symbols are the same as defined above.]

First, the process for preparing the compound (In-2) is described.

The compound (In-2)) may be prepared by using a compound represented by formula (M-14) (hereinafter, referred to as Compound (M-14)) in place of the compound (M-8) according to the method described in Process 14.

Next, the process for preparing the compound (Io-2) is described.

The compound (Io-2) can be prepared by using the compound (In-2) in place of the compound (Ia) according to the method described in Process 1.

Next, the process for preparing the compound (Ip-2) is described.

The compound (Ip-2) can be prepared by using the compound (Io -2) in place of the compound (Ib) according to the method described in Process 1.

Process 21

A compound represented by formula (In-4) (hereinafter, referred to as Compound (In-4)), a compound represented by formula (Io-4) (hereinafter, referred to as Compound (Io-4)), and a compound represented by formula (Ip-4) (hereinafter referred to as Compound (Ip-4)) can be prepared according to the following method.

[wherein the symbols are the same as defined above.]

The reaction may be carried out according to the method described in Process 20.

Process 22

A compound represented by formula (Iq) (hereinafter, referred to as Compound (Iq)) and a compound represented by formula (Ir) (hereinafter, referred to as Compound (Ir)) may he prepared according to the following scheme.

[wherein Q³ represents N—CN, N—NO₂, NR⁵, N—C(O)R⁵ or N—C(O)OR¹⁵, and the other symbols are the same as defined above.]

The compound (Iq) may be prepared by using the compound (Ia) according to the method described in Organic Letters, 9(19), 3809, 2007.

The compound (Ir) may be prepared by using the compound (Iq) according to the method described in Process 1 for preparing the compound (Ib) from the compound (Ia).

Process 23

A compound represented by formula (Is) (hereinafter, referred to as Compound (Is)) and a compound represented by formula (It) (hereinafter, referred to as Compound (It)) may be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

The compound (Is) may be prepared by using the compound (Ia), or the compound (It) may be prepared by using the compound (Is), each according to the method described in Russian Journal of Organic Chemistry, Vol, No. 5, 778-779, 2013.

Process 24

A compound represented by formula (Iu-2) (hereinafter, referred to as Compound (Iu-2)) may be prepared by reacting a compound represented by formula (M-25) (hereinafter, referred to as Compound (M-25)) with trifluoroacetic anhydride in the presence of organic bases. Also, the compound (Iu-2) may be prepared by reacting the compound (M-25) with acetic anhydride, followed by reacting with methanol.

[wherein, R⁵³ represents a C1-C6 alkyl group optionally having one or more substituents selected from Group B, a C3-C7 cycloalkyl group optionally having one or more substituents selected from Group E, a phenyl group optionally having one or more substituents selected from Group H, or a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group H, and the other symbols are the same as defined above.]

The reaction may be carried out according to the method described in WO 2009/076387.

Process 25

A compound represented by formula (Iv-2) may be prepared by reacting the compound (Iu-2) with a compound represented by formula (R-20) (hereinafter, referred to as Compound (R-20)) in the presence of a base.

[wherein the symbols are the same as defined above.]

The reaction may be carried out by using the compound (Iu-2) in place of the compound (M-4) and using the compound (R-20) in place of the compound (R-3) according to the method described in Process 6.

The compound (R-20) is a commercially available compound, or can be prepared by using a known method.

Process 26

A compound presented by formula (Iw-2) can be prepared by reacting a compound represented by formula (Iv-2-1) (hereinafter, referred to as Compound (Iv-2-1)) and a compound represented by formula (R-21) (hereinafter, referred to as Compound (R-21)) in the presence of metal catalyst.

[where, R⁵⁵ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group B, a C3-C7 cycloalkyl group optionally having one or more substituents selected from Group E, a phenyl group optionally having one or more substituents selected from Group H, or a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group H, and the other symbols are the same as defined above.]

The reaction may be carried out by using the compound (Iv-2-1) in place of the compound (M-2) and using the compound (R-21) in place of the compound (R-2) according to the method described in Process 4.

The compound (R-21) is a commercially available compound, or can be prepared by using a known method.

Process 27

A compound represented by formula (Iu-4) (hereinafter, referred to as Compound (Iu-4)) may be prepared by reacting a compound represented by formula (M-29) (hereinafter, referred to as Compound (M-29)) with trifluroacetic anhydride in the presence of organic bases. Also, the compound (Iu-4) may be prepared by reacting the compound (M-29) with acetic anhydride, followed by reacting with methanol.

[wherein the symbols are the same as defined above.]

The reaction may be carried out according to the method described in WO 2009/076387.

Process 28

A compound represented by formula (Iv-4) may be prepared by reacting the compound (Iu-4) with the compound (R-20) in the presence of a base.

[wherein the symbols are the same as defined above.]

The reaction may be carried out by using the compound (Iu-4) in place of the compound (M-4) and using the compound. (R-20) in place of the compound (R-3) according to the method described in Process 6.

Process 29

A compound represented by formula (Iw-4) ray be prepared by reacting a compound represented by formula (Iv-4-1) (hereinafter, referred to as Compound (Iv-4-1)) with the compound (R-21) in the presence of a metal catalyst.

[wherein the symbols are the same as defined above.]

The reaction may be carried out by using the compound (Iv-4-1) in place of the compound (M-2) and using the compound (R-21) in place of the compound (R-2) according to the method described Process 4.

Process 30

The compound may be prepared by reacting a compound represented by formula (M-30) (hereinafter, referred to as Compound (M-30)) with a compound represented by formula (R-16) (hereinafter, referred to as Compound (R-16)) in the presence of a base.

[wherein x^(a) represents a fluorine atom or a chlorine atom, and the other symbols are the same as defined above.]

The reaction may be carried out by using the compound (M-30) in place of the compound (M-2) and using the compound (R-16) in place of the compound (R-1) according to the method described in Process 2.

The compound (R-16) is a commercially available compound, or can be prepared by using a known method.

Process 31

A compound represented by formula (Ix-2) (hereinafter, referred to as Compound (Ix-2)) may be prepared by reacting a compound represented by formula (M-31) (hereinafter, referred to as Compound (M-31)) with a compound represented by formula (M-1) (hereinafter, referred to as Compound (M-1)) in the presence of a metal catalyst.

[wherein the symbols are the same as defined above.]

The reaction may be carried out by using the compound (M-31) in place of the compound (R-2) and using the compound (M-1) in place of the compound (M-2) according to the method described in Process 4.

The compound (M-31) can be prepared by using the method described in the reference process 31 or a known method.

Process 32

A compound represented by formula (4) (hereinafter, referred to as Compound (Ix-4)) may be prepared by reacting a compound represented by formula (M-32) (hereinafter, referred to as Compound (M-32)) with the compound (M-1) in the presence of a metal catalyst.

[wherein the symbols are the same as defined above.]

The reaction may be carried out by using the compound (M-32) in place of the compound (R-2) and using the compound (M-1) in place of the compound (M-2) according to the method described in Process 4.

The compound (M-32) can be prepared by using the method described in the reference process 32 or a known method,

Process 33

The compound (Id-2) may be prepared by reacting a compound represented by formula (M-43) (hereinafter, referred to as Compound (M-43)) with the compound (R-1) in the presence of a base.

[wherein the symbols are the same as defined above.]

The reaction may be carried out by using the compound (M-43) in place of the compound (M-2) according to the method described in Process 2.

Process 34

The compound (Id-4) may be prepared by reacting a compound represented by formula (M-46) (hereinafter, referred to as Compound (M-46)) with the compound (R-1) in the presence of a base.

[wherein the symbols are the same as defined above.]

The reaction may be carried out by using the compound (M46) in place of the compound (M-2) according to the method described in Process 1.

Reference Process 1

The compound (M-2) May be prepared by reacting a compound represented by formula (M-2c) (hereinafter, referred to as Compound (M-2c)) with compound represented by formula (R-10) (hereinafter, referred to as Compound (R-10)) in the presence of a base.

[wherein the symbols are the same as defined above.]

The reaction may be carried out by using the compound (R-10) in place of the compound (M-2) and using the compound (M-2c) in place of the compound (R-1) according to the method described in Process 2.

The compound (R-10) is a commercially available compound, or can be prepared by using a known method.

Reference Process 2

The compound (M-2c) may be prepared according to the following scheme.

[wherein, R⁵¹ represents a methyl group, an ethyl group, or a benzyl group, and the other symbols are the same as defined above.]

A compound represented by formula (M-2b) (hereinafter, referred to as Compound (M-2b)) may be prepared by reacting a compound represented by formula (M-2a) (hereinafter, referred to as Compound (M-2a)) with a compound represented by formula (R-11) (hereinafter, referred to as Compound (R-11) in the presence of a base. The reaction may be carried out according to method described in Process 2.

The compound (M-2c) may be prepared by reacting the compound (M-2b) with an acid. The reaction may be carried out according to the method described in, for example, WO 2016/052455.

The compound (R-11) is a commercially available compound, or can be prepared by using a known method.

Reference Process 3

The compound (M-2a) may be prepared by reacting a compound represented by formula (R-12) (hereinafter, referred to as Compound (R-12)) with the compound (M-1) in the presence of a metal catalyst.

[wherein the symbols are the same as defined above.]

The reaction may be carried out by using the compound (M-1) in place of the compound (M-2) and using the compound (R-12) in place of the compound (R-2) according to the method described in Process 4.

The compound (R-12) is a commercially available compound, or can be prepared by using known method.

Reference Process 4

The compound (M-3) may be prepared by reacting a compound represented by formula (M-3c) (hereinafter, referred to as Compound (M-3c)) with the compound (R-10) in the presence of a base.

[wherein the symbols are the same as defined.]

The reaction may be carried out according to the method described in Reference Process 1.

Reference Process 5

The compound (M-3c) may be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

These reactions may be carried out according to the methods described in Reference Process 2.

Reference Process 6

A compound represented by formula (M-3a) maybe prepared by reacting a compound represented by formula (R-13) (hereinafter, referred to as Compound (R-13)) with the compound (M-1) in the presence of a metal catalyst.

[wherein the symbols are the same as defined above.]

The reaction may be carried out according to the method described in Reference Process 3.

The compound (R-13) is a commercially available compound, or can be prepared by using a known method.

Reference Process 7

The compound (M-4) may be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

These reactions may be carried out according to the methods described in Reference Process 2.

Reference Process 8

The compound (M-5) may be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

These reactions may be carried out according to the methods described in Reference Process 2.

Reference Process 9

The compound (M-6) may be prepared by reacting the compound (M-2) with dry ice in the presence of a base.

[wherein the symbols are the same as defined above.]

The reaction may be carried out by using dry ice in place of the compound (R-5) according to the method described in Process 10.

Reference Process 10

The compound (M-7) may be prepared by reacting the compound (M-3) with dry ice in the presence of a base.

[wherein the symbols are the same as defined above.]

The reaction may be carried out by using dry ice in place of the compound (R-5) according to the method described in Process 10.

Reference Process 11

The compound (M-3) may be prepared by reacting the compound (M-6) with a reducing agent.

[wherein the symbols are the same as defined above.]

The reaction is usually carried out in a solvent.

Examples of the solvent to be used in the reaction include ethers, aliphatic hydrocarbons, aromatic hydrocarbons, alcohols, and mixed solvents thereof.

Examples of the reducing agent to be used in the reaction include sodium borohydride, lithium borohydride, lithium aluminium hydride, diisobutylaluminum hydride, and the others.

In the reaction, the reducing agent is used usually within a range of 1 to 5 molar ratio(s), as opposed to 1 mole of the compound (M-6).

The reaction temperature of the reaction is usually within a range of −20 to 120° C. The reaction period of the reaction is usually within a range of 0.1 to 24 hours.

When the reaction is completed, water is added to the reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and the organic solvents are worked up (for example, drying and concentration) to give the compound (M-8).

Reference Process 12

The compound (M-9) may be prepared by reacting the compound (M-7) with a reducing agent.

[wherein the symbols are the same as defined above.]

These reactions may be carried out according to the methods described in Reference Process 11.

Reference Process 13

The compound (M-10) may be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

A compound represented by formula (M-10a) (hereinafter, referred to as compound (M-10a)) may be prepared by using the compound (M-2) in place of the compound (M-2a) and using p-methoxybenzylamine to in place of the compound (R-11) according to the method described in Reference Process 2.

The compound (M-10) may be prepared by using the compound (M-10a)in place of the compound (M-2b) according to the method described in Reference Process 2.

Reference Process 14

The compound (M-11) may be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

These reactions may be carried out according to the methods described in Reference Process 13.

Reference Process 15

The compound (M-12) may be prepared by reacting the compound (M-2) with a compound represented by formula (R-14) (hereinafter, referred to as Compound (R-14)) in the presence of a base.

[wherein the symbols are the same as defined above.]

The compound (R-14) is a commercially available compound, or can be prepared by using a known method.

The reaction is usually carried out in a solvent.

Examples of the solvent to be used in the reaction include ethers, aromatic hydrocarbons, polar aprotic solvent, and mixed solvents thereof.

Examples of the palladium catalyst include aryl palladium (II) chloride.

In the reaction, phenol as the additive, and potassium tert-butoxide as the base are used.

In the reaction, the compound (R-14) is usually used within a range of 1 to 10 molar ratio(s), the palladium catalyst is usually used within a range of 0.01 to 1 molar ratio(s), phenol is usually used within a range of 1 to 5 molar ratio(s) and potassium tert-butoxide is usually used within a range of 0.1 to 10 molar ratios, as opposed to 1 mole of the compound (M-2).

The reaction temperature of the reaction is usually within a range of 40 to 180° C. The reaction period of the reaction is usually within a range of 0.1 to 24 hours.

When the reaction is completed, water is added to reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and the organic layers are worked up (for example, drying and concentration) to give the compound (M-12).

Reference Process 16

The compound (M-13) may be prepared by reacting the compound (M-3) with the compound (R-14) in the presence of a base.

[wherein the symbols are the same as defined above.]

The reaction may be carried out according to the method described in Reference process 15.

Reference Process 17

The compound (M-14) may be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

First, a process for preparing a compound represented by formula (M-14a) (hereinafter, referred to as Compound (M-14a)) is described.

The compound (M-14a) may be prepared by reacting the compound (M-2) with thiobenzoic acid in the presence of a copper catalyst and a base.

The reaction is usually carried out in the presence of a solvent. Examples of the solvent to be used in the reaction include ethers, aromatic hydrocarbons, aprotic polar solvents, water, and mixed solvents thereof.

Examples of the copper catalyst to be used in the reaction include copper chloride, copper bromide, and copper iodide.

Examples of the base to be used in the reaction include alkali metal hydrides, alkali metal carbonates, and organic bases.

A ligand may be added to the reaction as needed. Examples of the ligand to be used in the reaction include 2,2′-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, and the others.

In the reaction, thiobenzoic acid is usually used within a range of 1 to 10 molar ratio(s), the copper catalyst is usually used within a range of 0.01 to 0.5 molar ratios, the ligand is usually used within a range of 0.01 to 1 molar ratio(s), and the base is usually used with a range of 0.1 to 5 molar ratios, as opposed to 1 mole of the compound (M-2)

The reaction temperature is usually within a range of −20 to 200° C. The reaction period of the reaction is usually within a range of 0.1 to 24 hours.

When the reaction is completed, water is added to reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and the organic layers are worked up (for example, drying and concentration) to give the compound (M-14a).

Next, the process for preparing the compound (M-14) is described.

The compound (M-14) may be prepared, for example, according to the method described WO 2011/068171 or the method described in Journal of Organic Chemistry, 1978, 43(6), 1190-1192.

Reference Process 18

The compound (M-15) may be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

These reactions may be carried out according to the methods described in Reference Process 17.

Reference Process 19

A compound represented by formula (M-1b) and a compound represented by formula (M-1c) may be prepared by oxidizing a compound represented by formula (M-1a) (hereinafter, referred to as Compound (M-1a)).

[wherein the symbols are the same as defined above.]

These reactions may be carried out according to the methods described in Process 1.

Reference Process 20

The compound (M-1a) may be prepared by reacting a compound represented by formula (R-15) (hereinafter, referred to as Compound (R-15)) with the compound (R-16) in the presence of a base.

[wherein the symbols are the same as defined above.]

The reaction may be carried out according to the method described in Process 2.

The compound (R-15) is commercially available compounds, or can be prepared by using a known method.

Reference Process 21

A compound represented by formula (M-2b-1) (hereinafter, referred to as Compound (M-2b-1)) may be prepared according to the following scheme.

[wherein R⁵⁰ represents a methyl group or an ethyl group, R⁵² and R⁵⁴ are identical to or different from each other and each represents independently a C1-C6 alkyl group, X^(d) represents a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, BF₄, or PF₆, and the other symbols are the same as defined above. ]

A compound represented by formula (M-17) (hereinafter, referred to as Compound (M-17)) may be prepared by reacting a compound represented by formula (M-16) (hereinafter, referred to as Compound (M-16)) with a compound represented by formula (R-17) (hereinafter, referred to as Compound (R-17)) in the presence of a base.

The reaction is usually carried out in the presence of a solvent. Examples of the solvent to be used in the reaction include alcohols, ethers, aromatic hydrocarbons, aprotic polar solvents, and mixed solvents thereof.

Examples of the base to be used in the reaction include n-butyl lithium, s-butyl lithium, t-butyl lithium, lithium diisopropylamide, lithium bis(trimethylsilyl)amide, sodium bis(trimethylsilyl)amide, potassium bis(trimethylsilyl)amide, potassium t-butoxide, sodium methoxide, sodium ethoxide, and alkali metal hydrides.

In the reaction, the compound (R-17) is usually used within a range of 1 to 5 molar ratio(s), and the base is usually used within a range of 1 to 5 molar ratio(s), as opposed to 1 mole of the compound (M-16). Preferably, the compound (R-17) is used within a range of 1.0 to 1.1 molar ratio(s), and the base is used within a range of 1 to 2 molar ratio(s), as opposed to 1 mole of the compound (M-16).

The reaction temperature of the reaction is usually within a range of −78 to 100° C. The reaction period of the reaction is usually within a range of 0.5 to 12 hours.

When the reaction is completed, water is added to reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and the organic layers are worked up (for example, drying and concentration) to give the compound (M-17).

The compound (M-16) is a commercially available compound, or can be prepared by using a known method.

The compound (R-17) is a commercially available compound, or can be prepared by using the method described in Journal of Molecular Catalysis A: Chemical, 2011, 341(1-2), 57.

The compound (M-2b-1) may be prepared by reacting the compound (M-17) with a compound represented by formula (R-18) (hereinafter, referred to as Compound (R-18)), followed by reacting with ammonia.

The step 1 in which the compound (M-17) is reacted with the compound (R-18) is described.

The reaction is usually carried out in a solvent.

Examples of the solvent to be used in the reaction include ethers; aromatic hydrocarbons; halogenated hydrocarbons (such as dichloromethane and chloroform) (hereinafter, collectively referred to as aliphatic hydrocarbons); alcohols; esters; nitriles; aprotic polar solvents; nitrogen-containing aromatic compounds such as pyridine and 2,6-lutidine (hereinafter, collectively referred to as nitrogen-containing aromatic compounds); and mixed solvents thereof.

A base may be used in the reaction, and examples of the base include alkali metal carbonates, alkali metal hydrides, and organic bases.

When a base is used in the reaction, the base is usually used within a range of 1 to 10 molar ratio(s), as opposed to 1 mole of the compound (M-17).

In the reaction, the compound (R-18) is usually used within a range of 1 to 10 molar ratio(s), as opposed to 1 mole of the compound (M-17).

The reaction temperature of the reaction is usually within a range of −50 to 200° C. The reaction period of the reaction is usually within a range of 0.1 to 24 hours.

When the reaction is completed, the reaction mixtures are concentrated to obtain the residues and then the residues are used as itself in the second step, or alternatively, water is added to the reaction mixtures and the mixtures are extracted with organic solvents(s), and the organic layers are worked up (for example, drying and concentration) to obtain the residues, and then the residues may be used as itself in the second step.

Next, the step 2 in which the residues obtained in the step 1 is reacted with ammonia to obtain the compound (M-2b-1) is described.

The reaction is usually carried out in the presence of a solvent. Examples of the solvents to be used in the reaction include ethers, nitriles, alcohols, aprotic polar solvents, nitrogen-containing aromatic compounds, and mixed solvents thereof.

Ammonia to be used in the reaction may be used as an aqueous solution or an alcoholic solution thereof.

In the reaction, ammonia is usually used within a range of 1 to 100 molar ratio(s), as opposed to 1 mole of the compound (M-17) used in the step 1.

The reaction temperature of the reaction is usually within a range of 0 to 100° C. The reaction period of the reaction is usually within a range of 0.1 to 24 hours.

When the reaction is completed, water is added to reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and the organic layers are worked up (for example, drying and concentration) to give the compound (M-2b-1).

The compound (R-18) may be prepared according to the method described in WO 2009/054742.

Reference Process 29

A compound represented by formula (M-2b-2) (hereinafter, referred to Compound (M-2b-2)) may be prepared according to the following scheme.

[wherein X^(e) represents a chlorine atom, a bromine atom, an iodine atom, a methyl group, a nitro group, or a trifluoromethyl group, and the other symbols are the same as defined above.]

A compound represented by formula (M-20) (hereinafter, referred to as Compound (M-20)) may be prepared by reacting the compound (M-17) with ammonia.

The reaction is usually carried out in the presence of a solvent. Examples of the solvents to be used in the reaction include ethers, aromatic hydrocarbons, nitriles, alcohols, aprotic polar solvents, water, and mixed solvents thereof.

Ammonia to be used in the reaction may be used as ammoia gas, or may be used as an aqueous solution or an alcoholic solution thereof. Also, ammonium salts including ammonium carboxylate such as ammonium acetate; ammonium phosphate such as ammonium dihydrogen phosphate; ammonium carbonate; and ammonium chloride may be used.

In the reaction, ammonia is usually used within a range of 0.1 to 100 molar ratios, as opposed to 1 mole of the compound (M-17).

The reaction temperature of the reaction is usually within a range of 0 to 200° C. The reaction period of the reaction is usually within a range of 0.5 to 24 hours.

When the reaction is completed, water is added to reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and the organic layers are worked up (for example, drying and concentration) to give the compound (M-20).

The compound (M-2b-2) may be prepared by reacting the compound (M-20) with a compound represented by formula (R-19) (hereinafter, referred to as Compound (R-19)).

The reaction is usually carried out in the presence of a solvent. Examples of the solvents to be used in the reaction include ethers, aromatic hydrocarbons, halogenated hydrocarbons, alcohols, esters, nitriles, aprotic polar solvents, nitrogen-containing aromatic compounds, and mixed solvents thereof.

A base may be used in the reaction, and examples of the base include alkali metal carbonates, alkali metal hydrides, and organic bases.

When a base may be used in the reaction, the base is usually used within a range of 1 to 10 molar ratio(s), as opposed to 1 mole of the compound (M-20).

In the reaction, the compound (R-19) is usually used within a range of 1 to 10 molar ratio(s), as opposed to 1 mole of the compound (M-20).

The reaction temperature of the reaction is usually within a range of −50 to 200° C. The reaction period of the reaction is usually within a range of 0.1 to 24 hours.

When the reaction is completed, water is added to reaction mixtures, and the reaction mixtures are extracted with organic solvent(s), and the organic layers are worked up (for example, drying and concentration) to give the compound (M-2b-2).

The compound (R-19) may be prepared according to the method described in Organic Process Research & Development, 2005, 9, 141, or The Journal of Organic Chemistry 2000, 65, 4571-4574.

Reference process 23

A compound represented by formula (M-3b-1) (hereinafter, referred to as Compound (M-3b-1)) may be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

These reactions may be carried out by using the compound (M-18) in place of the compound (M-16) according to the methods described in Reference Process 21.

Reference process 24

A compound represented by formula (M-3b-2) (hereinafter, referred to as Compound (M-3b-2)) may be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

These reactions may be carried out by using the compound (M-19) in place of the compound (M-17) according to the methods described in Reference Process 22.

Reference Process 25

A compound represented by formula (M-22) (hereinafter, referred to as Compound (M-22)) may be prepared by reacting the compound (M-17) with the compound (R-18), followed by reacting with hydroxyl amine.

[wherein the symbols are the same as defined above.]

The reaction may be carried out by using hydroxyl amine in place of ammonia according to the method described in Reference Process 21 for preparing the compound (M-2b-1) from the compound (M-17).

Reference Process 26

The compound (M-25) may be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

A compound represented by formula (M-23) (hereinafter, referred to as Compound (M-23)) may be prepared by using the compound (M-22) in place of the compound (M-2b) according to the method described in Reference Process 2.

A compound represented by formula (M-24) (hereinafter, referred to as Compound (M-24)) may be prepared by using the compound (M-23) in place of the compound (M-2c) according to the method described in Reference Process 2.

The compound (M-25) may be prepared by using the compound (M-24) in place of the compound (M-2) according to the method described in Process 2.

Reference Process 27

A compound represented by formula (M-26) (hereinafter, referred to as Compound (M-26)) may be prepared by reacting the compound (M-19) with the compound (M-18), followed by reacting with hydroxyl amine.

[wherein the symbols are the same as defined above.]

The reaction may be carried out by using the compound (M-19) in place of the compound (M-16) and using hydroxyl amine in place of ammonia, according to the method described in Reference Process 21 for preparing the compound (M-2b-1) from the compound (M-17).

Reference Process 28

The compound (M-29) may be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

A compound represented by formula (M-27) (hereinafter, referred to as Compound (M-27)) may be prepared by using the compound (M-26) in place of the compound (M-2b) according to the method described in Reference Process 2.

A compound represented by formula (M-28) (hereinafter, referred to as Compound (M-28)) may be prepared by using the compound (M-27) in place of the compound (M-2c) according to the method described in Reference Process 2.

A compound represented by formula (M-29) maybe prepared by using the compound (M-28) in place of the compound (M-2) according to the method described in Process 2.

Reference Process 29

Among the compound (M-30), a compound represented by formula (M-33) wherein Het represents a group represented by formula Het 1 can be prepared by reacting the compound (M-31) and the compound (R-15).

[wherein the symbols are the same as defined above.]

The reaction may be carried out by using the compound (M-31) in place of the compound (R-2) and using the compound (R-15) in place of the compound (M-2) according to the method described in the Process 4.

Reference Process 30

Among the compound (M-30), a compound represented by formula (M-34) wherein Het represents a group represented by formula Het 2 can be prepared by reacting the compound (M-32) and the compound (R-15).

[wherein the symbols are the same as defined above.]

The reaction may be carried out by using the compound (M-32) in place of the compound (R-2) and using the compound (R-15)in place of the compound (M-2) according to the method described in the Process 4.

Reference Process 31

A compound represented by formula (M-37) (hereinafter, referred to as Compound (M-37)) can be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

A compound represented by formula (M-36) (hereinafter, referred to as Compound (M-36)) can be prepared by reacting a compound represented by formula (M-35) (hereinafter, referred to as Compound (M-35)) and the compound (R-1). The reaction can be carried out by using the compound (M-35) in place of the compound (M-2) according to the method described in the Process 2.

The compound (M-37) can be prepared by reacting the compound (M-36and bis(pinacolato)diboron in the presence of a palladium catalyst and a base. The reaction can be carried out, for example, according the method described in Journal of Organic Chemistry, 1995, (60), 7508-7510.

The compound (M-35) is a commercially available compound, or can be prepared by using a known method.

Reference Process 32

A compound represented by formula (M-40) (hereinafter, referred to as Compound (M-40)) can be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

A compound represented by formula (M-39) (hereinafter, referred to as Compound (M-39)) can be prepared by reacting a compound represented by formula (M-38) (hereinafter, referred to as Compound (M-38)) and the compound (R-1). The reaction can be carried out by using the compound (M-38) in place of the compound (M-2) according to the method described in the Process 2.

The compound (M-40) can be prepared by reacting the compound (M-39) and bis(pinacolato)diboron in the presence of a palladium catalyst and a base. The reaction can be carried out, for example, according the method described in Journal of Organic Chemistry, 1995, (60), 7508-7510.

The compound (M-38) is a commercially available compound, or can be prepared by using a known method.

Reference Process 33

A compound represented by formula (M-41) (hereinafter, referred to as Compound (M-41)), a compound represented by formula (M-42) (hereinafter, referred to as Compound (M-42)), and the compound (M-43) can be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

The reaction can be carried out according to the method described in the Process 20.

The compound (R-22) is a commercially available compound, or can be prepared by using a known method.

Reference Process 34

A compound represented by formula (M-44) (hereinafter, referred to as Compound (M-44)), a compound represented by formula (M-45) (hereinafter, referred to as Compound (M-45)), and the compound (M-46) can be prepared according to the following scheme.

[wherein the symbols are the same as defined above.]

The reaction can be carried out according to the method described in the Process 20.

Examples of the embodiment of the compound (M-36) include the following compounds.

Reference Process 35

The compound (M-41) can be prepared by reacting the compound (M-2) and the compound (R-16) in the presence of a base.

[wherein the symbols are the same as defined above.]

The reaction can be carried out by using the compound (R-16) in place of the compound (R-1) according to the method described in the process 2.

Reference Process 36

The compound (M-44) can be Prepared by reacting the compound (M-3) and the compound (R-16) in the presence of a base.

[wherein the symbols are the dame as defined above.]

The reaction can be carried out by using the compound (R-16) in place of the compound (R-1) according to the method described in the process 2.

-   [Embodiment M1] The compound (M-36) wherein A² represents a nitrogen     atom or CH, A³ represent a nitrogen atom or CH, R⁵ represents a     C1-C3 alky group, and T¹ represents a C2-C6 alkoxy group having one     or more halogen atoms. -   [Embodiment M2] The compound according to the embodiment M1 wherein     A² represents CH, and A³ represents CH. -   [Embodiment M3] The compound according to the embodiment M1 wherein     A² represents CH, and A³ represent, a nitrogen atom.

Examples of the embodiment of the compound (M-39) include the following compounds.

-   [Embodiment M4] The compound (M-39) wherein A² represents a nitrogen     atom or CH, A⁴ represents a nitrogen atom or CH, R⁵ represents a     C1-C3 alkyl group, and T¹ represents a C2-C6 alkoxy group having one     or more halogen atoms. -   [Embodiment M5] The compound according to the embodiment M4 wherein     A² represents CH, and A⁴ represents CH. -   [Embodiment M6] The compound according to the embodiment M4 wherein     A² represents CH, and A⁴ represents a nitrogen atom.

Examples of the embodiment of the compound (M-31) includes the following compounds.

-   [Embodiment M7] The compound (M-31) wherein A² represents a nitrogen     atom or CH, A³ represents a nitrogen atom or CH, R⁵ represents a     C1-C3 alkyl group, and T represents a C2-C6 alkoxy group having one     or more halogen atoms. -   [Embodiment M8] The compound according to the embodiment M7 wherein     A² represents CH, and A³ represents CH. -   [Embodiment M9] The compound according to the embodiment M7 wherein     A² represents CH, and A³ represents a nitrogen atom. -   [Embodiment M10] The compound according to the embodiment M7 wherein     M represents a 9-borabicyclo[3,3,1]nonan-9-yl, a borono group, a     4,4,5,5,-tetramethyl-1,3,2-dioxaborolan-2-yl, or a tributylstannyl     group.

Examples of the embodiment of the compound (M-32) include the following compounds.

-   [Embodiment M11] The compound (M-32) wherein A² represents a     nitrogen atom or CH, A⁴ represents a nitrogen atom or CH, R⁵     represents a C1-C3 alkyl group, and T represents a C2-C6 alkoxy     group having one or more halogen atoms. -   [Embodiment M12] The compound according to the embodiment M11     wherein A² represents CH, and A⁴ represents CH. -   [Embodiment. M13] The compound according to the embodiment M11     wherein A² represents CH, and A⁴ represents a nitrogen atom. -   [Embodiment M14] The compound according to the embodiment M11     wherein M represents a 9-borabiclo[3,3,1]nonan-9-yl, a borono group,     a 4,4,5,5,-tetramethyl-1,3,2-dioxaborolan-2-yl, or a tributylstannyl     group.

Next, specific examples of the compound Z of the present invention are indicated below.

Herein, Me represents a methyl group, Et represents an ethyl group, Pr represents a propyl group, i-Pr represents an isopropyl group, Bu represents a butyl group, c-Pr represents a cyclopropyl group, 1-CN-c-Pr represents a 1-cyano-cyclopropyl group, Ph represents a phenyl group, Py2 represents a 2-pyridyl group, Py3 represents a 3-pyridyl group, Py4 represents a 4-pyridyl group, and Bn represents a benzyl group. When the Ph, Py2, Py3, and Py4 have any substituent(s), the substituent(s) is described together with a substitution position before the symbol. For example, 4-CF₃-Py2 represents a 4-(trifluoromethyl)-2-pyridyl group, and 3,5-(CF₃)₂-Ph represents a 3,5-bis(trifluoromethyl) phenyl group.

A compound represented by formula (L-1):

(hereinafter, referred to as Compound (L-1)) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁).

TABLE 1 CF₃ CHF₂ CH₂CF₃ CF₂CF₃ CH₂CF₂CF₃ CF₂CF₂CF₃ CF₂CF₂CF₂CF₃ CF₂CF₂CF₂CF₂CF₃ OCF₃ OCHF₂ OCH₂CF₃ OCH₂CHF₂ OCF₂CF₃ OCH(CH₃)CF₃ OCH₂CF₂CHF₂ OCH₂CF₂CF₃ OCF₂CF₂CF₃ OCH₂CF₂CHFCF₃ OCH₂CF₂CF₂CF₃ OCF₂CF₂CF₂CF₃ OCH₂CF₂CF₂CF₂CF₃ OCH₂CMe₂CN

TABLE 2 SCF₃ SCH₂CF₃ SCF₂CF₃ SCH₂CF₂CF₃ SCF₂CF₂CF₃ SCH₂CF₂CF₂CF₃ SCF₂CF₂CF₂CF₃ S(O)CF₃ S(O)CH₂CF₃ S(O)CF₂CF₃ S(O)CH₂CF₂CF₃ S(O)CF₂CF₂CF₃ S(O)CH₂CF₂CF₂CF₃ S(O)CF₂CF₂CF₂CF₃ S(O)₂CF₃ S(O)₂CH₂CF₃ S(O)₂CF₂CF₃ S(O)₂CH₂CF₂CF₃ S(O)₂CF₂CF₂CF₃ S(O)₂CH₂CF₂CF₂CF₃ S(O)₂CF₂CF₂CF₂CF₃ OCH₂(1-CN-c-Pr)

TABLE 3 NHCH₂CF₃ NHCH₂CF₂CF₃ NHCH₂CF₂CF₂CF₃ NMeCH₂CF₃ NMeCH₂CF₂CF₃ NMeCH₂CF₂CF₂CF₃ NEtCH₂CF₃ NEtCH₂CF₂CF₃ NEtCH₂CF₂CF₂CF₃ OS(O)₂CF₃ OS(O)₂CF₂CF₃ OS(O)₂CF₂CF₂CF₃ CH₂OCF₃ CH₂OCH₂CF₃ CH₂OCF₂CF₃ C(O)CF₃ C(O)CF₂CF₃ C(O)CF₂CF₂CF₃ C(O)NMeCH₂CF₃ NMeC(O)CF₃ N═CEtCH₂CF₃ OCH₂(1-CN-c-Bu)

TABLE 4 3-CF₃—Ph 4-CF₃—Ph 3,5-(CF₃)₂—Ph 3-SCF₃—Ph 3-S(O)CF₃—Ph 3-S(O)₂CF₃—Ph 4-SCF₃—Ph 4-S(O)CF₃—Ph 4-S(O)₂CF₃—Ph

TABLE 5 4-CF₃—Py2 5-CF₃—Py2 4-SCF₃—Py2 4-S(O)CF₃—Py2 4-S(O)₂CF₃—Py2 5-SCF₃—Py2 5-S(O)CF₃—Py2 5-S(O)₂CF₃—Py2 5-NMeCH₂CF₃—Py2

TABLE 6 5-CF₃—Py3 6-CF₃—Py3 5-SCF₃—Py3 5-S(O)CF₃—Py3 5-S(O)₂CF₃—Py3 6-SCF₃—Py3 6-S(O)CF₃—Py3 6-S(O)₂CF₃—Py3 6-NMeCH₂CF₃—Py3

A compound (L-1) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₂).

A compound (L-1) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₃).

A compound (L-1) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₄).

A compound (L-1) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₅).

A compound (L-1) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₆).

A compound (L-1) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₇).

A compound (L-1) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₈).

A compound (L-1) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉).

A compound (L-1) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀).

A compound (L-1) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁).

A compound (L-1) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₂).

A compound represented by formula (L-2):

(hereinafter, referred to as Compound (L-2)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₃).

A compound (L-2) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₄).

A compound (L-2) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₅).

A compound (L-2) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₆).

A compound (L-2) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₇).

A compound (L-2) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₈).

A compound (L-2) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₉).

A compound represented by formula (L-3):

(hereinafter, referred to as Compound (L-3)) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₂₀).

A compound (L-3) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₂₁).

A compound (L-3) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₂₂).

A compound (L-3) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₂₃).

A compound (L-3) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₂₄).

A compound (L-3) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₂₅).

A compound (L-3) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₂₆).

A compound (L-3) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₂₇).

A compound (L-3) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₂₈).

A compound (L-3) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₂₉).

A compound (L-3) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₃₀).

A compound (L-3) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₃₁).

A compound represented by formula (L-4):

(hereinafter, referred to as Compound (L-4)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₃₂).

A compound (L-4) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₃₃).

A compound (L-4) wherein A¹ represents a nitrogen atom, represents a methyl group, and T represent any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₃₄).

A compound (L-4) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₃₅).

A compound (L-4) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₃₆).

A compound (L-4) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₃₇).

A compound (L-4) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₃₈).

A compound represented by formula (L-5):

(hereinafter, referred to as Compound (L-5)) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₃₉).

A compound (L-5) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents an ethyl group, and represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₄₀).

A compound (L-5) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₄₁).

A compound (L-5) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₄₂).

A compound (L-5) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₄₃).

A compound (L-5) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₄).

A compound (L-5) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₄₅).

A compound (L-5) wherein A¹ represents a nitrogen atom, R⁴ represents chlorine atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₄₆).

A compound (L-5) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₄₇).

A compound (L-5) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₄₈).

A compound (L-5) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₄₉).

A compound (L-5) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₅₀).

A compound represented by formula (L-6):

(hereinafter, referred to as Compound (L-6)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₅₁).

A compound (L-6) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₅₂).

A compound (L-6) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₅₃).

A compound (L-6) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₅₄).

A compound (L-6) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₅₅).

A compound (L-6) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₅₆).

A compound (L-6) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₅₇).

A compound represented by formula (L-7):

(hereinafter, referred to as Compound (L-7)) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₅₈).

A compound (L-7) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₅₉).

A compound (L-7) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₆₀).

A compound (L-7) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₆₁).

A compound (L-7) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₆₂).

A compound (L-7) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₆₃).

A compound (L-7) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₆₄).

A compound (L-7) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₆₅).

A compound (L-7) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₆₆).

A compound (L-7) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₆₇).

A compound (L-7) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₆₈).

A compound (L-7) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₆₉).

A compound represented by formula (L-8):

(hereinafter, referred to as Compound (L-8)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₇₀).

A compound (L-8) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₇₁).

A compound (L-8) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₇₂).

A compound (L-8) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₇₃).

A compound (L-8) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₇₄).

A compound (L-8) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₇₅).

A compound (L-8) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₇₆).

A compound represented by formula (L-9):

(hereinafter, referred to as Compound (L-9)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₇).

TABLE 7 F Cl Br Me Et Pr i-Pr c-Pr 1-CN-c-Pr OMe OEt OPr Oi-Pr CF₃ NH₂ NHCH₂CF₃ CN C(O)OEt NHC(O)c-Pr NMeC(O)c-Pr CH═N—OH CH═N—OMe

TABLE 8 Ph 3-F—Ph 4-F—Ph 3-Cl—Ph 4-Cl—Ph 3-CF₃—Ph 4-CF₃—Ph 3-NMe₂—Ph 4-NMe₂—Ph 3-CN—Ph 4-CN—Ph 4-C(O)NMe₂—Ph 4-NHC(O)Me—Ph 3,4-F₂—Ph 3,5-F₂—Ph 2,4-F₂—Ph 3,4,5-F₃—Ph 3,4-Cl₂—Ph 3,5-Cl₂—Ph 3,5-Cl₂-4-F—Ph OPh O-2-F—Ph

TABLE 9 Py2 4-F-Py2 5-F-Py2 4-Cl-Py2 5-Cl-Py2 4-CF₃-Py2 5-CF₃-Py2 3-Me-Py2 4-Me-Py2 5-Me-Py2 6-Me-Py2 5-CN-Py2 5-OCH₂CF₂CF₃-Py2 3,5-F₂-Py2 Py3 6-CF₃-Py3 5-CF₃-Py3 6-F-Py3 6-Cl-Py3 Py4 OPy2 OPy3

TABLE 10

TABLE 11

TABLE 12

TABLE 13

TABLE 14

TABLE 15

A compound (L-9) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₈).

A compound (L-9) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₉).

A compound (L-9) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₀).

A compound (L-9) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₁).

A compound (L-9) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₂).

A compound (L-9) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₃).

A compound (L-9) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₄).

A compound (L-9) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₅),

A compound (L-9) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₆).

A compound (L-9) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₇).

A compound (L-9) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₈).

A compound (L-9) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₉).

A compound (L-9) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₀).

A compound represented by formula (L-10):

(hereinafter, referred to as Compound (L-10)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₁).

A compound (L-10) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₂).

A compound (L-10) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₃).

A compound (L-10) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 thereinafter, referred to as Compound Class SX₉₄).

A compound (L-10) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₅).

A compound (L-10) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as compound Class SX₉₆).

A compound (L-10) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₇).

A compound (L-10) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₈).

A compound (L-10) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₉).

A compound (L-10) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₀₀).

A compound (L-10) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₀₁).

A compound (L-10) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (.hereinafter, referred to as Compound Class SX₁₀₂).

A compound (L-10) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₀₃).

A compound (L-10) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₀₄).

A compound represented by formula (L-11):

(hereinafter, referred to as Compound (L-11)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₀₅).

A compound (L-11) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₀₆).

A compound (L-11) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₀₇).

A compound (L-11) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₀₈).

A compound (L-11) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₀₉).

A compound (L-11) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₁₀).

A compound (L-11) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituent, indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₁₁).

A compound (L-11) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₁₂).

A compound (L-11) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₁₃).

A compound (L-11) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₁₄).

A compound (L-11) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₁₅).

A compound (L-11) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₁₆).

A compound (L-11) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₁₇).

A compound (L-11) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX¹¹⁸).

A compound represented by formula (L-12):

(hereinafter, referred to as Compound (L-12)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₁₉).

A compound (L-12) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₂₀).

A compound (L-12) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₂₁).

A compound (L-12) wherein A¹ represents a nitrogen atom, R⁵ represents ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₂₂).

A compound (L-12) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₂₃).

A compound (L-12) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₂₄).

A compound (L-12) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₂₅).

A compound (L-12) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₂₆).

A compound (L-12) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₂₇).

A compound (L-12) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₂₈).

A compound (L-12) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₂₉).

A compound (L-12) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₃₀).

A compound (L-12) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₃₁).

A compound (L-12) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₃₂).

A compound represented by formula L-13):

(hereinafter, referred to as Compound (L-13)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₃₃).

A compound (L-13) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 Table 15 (hereinafter, referred to as Compound Class SX₁₃₄).

A compound (L-13) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₃₅).

A compound (L-13) wherein, A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₃₆).

A compound (L-13) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₃₇).

A compound (L-13) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX¹³⁸).

A compound (L-13) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₃₉).

A compound (L-13) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₄₀).

A compound (L-13) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX¹⁴¹).

A compound (L-13) wherein A¹ represents a nitrogen atom, and R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX¹⁴²).

A compound (L-13) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₄₃).

A compound (L-13) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₄₄).

A compound (L-13) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₄₅).

A compound (L-13) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₄₆).

A compound represented by formula (L-14):

(hereinafter, referred to as Compound (L-14)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₄₇).

A compound (L-14) wherein A¹ represents CH, R⁵ represents an ethyl group R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₄₈).

A compound (L-14) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₄₉).

A compound (L-14) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₅₀).

A compound (L-14) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₅₁).

A compound (L-14) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₅₂).

A compound (L-14) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represent any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₅₃).

A compound (L-14) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₅₄).

A compound (L-14) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₅₅).

A compound (L-14) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₅₆).

A compound (L-14) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₅₇).

A compound (L-14) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₅₈).

A compound (L-14) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₅₉).

A compound (L-14) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₆₀).

A compound represented by formula (L-15):

(hereinafter, referred to as Compound (L-15)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₆₁).

A compound (L-15) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₆₂).

A compound (L-15) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₆₃).

A compound (L-15) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₆₄).

A compound (L-15) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₆₅).

A compound (L-15) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₆₆).

A compound (L-15) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₆₇).

A compound (L-15) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₆₈).

A compound (L-15) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₆₉).

A compound (L-15) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₇₀).

A compound (L-15) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₇₁).

A compound (L-15) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₇₂).

A compound (L-15) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₇₃).

A compound (L-15) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₇₄).

A compound represented by formula (L-16):

(hereinafter, referred to as Compound (L-16)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₇₅).

A compound (L-16) wherein A¹ represent CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₇₆).

A compound (L-16) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₇₇).

A compound (L-15) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₇₈).

A compound (L-16) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₇₉).

A compound (L-16) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₈₀).

A compound (L-16) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₈₁).

A compound (L-16) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₈₂).

A compound (L-16) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₈₃).

A compound (L-15) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₈₄).

A compound (L-16) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₈₅).

A compound (L-6) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₈₆).

A compound (L-16) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₈₇).

A compound (L-16) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₈₈).

A compound represented by formula (L-17):

(hereinafter, referred Compound (L-17)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₈₉).

A compound (L-17) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₉₀).

A compound (L-17) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₉₁).

A compound (L-17) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₉₂).

A compound (L-17) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₉₃).

A compound (L-17) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₉₄).

A compound (L-17) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₉₅).

A compound (L-17) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₉₆).

A compound (L-17) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₉₇).

A compound (L-17) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₉₈).

A compound (L-17) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₉₉).

A compound (L-17) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₀₀). A compound (L-17) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₀₁).

A compound (L-17) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₀₂).

A compound represented by formula (L-18):

(hereinafter, referred to as Compound (L-18)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₀₃).

A compound (L-18) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₀₄).

A compound (L-18) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₀₅).

A compound (L-18) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₀₆).

A compound (L-18) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₀₇).

A compound (L-18) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₀₈).

A compound (L-18) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₀₉).

A compound (L-18) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₁₀).

A compound (L-18) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₁₁).

A compound (L-18) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₁₂).

A compound (L-18) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₁₃).

A compound (L-18) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₁₄).

A compound (L-18) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represent any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₁₅).

A compound (L-18) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₁₆).

A compound represented by formula (L-19):

(hereinafter, referred to as Compound (L-19)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₁₇).

A compound (L-19) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₁₈).

A compound (L-19) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₁₉).

A compound (L-19) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₂₀).

A compound (L-19) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₂₁).

A compound (L-19) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₂₂).

A compound (L-19) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₂₃).

A compound (L-19) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₂₄).

A compound (L-19) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₂₅).

A compound (L-19) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₂₆).

A compound (L-19) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₂₇).

A compound (L-19) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₂₈).

A compound (L-19) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₂₉).

A compound (L-19) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₃₀).

A compound represented by formula (L-20):

(hereinafter, referred to as Compound (L-20)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₃₁).

A compound (L-20) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₃₂).

A compound (L-20) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₃₃).

A compound (L-20) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₃₄).

A compound (L-20) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₃₅).

A compound (L-20) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₃₆).

A compound (L-20) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₃₇).

A compound (L-20) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₃₈).

A compound (L-20) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₃₉).

A compound (L-20) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₄₀).

A compound (L-20) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₄₁).

A compound (L-20) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₄₂).

A compound (L-20) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₄₃).

A compound (L-20) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₄₄).

A compound represented by formula (L-21):

(hereinafter, referred to as Compound (L-21)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₄₅).

A compound (L-21) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₄₆).

A compound (L-21) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represent a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₄₇).

A compound (L-21) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₄₈).

A compound (L-21) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₄₉).

A compound (L-21) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₅₀).

A compound (L-21) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₅₁).

A compound (L-21) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₅₂).

A compound (L-21) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₅₃).

A compound (L-21) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₅₄).

A compound (L-21) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₅₅).

A compound (L-21) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₅₆).

A compound (L-21) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₅₇).

A compound (L-21) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₅₈).

A compound represented by formula (L-22):

(hereinafter, referred to as Compound (L-22)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₅₉).

A compound (L-22) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₆₀).

A compound (L-22) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₆₁).

A compound (L-22) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₆₂).

A compound (L-22) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₆₃).

A compound (L-22) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₆₄).

A compound (L-22) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₆₅).

A compound (L-22) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₆₆).

A compound (L-22) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₆₇).

A compound (L-22) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₆₈).

A compound (L-22) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₆₉).

A compound (L-22) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₇₀).

A compound (L-22) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₇₁).

A compound (L-22) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₇₂).

A compound represented by formula (L-23):

(hereinafter, referred to as Compound (L-23)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₇₃).

A compound (L-23) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₇₄).

A compound (L-23) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₇₅).

A compound (L-23) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₇₆).

A compound (L-23) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₇₇).

A compound (L-23) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen at and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₇₈).

A compound (L-23) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₇₉).

A compound (L-23) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₈₀).

A compound (L-23) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₈₁).

A compound (L-23) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₈₂).

A compound (L-23) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₈₃).

A compound (L-23) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₈₄).

A compound (L-23) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₈₅).

A compound (L-23) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₈₆).

A compound represented by formula (L-24):

(hereinafter, referred to as Compound (L-24)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₈₇).

A compound (L-24) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₈₈).

A compound (L-24) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₈₉).

A compound (L-24) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₉₀).

A compound (L-24) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₉₁).

A compound (L-24) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₉₂).

A compound (L-24) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₉₃).

A compound (L-24) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₉₄).

A compound (L-24) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₉₅).

A compound (L-24) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₉₆).

A compound (L-24) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₉₇).

A compound (L-24) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₉₈).

A compound (L-24) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 1 (hereinafter, referred to as Compound Class SX₂₉₉).

A compound (L-24) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₀₀).

A compound represented by formula (L-25):

(hereinafter, referred to as Compound (L-24)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₀₁).

A compound (L-25) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₀₂).

A compound (L-25) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₀₃).

A compound (L-25) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₀₄).

A compound (L-25) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₀₅).

A compound (L-25) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₀₆).

A compound (L-25)wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₀₇).

A compound (L-25) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₀₈).

A compound (L-25) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₀₉).

A compound (L-25) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₁₀).

A compound (L-25) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₁₁).

A compound (L-25) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₁₂).

A compound (L-25) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₁₃).

A compound (L-25) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₁₄).

A compound represented by formula (L-26):

(hereinafter, referred to as Compound (L-26)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₁₅).

A compound (L-26) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₁₆).

A compound (L-26) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₁₇).

A compound (L-26) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₁₈).

A compound (L-26) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₁₉).

A compound (L-26) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₂₀).

A compound (L-26) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₂₁).

A compound (L-26) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₂₂).

A compound (L-26) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₂₃).

A compound (L-26) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₂₄).

A compound (L-26) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, Table 15 (hereinafter, referred to as Compound class SX₃₂₅).

A compound (L-26) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₂₆).

A compound (L-26) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₂₇).

A compound (L-26) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₂₈).

A compound represented by formula (L-27):

(hereinafter, referred to as Compound (L-27)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₂₉).

A compound (L-27) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₃₀).

A compound (L-27) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₃₁).

A compound (L-27) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₃₂).

A compound (L-27) wherein A¹ represents a nitrogen atom, R⁵ represents a propel group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₃₃).

A compound (L-27) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₃₄).

A compound (L-27) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₃₅).

A compound (L-27) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₃₆).

A compound (L-27) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₃₇).

A compound (L-27) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₃₈).

A compound (L-27) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₃₉).

A compound (L-27) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₄₀).

A compound (L-27) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₄₁).

A compound (L-27) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₄₂).

A compound represented by formula (L-28):

(hereinafter, referred to as Compound (L-28)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₄₃).

A compound (L-28) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₄₄).

A compound (L-28) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred Compound Class SX₃₄₅).

A compound (L-28) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₄₆).

A compound (L-28) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₄₇).

A compound (L-28) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₄₈).

A compound (L-28) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₄₉).

A compound (L-28) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₅₀).

A compound (L-28) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₅₁).

A compound (L-28) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₅₂).

A compound (L-28) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₅₃).

A compound (L-28) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₅₄).

A compound (L-28) wherein A¹ represents nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₅₅).

A compound (L-28) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₅₆).

A compound represented by formula (L-29):

(hereinafter, referred to as Compound (L-29)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₅₇).

A compound (L-29) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₅₈).

A compound (L-29) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₅₉).

A compound (L-29) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₆₀).

A compound (L-29) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₆₁).

A compound (L-29) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₆₂).

A compound (L-29) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₆₃).

A compound (L-29) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₆₄).

A compound (L-29) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₆₅).

A compound (L-29) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₆₆).

A compound (L-29) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₆₇).

A compound (L-29) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₆₈).

A compound (L-29) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₆₉).

A compound (L-29) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₇₀).

A compound represented by formula (L-30):

(hereinafter, referred to as Compound (L-30)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₇₁).

A compound (L-30) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₇₂).

A compound (L-30) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₇₃).

A compound (L-30) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₇₄).

A compound (L-30) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₇₅).

A compound (L-30) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₇₆).

A compound (L-30) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₇₇).

A compound (L-30) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₇₈).

A compound (L-30) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₇₉).

A compound (L-30) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₈₀).

A compound (L-30) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₈₁).

A compound (L-30) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₈₂).

A compound (L-30) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₈₃).

A compound (L-30) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₈₄).

A compound represented by formula (L-31):

(hereinafter, referred to as Compound (L-31)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₈₅).

A compound (L-31 wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₈₆).

A compound (L-31) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₈₇).

A compound (L-31) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₈₈).

A compound (L-31) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₈₉).

A compound (L-31) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₉₀).

A compound (L-31) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₉₁).

A compound (L-31) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₉₂).

A compound (L-31) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₉₃).

A compound (L-31) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₉₄).

A compound (L-31) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₉₅).

A compound (L-31) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₉₆).

A compound (L-31) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₉₇).

A compound (L-31) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₉₈).

A compound represented by formula (L-32):

(hereinafter, referred to as Compound (L-32)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₃₉₉).

A compound (L-32) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₀₀).

A compound (L-32) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₀₁).

A compound (L-32) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₀₂).

A compound (L-32) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₀₃).

A compound (L-32) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₀₄).

A compound (L-32) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₀₅).

A compound (L-32) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₀₆).

A compound (L-32) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₀₇).

A compound (L-32) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₀₈).

A compound (L-32) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₀₉).

A compound (L-32) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₁₀).

A compound (L-32) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₁₁).

A compound (L-32) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₁₂).

A compound represented by formula (L-33):

(hereinafter, referred to as Compound (L-33)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₁₃).

A compound (L-33) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₁₄)

A compound (L-33) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₁₅).

A compound (L-33) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₁₆).

A compound (L-33) wherein A¹ represents a nitrogen atom, R⁵ represents propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₁₇).

A compound (L-33) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₁₈).

A compound (L-33) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₁₁₉).

A compound (L-33) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₂₀).

A compound (L-33) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₂₁).

A compound (L-33) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₂₂).

A compound (L-33) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₂₃).

A compound (L-33) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₂₄).

A compound (L-33) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₂₅).

A compound (L-33) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₂₆).

A compound represented by formula (L-34):

(hereinafter, referred to as Compound (L-34)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₂₇).

A compound (L-34) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 1 (hereinafter, referred to as Compound Class SX₄₂₈).

A compound (L-34) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₂₉).

A compound (L-34) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₃₀).

A compound (L-34) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₃₁).

A compound (L-34) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₃₂).

A compound (L-34) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₃₃).

A compound (L-34) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₃₄).

A compound (L-34) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₃₅).

A compound (L-34) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₃₆).

A compound (L-34) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₃₇).

A compound (L-34) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₃₈).

A compound (L-34) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₃₉).

A compound (L-34) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₄₀).

A compound represented by formula (L-35):

(hereinafter, referred to as Compound (L-35)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₄₁).

A compound (L-35) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₄₂).

A compound (L-35) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated it Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₄₃).

A compound (L-35) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₄₄).

A compound (L-35) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₄₅).

A compound (L-35) wherein A² represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₄₆).

A compound (L-35) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₄₇).

A compound (L-35) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₄₈).

A compound (L-35) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₄₉).

A compound (L-35) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₅₀).

A compound (L-35) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₅₁).

A compound (L-35) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₅₂).

A compound (L-35) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₅₃).

A compound (L-35) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₅₄).

A compound represented by formula (L-36):

(hereinafter, referred to as Compound (L-36)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₅₅).

A compound (L-36) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₅₆).

A compound (L-36) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₅₇).

A compound (L-36) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₅₈).

A compound (L-36) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₅₉).

A compound (L-36) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₆₀).

A compound (L-36) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₆₁).

A compound (L-36) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₆₂).

A compound (L-36) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₆₃).

A compound (L-36) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated, in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₆₄).

A compound (L-36) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₆₅).

A compound (L-36) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₆₆).

A compound (L-36) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₆₇).

A compound (L-36) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₆₈).

A compound represented by formula (L-37):

(hereinafter, referred to as Compound (L-37)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₆₉).

A compound (L-37) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₇₀).

A compound (L-37) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₇₁).

A compound (L-37) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₇₂).

A compound (L-37) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₇₃).

A compound (L-37) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₇₄).

A compound (L-37) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₇₅).

A compound (L 37) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₇₆).

A compound (L-37) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₇₇).

A compound (L-37) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₇₈).

A compound (L-37) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₇₉).

A compound (L-37) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₈₀).

A compound (L-37) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₈₁).

A compound (L-37) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₈₂).

A compound represented by formula (L-38):

(hereinafter, referred to as Compound (L-38)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₈₃).

A compound (L-38) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₈₄).

A compound (L-38) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₈₅).

A compound (L-38) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₈₆).

A compound (L-38) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₈₇).

A compound (L-38) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₈₃).

A compound (L-38) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₈₉).

A compound (L-38) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₉₀).

A compound (L-38) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₉₁).

A compound (L-38) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₉₂).

A compound (L-38) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₉₃).

A compound (L-38) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₉₄).

A compound (L-38) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₉₅).

A compound (L-38) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₉₆).

A compound represented by formula (L-39):

(hereinafter, referred to as Compound (L-39)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₉₇).

A compound (L-39) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₉₈).

A compound (L-39) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₄₉₉).

A compound (L-39) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₀₀).

A compound (L-39) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₀₁).

A compound (L-39) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₀₂).

A compound (L-39) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₀₃).

A compound (L-39) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₀₄).

A compound (L-39) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₀₅).

A compound (L-39) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₀₆).

A compound (L-39) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₀₇).

A compound (L-39) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₀₈).

A compound (L-39) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₀₉).

A compound (L-39) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₁₀).

A compound represented by formula (L-40):

(hereinafter, referred to as Compound (L-40)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₁₁).

A compound (L-40) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₁₂).

A compound (L-40) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₁₃).

A compound (L-40) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₃₄).

A compound (L-40) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₁₅).

A compound (L-40) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₁₆).

A compound (L-40) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₁₇).

A compound (L-40) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₁₈).

A compound (L-40) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₁₉).

A compound (L-40) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₂₀).

A compound (L-40) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₂₁).

A compound (L-40) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₂₂).

A compound (L-40) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₂₃).

A compound (L-40) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₂₄).

A compound represented by formula (L-41):

(hereinafter, referred to as Compound (L-41)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₂₅).

A compound (L-41) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₂₆).

A compound (L-41) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₂₇).

A compound (L-41) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₂₈).

A compound (L-41) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₂₉).

A compound (L-41) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₃₀).

A compound (L-41) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₃₁).

A compound (L-41) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₃₂).

A compound (L-41) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₃₃).

A compound (L-41) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₃₄).

A compound (L-41) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₃₅)

A compound (L-41) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₃₆).

A compound (L-41) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₃₇).

A compound (L-41) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₃₈).

A compound represented by formula (L-42):

(hereinafter, referred to as Compound (L-42)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₃₉).

A compound (L-42) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₄₀).

A compound (L-42) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₄₁).

A compound (L-42) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₄₂).

A compound (L-42) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₄₃).

A compound (L-42) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₄₄).

A compound (L-42) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₄₅).

A compound (L-42 ) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₄₆).

A compound (L-42) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₄₇).

A compound (L-42) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₄₈).

A compound (L-42) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₄₉).

A compound (L-42) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₅₀).

A compound (L-42) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₅₁).

A compound (L-42) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₅₂).

A compound represented by formula (L-43):

(hereinafter, referred to as Compound (L-43)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₅₃).

A compound (L-43) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₅₄).

A compound (L-43) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₅₅).

A compound (L-43) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₅₆).

A compound (L-43) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₅₇).

A compound (L-43) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₅₈).

A compound (L-43) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₅₉).

A compound (L-43) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₆₀).

A compound (L-43) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₆₁).

A compound (L-43) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₆₂).

A compound (L-43) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₆₃).

A compound (L-43) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₆₄).

A compound (L-43) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₆₅).

A compound (L-43) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₆₆).

A compound represented by formula (L-44):

(hereinafter, referred to as Compound (L-44)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₆₇).

A compound (L-44) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₆₈).

A compound (L-44) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₆₉).

A compound (L-44) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₇₀).

A compound (L-44) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₇₁).

A compound (L-44) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₇₂).

A compound (L-44) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₇₃).

A compound (L-44) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₇₄).

A compound (L-44) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₇₅).

A compound (L-44) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₇₆).

A compound (L-44) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₇₇).

A compound (L-44) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₇₈).

A compound (L-44) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₇₉).

A compound (L-44) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₈₀).

A compound represented by formula (L-45):

(hereinafter, referred to as Compound (L-45)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₈₁).

A compound (L-45) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₈₂).

A compound (L-45) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₈₃).

A compound (L-45) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₈₄).

A compound (L-45) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₈₅).

A compound (L-45) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₈₆).

A compound (L-45) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₈₇).

A compound (L-45) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₈₈).

A compound (L-45) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₈₉).

A compound (L-45) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₉₀).

A compound (L-45) wherein A¹ represents a nitrogen atom, R⁵ represents n ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₉₁).

A compound (L-45) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₉₂).

A compound (L-45) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represent a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₉₃).

A compound (L-45) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₉₄).

A compound represented by formula (L-46):

(hereinafter, referred to as Compound (L-46)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₉₅).

A compound (L-46) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₉₆).

A compound (L-46) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₉₇).

A compound (L-46) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₉₈).

A compound (L-46) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₉₉).

A compound (L-46) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₀₀).

A compound (L-46) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₀₁).

A compound (L-46) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₀₂).

A compound (L-46) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₀₃).

A compound (L-46) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₀₄).

A compound (L-46) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₀₅).

A compound (L-46) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₀₆).

A compound (L-46) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₀₇).

A compound (L-46) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₀₈).

A compound represented by formula (L-47):

(hereinafter, referred to as Compound (L-47)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₀₉).

A compound (L-47) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₁₀).

A compound (L-47) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₁₁).

A compound (L-47) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₁₂).

A compound (L-47) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₁₃).

A compound (L-47) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₁₄).

A compound (L-47) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₁₅).

A compound (L-47) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₁₆).

A compound (L-47) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₁₇).

A compound (L-47) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₁₈).

A compound (L-47) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₁₉).

A compound (L-47) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₂₀).

A compound (L-47) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₂₁).

A compound (L-47) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₂₂).

A compound represented by formula (L-48):

(hereinafter, referred to as Compound (L-48)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₂₃).

A compound (L-48) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₂₄).

A compound (L-48) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₂₅).

A compound (L-48) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₂₆).

A compound (L-48) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₂₇).

A compound (L-48) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₂₈).

A compound (L-48) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₂₉).

A compound (L-48) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₃₀).

A compound (L-48) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₃₁).

A compound (L-48) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₃₂).

A compound (L-48) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₃₃).

A compound (L-48) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₃₄).

A compound (L-48) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₃₅).

A compound (L-48) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₅₃₆).

A compound represented by formula (L-49):

(hereinafter, referred to as Compound (L-49)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₃₇).

A compound (L-49) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₃₈).

A compound (L-49) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₃₉).

A compound (L-49) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₄₀).

A compound (L-49) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₄₁).

A compound (L-49) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₄₂).

A compound (L-49) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₄₃).

A compound (L-49) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₄₄).

A compound (L-49) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₄₅).

A compound (L-49) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₄₆).

A compound (L-49) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₄₇).

A compound (L-49) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₄₈).

A compound (L-49) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₄₉).

A compound (L-49) wherein represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₅₀).

A compound represented by formula (L-50):

(hereinafter, referred to as Compound (L-50)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₅₁).

A compound (L-50) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₅₂).

A compound (L-50) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₅₃).

A compound (L-50) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen at and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₅₄).

A compound (L-50) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₅₅).

A compound L-50) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₅₆).

A compound (L-50) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₅₇).

A compound (L-50) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₅₈).

A compound (L-50) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₅₉).

A compound (L-50) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₆₀).

A compound (L-50) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₆₁).

A compound (L-50) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₆₂).

A compound (L-50) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₆₃).

A compound (L-50) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₆₄).

A compound represented by formula (L-51):

(hereinafter, referred to as Compound (L-51)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₆₅).

A compound (L-51) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₆₆).

A compound (L-51) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₆₇).

A compound (L-51) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₆₉).

A compound (L-51) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₆₉).

A compound (L-51) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₇₀).

A compound (L-51) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₇₁).

A compound (L-51) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₇₂).

A compound (L-51) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₇₃).

A compound (L-51) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₇₄).

A compound (L-51) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₇₅).

A compound (L-51) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₇₆).

A compound (L-51) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₇₇).

A compound (L-51) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₇₈).

A compound represented by formula (L-52):

(hereinafter, referred to as Compound (L-52)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₇₉).

A compound (L-52) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₈₀).

A compound (L-52) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₈₁).

A compound (L-52) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₈₂).

A compound (L-52) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₈₃).

A compound (L-52) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₈₄).

A compound (L-52) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₈₅).

A compound (L-52) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₈₆).

A compound (L-52) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₈₇).

A compound (L-52) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₈₈).

A compound (L-52) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₈₉).

A compound (L-52) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₉₀).

A compound (L-52) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₉₁).

A compound (L-52) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₉₂).

A compound represented by formula (L-53):

(hereinafter, referred to as Compound (L-53)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₉₃).

A compound (L-53) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₉₄).

A compound (L-53) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₉₅).

A compound (L-53) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₉₆).

A compound (L-53) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 Table 15 (hereinafter, referred to as Compound Class SX₆₉₇).

A compound (L-53) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₉₈).

A compound (L-53) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₆₉₉).

A compound (L-53) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₀₀).

A compound (L-53) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₀₁).

A compound (L-53) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₀₂).

A compound (L-53) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₀₃).

A compound (L-53) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₀₄).

A compound (L-53) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₀₅).

A compound (L-53) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₀₆).

A compound represented by formula (L-54):

(hereinafter, referred to as Compound (L-54)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₀₇).

A compound (L-54) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₀₈).

A compound (L-54) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₀₉).

A compound (L-54) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₁₀).

A compound (L-54) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₁₁).

A compound (L-54) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₁₂).

A compound (L-54) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₁₃).

A compound (L-54) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₁₄).

A compound (L-54) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₁₅).

A compound (L-54) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₁₆).

A compound (L-54) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₁₇).

A compound (L-54) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₁₈).

A compound (L-54) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₁₉).

A compound (L-54) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₂₀).

A compound represented by formula (L-55):

(hereinafter, referred to as Compound (L-55)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₂₁).

A compound (L-55) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents n substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₂₂).

A compound (L-55) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₂₃).

A compound (L-55) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₂₄).

A compound (L-55) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₂₅).

A compound (L-55) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₂₆).

A compound (L-55) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₂₇).

A compound (L-55) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₂₈).

A compound (L-55) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₂₉).

A compound (L-55) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₃₀).

A compound (L-55) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₃₁).

A compound (L-55) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₃₂).

A compound (L-55) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₃₃).

A compound (L-55) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₃₄).

A compound represented by formula (L-56):

(hereinafter, referred to as Compound (L-56)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₃₅).

A compound (L-56) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₃₆).

A compound (L-56) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₃₇).

A compound (L-56) wherein A² represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₃₈).

A compound (L-56) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₃₉).

A compound (L-56) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₄₀).

A compound (L-56) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₄₁).

A compound (L-56) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₄₂).

A compound (L-56) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₄₃).

A compound (L-56) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₄₄).

A compound (L-56) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₄₅).

A compound (L-56) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₄₆).

A compound (L-56) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₄₇).

A compound (L-56) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₄₈).

A compound represented by formula (L-57):

(hereinafter, referred to as Compound (L-57)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₄₉).

A compound (L-57) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₅₀).

A compound (L-57) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₅₁).

A compound (L-57) wherein A¹ presents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₅₂).

A compound (L-57) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₅₃).

A compound (L-57) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₂₅₄).

A compound (L-57) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₅₅).

A compound (L-57) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₅₆).

A compound (L-57) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₅₇).

A compound (L-57) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₅₈).

A compound (L-57) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₅₉).

A compound (L-57) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₆₀).

A compound (L-57) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₆₁).

A compound (L-57) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₆₂).

A compound represented by formula (L-58):

(hereinafter, referred to as Compound (L-58)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₆₃).

A compound (L-58) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₆₄).

A compound (L-58) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₆₅).

A compound (L-58) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₆₆).

A compound (L-58) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₆₇).

A compound (L-58) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₆₈).

A compound (L-58) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₆₉).

A compound (L-58) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₇₀).

A compound (L-58) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₇₁).

A compound (L-58) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₇₂).

A compound (L-58) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₇₃).

A compound (L-56) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₇₄).

A compound (L-56) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₇₅).

A compound (L-58) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₇₆).

A compound represented by formula (L-59):

(hereinafter, referred to as Compound (L-59)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₇₇).

A compound (L-59) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₇₈).

A compound (L-59) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₇₉).

A compound (L-59) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₈₀).

A compound (L-59) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₈₁).

A compound (L-59) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₈₂).

A compound (L-59) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₈₃).

A compound (L-59) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₈₄).

A compound (L-59) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₈₅).

A compound (L-59)-wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₈₆).

A compound (L-59) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₈₇).

A compound (L-59) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₈₈).

A compound (L-59) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₈₉).

A compound (L-59) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₉₀).

A compound represented by formula (L-60):

(hereinafter, referred to as Compound (L-60)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₉₁).

A compound (L-60) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₉₂).

A compound (L-60) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₉₃).

A compound (L-60) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₉₄).

A compound (L-60) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₉₅).

A compound (L-60) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₉₆).

A compound (L-60) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₉₇).

A compound (L-60) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₉₈).

A compound (L-60) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₇₉₉).

A compound (L-60) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₀₀).

A compound (L-60) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₀₁).

A compound (L-60) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₀₂).

A compound (L-60) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₀₃).

A compound (L-60) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₀₄).

A compound represented by formula (L-61):

(hereinafter, referred to as Compound (L-61)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₀₅).

A compound (L-61) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₀₆).

A compound (L-61) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₀₇).

A compound (L-61) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₀₈).

A compound (L-61) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₀₉).

A compound (L-61) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₁₀).

A compound (L-61) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₁₁).

A compound (L-61) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₁₂).

A compound (L-61) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₁₃).

A compound (L-61) wherein A¹ represents a nitrogen atom, R⁵ represents methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₁₄).

A compound (L-61) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₁₅).

A compound (L-61) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₁₆).

A compound (L-61) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₁₇).

A compound (L-61) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₁₈).

A compound represented by formula (62):

(hereinafter, referred to as Compound (L-62)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₁₉).

A compound (L-62) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₂₀).

A compound (L-62) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₂₁).

A compound (L-62) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₂₂).

A compound (L-62) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₂₃).

A compound (L-62) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₂₄).

A compound (L-62) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₂₅).

A compound (L-62) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₂₆).

A compound (L-62) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₂₇).

A compound (L-62) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₂₈).

A compound (L-62) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₂₉).

A compound (L-62) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₃₀).

A compound (L-62) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₃₁).

A compound (L-62) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₃₂).

A compound represented by formula (L-63):

(hereinafter, referred to as Compound (L-63)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₃₃).

A compound (L-63) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₃₄).

A compound (L-63) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₃₅).

A compound (L-63) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₃₆).

A compound (L-63) wherein A¹ represents a nitrogen atom, P⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₃₇).

A compound (L-63) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, refer to as Compound Class SX₈₃₈).

A compound (L-63) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₃₉).

A compound (L-63) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₄₀).

A compound (L-63) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₄₁).

A compound (L-63) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₄₂).

A compound (L-63) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₄₃).

A compound (L-63) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₄₄).

A compound (L-63) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₄₅).

A compound (L-63) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₄₆).

A compound represented by formula (L-64):

(hereinafter, referred to as Compound (L-64)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₄₇).

A compound (L-64) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₄₈).

A compound (L-64) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₄₉).

A compound (L-64) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₅₀).

A compound (L-64) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₅₁).

A compound (L-64) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₅₂).

A compound (L-64) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₅₃).

A compound (L-64) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₅₄).

A compound (L-64) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₅₅).

A compound (L-64) wherein A¹ represents a nitrogen atom, represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₅₆).

A compound (L-64) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₅₇).

A compound (L-64) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₅₅).

A compound (L-64) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₅₉).

A compound (L-64) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₆₀).

A compound represented by formula (L-65):

(hereinafter, referred to as Compound (L-65)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₆₁).

A compound (L-65) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₆₂).

A compound (L-65) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₆₃).

A compound (L-65) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₆₄).

A compound (L-65) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₆₅).

A compound (L-65) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₆₆).

A compound (L-65) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₆₇).

A compound (L-65) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₆₈).

A compound (L-65) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₆₉).

A compound (L-65) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₇₀).

A compound (L-65) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₇₁).

A compound (L-65) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₇₂).

A compound (L-65) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₇₃).

A compound (L-65) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₇₄).

A compound represented by formula (L-66):

(hereinafter, referred to as Compound (L-66)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₇₅).

A compound (L-66) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₇₆).

A compound (L-66) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₇₇).

A compound (L-66) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₇₈).

A compound (L-66) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₇₉).

A compound (L-66) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₈₀).

A compound (L-66) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₈₁).

A compound (L-66) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₈₂).

A compound (L-66) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₈₃).

A compound (L-66) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₈₄).

A compound (L-66) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₈₅).

A compound (L-66) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₈₆).

A compound (L-66) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₈₇).

A compound (L-66) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₈₈).

A compound represented by formula (L-67):

(hereinafter, referred to as Compound (L-67)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 thereinafter, referred to as Compound Class SX₈₈₉).

A compound (L-67) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₉₀).

A compound (L-67) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₉₁).

A compound (L-67) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₉₂).

A compound (L-67) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₉₃).

A compound (L-67) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₉₄).

A compound (L-67) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₉₅).

A compound (L-67) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₉₆).

A compound (L-67) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₉₇).

A compound (L-67) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₉₈).

A compound (L-67) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₈₉₉).

A compound (L-67) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₀₀).

A compound (L-67) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₀₁).

A compound (L-67) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₀₂).

A compound represented by formula (L-68):

(hereinafter, referred to as Compound (L-68)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₀₃).

A compound (L-68) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₀₄).

A compound (L-68) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₀₅).

A compound (L-68) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₀₆).

A compound (L-68) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₀₇).

A compound (L-69) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₀₈).

A compound (L-68) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₀₉).

A compound (L-68) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₁₀).

A compound (L-68) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₁₁).

A compound (L-68) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₁₂).

A compound (L-68) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₁₃).

A compound (L-68) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₁₄).

A compound (L-68) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₁₅).

A compound (L-68) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₁₆).

A compound represented by formula (L-69):

(hereinafter, referred to as Compound (L-69)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₁₇).

A compound (L-69) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₁₈).

A compound (L-69) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₁₉).

A compound (L-69) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₂₀).

A compound (L-69) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₂₁).

A compound (L-69) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₂₂).

A compound (L-69) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₂₃).

A compound (L-69) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₂₄).

A compound (L-69) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₂₅).

A compound (L-69) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₂₆).

A compound (L-69) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₂₇).

A compound (L-69) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₂₈).

A compound (L-69) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₂₉).

A compound (L-69) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₃₀).

A compound represented by formula L-70):

(hereinafter, referred to as Compound L-7.0)) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3b) represents hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₃₁).

A compound (L-70) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₃₂).

A compound (L-70) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₃₃).

A compound (L-70) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₃₄).

A compound (L-70) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₃₅).

A compound (L-70) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₃₆).

A compound (L-70) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₃₇).

A compound (L-70) wherein A¹ represents CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₃₈).

A compound (L-70) wherein A¹ represents CH, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₃₉).

A compound (L-70) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₄₀).

A compound (L-70) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₄₁).

A compound (L-70) wherein A¹ represents a nitrogen atom, represents a propyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₄₂).

A compound (L-70) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₄₃).

A compound (L-70) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15 (hereinafter, referred to as Compound Class SX₉₄₄).

A compound represented by formula (L-71):

(hereinafter, referred to as Compound (L-71)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₄₅).

A compound (L-71) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₄₆).

A compound (L-71) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₄₇).

A compound (L-71) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₄₈).

A compound (L-71) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₄₉).

A compound (L-71) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₅₀).

A compound (L-71) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₅₁).

A compound represented by formula (L-72):

(hereinafter, referred to as Compound (L-72)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₅₂).

A compound (L-72) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₅₃).

A compound (L-72) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₅₄).

A compound (L-72) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₅₅).

A compound (L-72) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₅₆).

A compound (L-72) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₅₇).

A compound L-72) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₅₈).

A compound represented by formula (L-73):

(hereinafter, referred to as Compound (L-73)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₅₉).

A compound (L-73) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₆₀).

A compound (L-73) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₆₁).

A compound (L-73) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₆₂).

A compound (L-73) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₆₃).

A compound (L-73) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₆₄).

A compound (L-73) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₆₅).

A compound represented by formula (L-74):

(hereinafter, referred to as Compound (L-74)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₆₆).

A compound (L-74) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as compound Class SX₉₆₇).

A compound (L-74) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₆₈).

A compound (L-74) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₆₉).

A compound (L-74) wherein A¹ represents a nitrogen atom, R⁵ represents propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₇₀).

A compound (L-74) wherein A¹ represents a nitrogen atom, R¹ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₇₁).

A compound (L-74) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₇₂).

A compound represented by formula (L-75):

(hereinafter, referred to Compound (L-75)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₇₃).

A compound (L-75) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₇₄).

A compound (L-75) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₇₅).

A compound (L-75) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₇₆).

A compound (L-75) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₇₇).

A compound (L-75) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₇₈).

A compound (L-75) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₇₉).

A compound represented by formula (L-76):

(hereinafter, referred to as Compound (L-76)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₈₀).

A compound (L-76) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₈₁).

A compound (L-76) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₈₂).

A compound (L-76) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₈₃).

A compound (L-76) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₈₄).

A compound (L-76) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₈₅).

A compound (L-76) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₈₆).

A compound represented by formula (L-77):

(hereinafter, referred to as Compound (L-77)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₈₇).

A compound (L-77) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₈₈).

A compound (L-77) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₈₉).

A compound (L-77) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₉₀).

A compound (L-77) wherein A¹ represents a nitrogen atom, R⁵ represents propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₉₁).

A compound (L-77) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₉₂).

A compound (L-77) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₉₃).

A compound represented by formula (L-78):

(hereinafter, referred to as Compound (L-78)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₉₄).

A compound (L-78) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₉₅).

A compound (L-78) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₉₆).

A compound (L-78) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₉₇).

A compound (L-78) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and b represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₉₈).

A compound (L-78) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₉₉₉).

A compound (L-78) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₀₀).

A compound represented by formula (L-79):

(hereinafter, referred to as Compound (L-79)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₀₁).

A compound (L-79) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₀₂).

A compound (L-79) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₀₃).

A compound (L-79) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₀₄).

A compound (L-79) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₀₅).

A compound (L-79) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₀₆).

A compound (L-79) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₀₇).

A compound represented by formula (L-80):

(hereinafter, referred to as Compound (L-80)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₀₈).

A compound (L-80) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₀₉).

A compound (L-80) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₁₀).

A compound (L-80) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₁₁).

A compound (L-80) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₁₂).

A compound (L-80) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₁₃).

A compound (L-80) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₁₄).

A compound (L-1) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₁₅).

A compound (L-1) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₁₆).

A compound (L-1) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₁₇).

A compound (L-1) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₁₈).

A compound (L-1) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₁₉).

A compound (L-3) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₂₀).

A compound (L-3) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₂₁).

A compound (L-3) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₂₂).

A compound (L-3) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₂₃).

A compound (L-3) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₂₄).

A compound (L-5) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₂₅).

A compound (L-5) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₂₆).

A compound (L-5) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₂₇).

A compound (L-5) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₂₈).

A compound (L-5) wherein A¹ represents a nitrogen atom, represents a methyl group, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₂₉).

A compound (L-7) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₃₀).

A compound (L-7) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₃₁).

A compound (L-7) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₃₂).

A compound (L-7) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₃₃).

A compound (L-7) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents an cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₃₄).

A compound represented by formula (L-81):

(hereinafter, referred to as Compound (L-81)) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₃₅).

A compound (L-81) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₃₆).

A compound (L-81) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₃₇).

A compound (L-81) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₃₈).

A compound (L-81) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₃₉).

A compound (L-81) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₄₀).

A compound (L-81) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₄₁).

A compound (L-81) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₄₂).

A compound (L-81) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₄₃).

A compound (L-81) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₄₄).

A compound (L-81) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₄₅).

A compound (L-81) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₄₆).

A compound (L-81) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₄₇).

A compound (L-81) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₄₈).

A compound (L-81) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₄₉).

A compound (L-81) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₅₀).

A compound (L-81) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₅₁).

A compound represented by formula (L-82):

(hereinafter, referred to as Compound (L-82)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₅₂).

A compound (L-82) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₅₃).

A compound (L-82) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₅₄).

A compound (L-82) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₅₅).

A compound (L-82) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₅₆).

A compound (L-82) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₅₇).

A compound (L-82) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₅₈).

A compound represented by formula (L-83):

(hereinafter, referred to as Compound (L-83)) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₅₉).

A compound (L-83) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₆₀).

A compound (L-83) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₆₁).

A compound (L-83) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₆₂).

A compound (L-83) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₆₃).

A compound (L-83) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₆₄).

A compound (L-83) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₆₅).

A compound (L-83) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₆₆).

A compound (L-83) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₆₇).

A compound (L-83) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₆₈).

A compound (L-83) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₆₉).

A compound (L-83) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₇₀).

A compound (L-83) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₇₁).

A compound (L-83) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₇₂).

A compound (L-83) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₇₃).

A compound (L-83) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₇₄).

A compound (L-83) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₇₅).

A compound represented by formula (L-64):

(hereinafter, referred to as Compound (L-84)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₇₆).

A compound (L-84) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₇₇).

A compound (L-84) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₇₈).

A compound (L-84) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₇₉).

A compound (L-84) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₈₀).

A compound (L-84) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₈₁).

A compound (L-84) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₈₂).

A compound represented by formula (L-85):

(hereinafter, referred to as Compound (L-85)) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₈₃).

A compound (L-85) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₈₄).

A compound (L-85) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₈₅).

A compound (L-85) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₈₆).

A compound (L-85) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₈₇).

A compound (L-85) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₈₈).

A compound (L-85) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₈₉).

A compound (L-85) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₉₀).

A compound (L-85) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₉₁).

A compound (L-85) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₉₂).

A compound (L-85) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₉₃).

A compound (L-8 wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₉₄).

A compound (L-85) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₉₅).

A compound (L-85) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₉₆).

A compound (L-85) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₉₇).

A compound (L-85) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₉₈).

A compound (L-85) wherein A¹ represents a nitrogen atom, R⁴ represents a methyl group, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₀₉₉).

A compound represented by formula (L-86):

(hereinafter, referred to as Compound (L-86)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₀₀).

A compound (L-86) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1to Table 6 (hereinafter, referred to as Compound Class SX₁₁₀₁).

A compound (L-86) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₀₂).

A compound (L-86) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₀₃).

A compound (L-86) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₀₄).

A compound (L-86) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₀₅).

A compound (L-86) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₀₆).

A compound represented by formula (L-87):

(hereinafter, referred to as Compound (L-87)) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₀₇).

A compound (L-87) wherein A¹ represents CH, R⁴ represents a hydrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₀₈).

A compound (L-87) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₀₉).

A compound (L-87) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₁₀).

A compound (L-87) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₁₁).

A compound (L-87) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₁₂).

A compound (L-87) wherein A¹ represents a nitrogen atom, R⁴ represents a hydrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₁₃).

A compound (L-87) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₁₄).

A compound (L-87) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₁₅).

A compound (L-87) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₁₆).

A compound (L-87) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₁₇).

A compound (L-87) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₁₈).

A compound (L-87) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₁₉).

A compound (L-87) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to, Compound Class SX₁₁₂₀).

A compound (L-87) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₂₁).

A compound (L-87) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₂₂).

A compound (L-67) wherein A¹ represents a nitrogen atom, R⁴ represents a chlorine atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₂₃).

A compound represented by formula (L-88):

(hereinafter, referred to as Compound (L-88)) wherein A¹ represents CH, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₂₄).

A compound (L-88) wherein A¹ represents CH, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₂₅).

A compound (L-88) wherein A¹ represents a nitrogen atom, R⁵ represents a methyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₂₆).

A compound (L-88) wherein A¹ represents a nitrogen atom, R⁵ represents an ethyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₂₇).

A compound (L-88) wherein A¹ represents a nitrogen atom, R⁵ represents a propyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₂₈).

A compound (L-88) wherein A¹ represents a nitrogen atom, R⁵ represents an isopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₂₉).

A compound (L-88) wherein A¹ represents a nitrogen atom, R⁵ represents a cyclopropyl group, and T represents any substituents indicated in Table 1 to Table 6 (hereinafter, referred to as Compound Class SX₁₁₃₀).

Next, specific examples of an intermediate compound for preparing the compound Z of the present invention are indicated below.

A compound represented by formula (LL-1):

(hereinafter, referred to as Compound (LL-1)) wherein R^(w) represents a hydrogen atom, and T^(W) represents any substituents indicated in Table 1 to Table 6 and Table 16.

TABLE 16 SMe SEt SPr S(i-Pr) S(O)Me S(O)Et S(O)Pr S(O)i-Pr S(O)₂Me S(O)₂Et S(O)₂Pr S(O)₂i-Pr OS(O)₂Me OS(O)₂Et OS(O)₂Pr OMe Oi-Pr OCH₂OMe OBn OCH₂(4-OMe—Ph) OC(O)Me OC(O)Et OC(O)CMe₃ OH F Cl Br I

A compound (LL-1) wherein R^(w) represents a methyl group, and T^(W) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-1) wherein R^(w) represents a benzyl group, and T^(W) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound represented by formula (LL-2):

(hereinafter, referred to as Compound (LL-2)) wherein R^(w) represents a hydrogen atom, and T^(W) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-2) wherein R^(w) represents a methyl group, and T^(W) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-2) wherein R^(w) represents a benzyl group, and T^(W) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound represented by formula (LL-3):

(hereinafter, referred to as Compound (LL-3)) wherein R^(w) represents a hydrogen atom, and T^(W) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-3) wherein R^(w) represents a methyl group, and T^(W) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-3) wherein R^(ow) represents a benzyl group, and T^(W) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound represented by formula (LL-4):

(hereinafter, referred to as Compound (LL-4)) wherein R^(ow) represents a hydrogen atom, and T^(W) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-4) wherein R^(w) represents a methyl group, and T^(W) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-4) wherein R^(w) represents a benzyl group, and T^(W) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound represented by formula (LL-5):

(hereinafter, referred to as Compound (LL-5)) wherein R^(w) represents a hydrogen atom, and T^(w) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-5) wherein R^(w) represents a methyl group, and T^(W) represents any substituents indicated in Table 1 Table 6 and Table 16.

A compound (LL-5) wherein R^(w) represents a benzyl group, and T^(W) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound represented by formula (LL-6):

(hereinafter, referred to as Compound (LL-6)) wherein A¹ represents CH, A² and A³ represent CH, R^(w) represents a hydrogen atom, n is 0, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-6) wherein A¹ represents CH, A² and A³ represent CH, R^(w) represents a hydrogen atom, n is 2, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-6) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R^(w) represents a hydrogen atom, n is 0, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-6) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R^(w) represents a hydrogen atom, n is 2, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-6) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R^(w) represents a methyl group, n is 0, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-6) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R^(w) represents a methyl group, n is 2, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-6) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R^(w) represents a benzyl group, n is 0, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-6) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R^(w) represents a benzyl group, n is 2, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-6) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R^(w) represents a hydrogen atom, n is 0, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-6) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R^(w) represents a hydrogen atom, n is 2, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-6) wherein A¹ represents a nitrogen atom, represents CH, A³ represents a nitrogen atom, R^(w) represents a methyl group, n is 0, and T^(W2) represents any substituents indicated In Table 1 to Table 6 and Table 16.

A compound (LL-6) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R^(w) represents a methyl group, n is 2, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-6) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R^(w) represents a benzyl group, n is 0, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-6) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R^(w) represents a benzyl group, n is 2, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound represented by formula (LL-7):

(hereinafter, referred to as Compound (LL-1)) wherein A¹ represents CH, A² and A⁴ represent CH, R^(w) represents a hydrogen atom, n is 0, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-7) wherein A¹ represents CH, A² and A⁴ represent CH, R^(w) represents a hydrogen atom, n is 2, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-7) wherein A¹ represents a nitrogen atom, A² and A⁴ represent CH, R^(w) represents a hydrogen atom, n is 0, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-7) wherein A¹ represents a nitrogen atom, A² and A⁴ represent CH, R^(w) represents a hydrogen atom, n is 2, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-7) wherein A¹ represents a nitrogen atom, A² and A⁴ represent CH, R^(w) represents a methyl group, n is 0, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-7) wherein A¹ represents a nitrogen atom, A² and A⁴ represent CH, R^(w) represents a methyl group, n and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-7) wherein A¹ represents a nitrogen atom, A² and A⁴ represent CH, R^(w) represents a benzyl group, n is 0, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-7) wherein A¹ represents a nitrogen atom, A² and A⁴ represent CH, R^(w) represents a benzyl group, n is 2, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-7) wherein A¹ represents a nitrogen atom, A² represents CH, A⁴ represents a nitrogen atom, R^(w) represents a hydrogen atom, n is 0, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-7) wherein A¹ represents a nitrogen atom, A² represents CH, A⁴ represents a nitrogen atom, R^(w) represents a hydrogen atom, n is 2, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-7) wherein A¹ represents a nitrogen atom, A² represents CH, A⁴ represents a nitrogen atom, R^(w) represents a methyl group, n is 0, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-7) wherein A¹ represents a nitrogen atom, A² represents CH, A⁴ represents a nitrogen atom, R^(w) represents a methyl group, n is 2, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-7) wherein A¹ represents a nitrogen atom, A² represents CH, A⁴ represents a nitrogen atom, R^(w) represents a benzyl group, n is 0, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound (LL-7) wherein A¹ represents a nitrogen atom, A² represents CH, A⁴ represents a nitrogen atom, R^(w) represents a benzyl group, n is 2, and T^(W2) represents any substituents indicated in Table 1 to Table 6 and Table 16.

A compound represented by formula (LL-8):

(hereinafter, referred to as Compound (LL-8)) wherein A¹ represents CH, A² and A³ represent CH, R^(w) represents a hydrogen atom, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents CH, A² and A³ represent CH, R^(w) represents a hydrogen atom, n is 2, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents CH, A² and A³ represent CH, R^(w) represents a hydrogen atom, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents CH, A² and A³ represent CH, R^(w) represents a hydrogen atom, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R^(w) represents a hydrogen atom, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R^(w) represents a hydrogen atom, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R^(w) represents a hydrogen atom, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A¹ and A³ represent CH, R^(w) represents a hydrogen atom, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R^(w) represents a methyl group, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R^(w) represents a methyl group, n is 2, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R^(w) represents a methyl group, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R^(w) represents a methyl group, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R^(w) represents a hydrogen atom, is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R^(w) represents a hydrogen atom, n is 2, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A² represents CH, R^(w) represents a hydrogen atom, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R^(w) represents a hydrogen atom, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R^(w) represents a methyl group, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R^(w) represents a methyl group, n is 2, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R^(w) represents a methyl group, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-8) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R^(w) represents a methyl group, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound represented by formula (LL-9):

(hereinafter, referred to as Compound (LL-9)) wherein A¹ represents CH, A² and A⁴ represent CH, R^(w) represents a hydrogen atom, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents CH, A² and A⁴ represent CH, R^(w) represents a hydrogen atom, a is 2, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents CH, A² and A⁴ represent CH, R^(w) represents a hydrogen atom, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents CH, A² and A⁴ represent CH, R^(w) represents a hydrogen atom, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² and A⁴ represent CH, R^(w) represents a hydrogen atom, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² and A⁴ represent CH, R^(w) represents a hydrogen atom, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² and A⁴ represent CH, R^(w) represents a hydrogen atom, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² and A⁴ represent CH, R^(w) represents a hydrogen atom, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² and A⁴ represent CH, R^(w) represents a methyl group, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² and A⁴ represent CH, R^(w) represents a methyl group, n is 2, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² and A⁴ represent CH, R^(w) represents a methyl group, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² and A⁴ represent CH, R^(w) represents a methyl group, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² represents CH, A⁴ represents a nitrogen atom, R^(w) represents a hydrogen atom, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² represents CH, A⁴ represents a nitrogen atom, R^(w) represents a hydrogen atom, n is 2, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² represents CH, A⁴ represents a nitrogen atom, R^(w) represents a hydrogen atom, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² represents CH, A⁴ represents a nitrogen atom, R^(w) represents a hydrogen atom, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² represents CH, A⁴ represents a nitrogen atom, R^(w) represents a methyl group, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² represents CH, A⁴ represents a nitrogen atom, R^(w) represents a methyl group, n is 2, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² represents CH, A⁴ represents a nitrogen atom, R^(w) represents a methyl group, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-9) wherein A¹ represents a nitrogen atom, A² represents CH, A⁴ represents a nitrogen atom, R^(w) represents a methyl group, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated, in Table 7to Table 15.

A compound represented by formula (LL-10):

(hereinafter, referred to as Compound (LL-10)) wherein A¹ represents CH, A² and A³ represent CH, R⁵ represents a methyl group, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-10) wherein A¹ represents CH, A² and A³ represent CH, R⁵ represents a methyl group, n is 2, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 1.5

A compound (LL-10) wherein A¹ represents CH, A² and A³ represent CH, R⁵ represents a methyl group, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-10) wherein A¹ represents CH, A² and A³ represent CH, R⁵ represents a methyl group, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-10) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R⁵ represents a methyl group, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-10) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R⁵ represents a methyl group, n is 2, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-10) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R⁵ represents a methyl group, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-10) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R⁵ represents a methyl group, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-10) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R⁵ represents a methyl group, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-10) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R⁵ represents a methyl group, n is 2, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-10) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R⁵ represents a methyl group, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-10) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R⁵ represents a methyl group, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound represented by formula (LL-11):

(hereinafter, referred to as Compound (LL-11)) wherein A¹ represents CH, A² and A³ represent CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-11) wherein A¹ represents CH, A² and A³ represent CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-11) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-11) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-11) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-11) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound represented by formula (LL-12):

(hereinafter, referred to as Compound (LL-12)) wherein A¹ represents CH, A² and A³ represent CH, R⁵ represents a methyl group, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-12) wherein A¹ represents CH, A² and A³ represent CH, R⁵ represents a methyl group, n is 2, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-12) wherein A¹ represents CH, A² and A³ represent CH, R⁵ represents a methyl group, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-12) wherein A¹ represents CH, A² and A³ represent CH, R⁵ represents a methyl group, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-12) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R⁵ represents a methyl group, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-12) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R⁵ represents a methyl group, n is 2, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-12) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R⁵ represents a methyl group, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-12) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R⁵ represents a methyl group, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-12) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R⁵ represents a methyl group, n is 0, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-12) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R⁵ represents a methyl group, n is 2, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-12) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R⁵ represents a methyl group, n is 0, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-12) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R⁵ represents a methyl group, n is 2, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound represented by formula (LL-13):

(hereinafter, referred to as Compound (LL-13)) wherein A¹ represents CH, A² and A³ represent CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-13) wherein A¹ represents CH, A² and A³ represent CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-13) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-13) wherein A¹ represents a nitrogen atom, A² and A³ represent CH, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-13) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R⁵ represents a methyl group, R^(3b) represents a hydrogen atom, and R^(3c) represents any substituents indicated in Table 7 to Table 15.

A compound (LL-13) wherein A¹ represents a nitrogen atom, A² represents CH, A³ represents a nitrogen atom, R⁵ represents a methyl group, R^(3c) represents a hydrogen atom, and R^(3b) represents any substituents indicated in Table 7 to Table 15.

All the compounds classes SX₁ to SX₁₁₃₀ may be prepared according to the method described in the Example or the Process described herein.

The Present compound Z may be mixed or combined with one or more ingredients selected from a group consisting of the following Group (a), Group (b), Group (c), Group (d), and Group (e).

The Present compound may be mixed or combined with one or more ingredients selected from a group consisting of the following Group (a), Group (b), Group (c), Group (d), Group (e), Group (f), Group (g), and group (h) (hereinafter, referred to as Present ingredient).

The above-mentioned mixing or combining represents a use of Present compound Z and the Present ingredient at same time, separately or at certain intervals.

When the Present compound Z and the present ingredient are used at the same time, the Present compound Z and the Present ingredient may be contained in separate formulations respectively or may be contained in the same one formulation.

One aspect of the present invention is a composition comprising one or more ingredients selected from Group (a) or Group (b) as well as the Present compound Z.

Group (a) is a group consisting of Acetylcholinesterase inhibitors (for example, carbamate insecticides, or organophosphorus insecticides), ABA-gated chloride channel blockers (for example, phenylpyrazole insecticides), Sodium channel modulators (for example, pyrethroid insecticides), Nicotinic acetylcholine receptor competitive modulators (for example, neonicotinoid insecticides), Nicotinic acetylcholine receptor allosteric modulators, Glutamatergic chlorine ion channel allosteric modulators (for example, macrolide insecticides), Juvenile hormone mimic, Multisite inhibitors, chordotonal organ TRPV channel modulators, Mites growth inhibitors, Mitochondria ATP biosynthetic enzyme inhibitors, Uncouplers of oxidative phosphorylation, Nicotinic acetylcholine receptor channel blocker (for example, Nereistoxin insecticides), Chitin synthesis inhibitors, Molting inhibitors, Ecdysone receptor agonist, Octopamine receptor agonist, Inhibitors of Mitochondrial electron transport system complex I, II, III and IV, Voltage-dependent sodium channel blockers, Acetyl CoA carboxylase inhibitor, Ryanodine receptor modulator (for example, Diamide insecticides), Chordtonal organ modulators, Microbial pesticides, and the other insecticidal, miticidal or nematicidal active ingredients. These ingredients are classified as a class based on the action mechanism of IRAC.

Group (b) is a group consisting of Nucleic acid synthesis inhibitors (for example, Phenylamide fungicides, or Acylamino acid fungicides), Cell division and cytoskeleton inhibitors (for example, MBC fungicides), Respiratory inhibitors (for example, QoI fungicides or Qil fulgicides), Amino acid synthesis and protein synthesis inhibitors (for example, anilinopyridine fungicides), Signal transduction inhibitors, Lipid synthesis and membrane synthesis inhibitors, sterol biosynthesis inhibitors (for example, DMI fungicides such as triazole), Cell wall synthesis inhibitors, Melanin synthesis inhibitors, Plant defense inducers, Other action point contact active fungicides, Microbial fungicides, and the other fungicidal ingredients. These are classified as a class based on the action mechanism of FRAC.

Group (c) is a plant growth modulating ingredients group consisting of Plant growth modulating ingredients, Mycorrhizal fungi, and Root nodule bacteria.

Group (d) is a phytotoxicity-reducing ingredient group which reduces the phytotoxicity against the crop when it is used in combination with the other chemicals.

Group (e) is a synergist group which enhances the effectiveness of the other chemicals when it is used in combination with the other chemicals.

Group (f) is a group consisting of repellent components consisting of bird repellant components, insect repellant components, and animal repellant components.

Group is a molluscicidal component group.

Group (h) is an insect pheromone group.

Examples of the combination of the Present ingredient and the Present compound Z are described below. For example, alanycarb+SX represents a combination of alanycarb and SX

The symbol of “SX” represents any one of the Present compound Z selected from the Compound Class SX₁ to the Compound Class SX₁₁₃₀. Also, all of the below-mentioned present ingredient are known ingredients, and are commercially available or may be produced by the known method. If the present ingredient is a bacterium, it is available also from the bacterial authority depository. The numerical number in bracket represents a CAS RN (Register Trademark).

Combination of the Present ingredient of the above group (a) and the Present compound Z:

abamectin+SX, acephate+SX, acequinocyl +SX, acetamiprid+SX, acrinathrin+SX, acynonapyr+SX, afidopyropen+SX, afoxolaner+SX, alanycarb+SX, aldicarb+SX, allethrin+SX, alpha-cypermethrin+SX, alpha-endoaulfan+SX, aluminium phosphide+SX, amitraz+SX, azadirachtin+SX, azamethiphos+SX, azinphos-ethyl+SX, azinphos-methyl+SX, azocyclotin+SX, bark of Celastrus angulatus+SX, bendiocarb+SX, benfluthrin+SX, benfuracarb+SX, bensultap+SX, benzoximate+SX, benzpyrimoxan+SX, beta-cyfluthrin+SX, beta-cypermethrin+SX, bifenazate+SX, bifenthrin+SX, bioallethrin+SX, bioresmethrin+SX, bistrifluron+SX, borax+SX, boric acid+SX, broflanilide+SX, bromopropylate+SX, buprofezin+SX, butocarboxim+SX, butoxycarboxim+SX, cadusafos+SX, calcium cyanide+SX, calcium phosphide+SX, carbaryl+SX, carbofuran+EX, carbosulfan+SX, cartap hydrochloride+SX, cartap+SX, chinomethionat+SX, chlorantraniliprole+SX, chlordane+SX, chloethoxyfos+SX, chlorfenapyr+SX, chlorfenvinphos+SX, chlorfluazuron+SX, chlormephos+SX, chloropicrin+SX, chlorpyrifos+SX, chlorpyrifos-methyl+SX, chromafenozide+SX, clofentezine+SX, clothianidin+SX, coumaphos+SX, cryolite+SX, cyanophos+SX, cyantraniliprole+SX, cycloniliprole+SX, cycloprothrin+SX, cycloxaprid+SX, cyenopyrafen+SX, cyflumetofen+SX, cyfluthrin+SX, cyhalodiamide+SX, cyhalothrin+SX, cyhexatin+SX, cypermethrin+SX, cyphenothrin+SX, cyromazine+SX, dazomet+SX, deltamethrin+SX, demeton-S-methyl+SX, diafenthiuron+SX, diazinon+SX, dichlorvos+SX, dicloromezotiaz+SX, dicofol+SX, dicrotophos+SX, diflovidazin+SX, diflubenzuron+SX, dimefluthrin+SX, dimethoate+SX, dimethylvinphos+SX, dinotefuran+SX, disodium octaborate+SX, disulfoton+SX, DNOC(2-methyl-4,6-dinitrophenol)+SX, dorametin+SX, dried leaves of Dryopteris filix-mas+SX, emamectin-benzoate+SX, empenthrin+SX, endosulfan+SX, EPN (O-ethyl O-(4-nitrophenyl) phenylphosphonothioate)+SX, epsilon-etofluthrin+SX, epsilon-momfluorothrin+SX, esfenvalerate+SX, ethiofencarb+SX, ethion+SX, ethiprole+SX, ethoprophos+SX, etofenprox+SX, etoxazole+SX, extract of Artemisia absinthium+SX, extract of Cassia nigricans+SX, extract of Clitoria ternatea+SX, extract of Symphytum officinale+SX, extracts or simulated blend of Chenopodium ambrosioides+SX, extract of Tanacetum vulgare+SX, extract of Urtica dioica+SX, extract of Viscum album+SX, famphur+SX, fenamlphos+SX, fenazaquin+SX, fenbutatin oxide+SX, fenitrothion+SX, fenobucarb+SX, fenoxycarb+SX, fenpropathrin+SX, fenpyroximate+SX, fenthion+SX, fenvalerate+SX, fipronil+SX, flometoquin+SX, flonicamid+SX, fluacrypyrim+SX, fluazaindolizine+fluazuron+SX, flubendiamide+SX, flucycloxuron+SX, flucythrinate+SX, fluensulfone+SX, flufenoprox+SX, flufenoxuron+SX, flufiprole+SX, flumethrin+SX, fluopyram+SX, flupyradifurone+SX, fluralaner+SX, fluvalinate+SX, fluxametamide+SX, formetanate+SX, fosthiazate+SX, furamethrin+SX, furathiocarb+SX, gamma-cyhalothrin+SX, GS-omega/kappa HXTX-Hvla peptide+SX, halfenprox+SX, halofenozide+SX, heptafluthrin+SX, heptenophos+SX, hexaflumuron+SX, hexythiazox+SX, potassium salt of hop beta acid+SX, hydramethylnon+SK, hydroprene+SX, imicyafos+SX, imidacloprid+SX, imiprothrin+SX, indoxacarb+SX, isofenphos+SX, isoprocarb+SX, isopropyl-O-(methoxyaminothiophosphoryl)salicylate+SX, isoxathion+SX, ivermectin+SX, kadethrin+SX, kappa-tefluthrin+SX, kappa-bifenthrin+SX, kinoprene+SX, lambda-cyhalothrin+SX, lepimectin+SX, lime sulfur+SX, lufenuron+SX, machine oil+SX, malathion+SX, mecarbam+SX, meperfluthrin+SX, metafiumizone+SX, metam+SX, methamidophos+SX, methidathion+SX, methiocarb+SX, methomyl+SX, methoprene+SX, methoxychlor+SX, methoxyfenozide+SX, methyl bromide+SX, metofluthrin+SX, metolcarb+SX, metoxadiazone+SX, mevinphos+SX, milbemectin+SX, milbemycin oxime+SX, momfluorothrin+SX, monocrotophos+SX, moxidectin+SX, naled+SX, neem oil+SX, nicotine+SX, nicotine-sulfate+SX, nitenpyram+SX, novalurori+SX, noviflumuron+SX, oil of the seeds of Chenopodium anthelminticum+SX, omethoate+SX, oxamyl+SX, oxydemeton-methyl+SX, parathion+SX, parathion-methyl+SX, permethrin+SX, phenothrin+SX, phenthoate+SX, phorate+SX, phosalone+SX, phosmet+SX, phosphamidon SX, phosphine+SX, phoxim+SX, pirimicarb+SX, pirimiphos-methyl+SX, potassium cyanide+SX, prallethrin+SX, profenofos+SX, profluthr+SX, propargite+SX, propetamphos+SX, propoxur+SX, propylene glycol alginate+SX, prothiofos+SX, pyflubumide+SX, pymetrozine+SX, pyraclofos+SX, pyrethrins+SX, pyridaben+SX, pyridalyl+SX, pyridaphenthion+SX, pyrifluquinazone+SX, pyrimidifen+SX, pyriminostrobin+SX, pyriprole+SX, pyriproxyfen+SX, quinalphos+SX, resmethrin+SX, rotenone+SX, ryanodine+SX, selamactin+SX, sigma-cypermethrin+SX, silafluofen+SX, sodium borate+SX, sodium cyanide+SX, sodium metaborate+SX, spinetoram+SX, spinosad+SX, spirodiclofen+SX, spiromesifen+SX, spiropidion+SX, spirotetramat+SX, sulfluramid+SX, sulfotep+SX, sulfoxaflor+SX, sulfur+SX, sulfuryl fluoride+SX, tartar emetic+SX, tau-fluvalinate SX, tebufenozide+SX, tebufenpyrad+SX, tebupirimfos+SX, teflubenzuron+SX, tefluthrin+SX, temephos SX, terbufos+SX, terpene constituents of the extract of chenopodium ambrosioides near ambrosioides, Brand name: Terpenoid blend QRD 460+SX, tetrachlorvinphos+SX, tetradifon+SX, tetramethrin+SX, tetramethylfluthrin+SX, tetraniliprole+SX, theta-cypermethrin+SX, thiacloprid+SX, thiamethoxam+SX, thiocyclam+SX, thiodicarb+SX, thiofanox+SX, thiometon+SX, thiosultap-disodium+SX, thiosultap-monosodium+SX, tioxazafen+SX, tolfenpyrad+SX, tralomethrin+SX, transfluthrin+SX, triazamate+SX, triazophos+SX, trichlorfon+SX, triflumezopyrim+SX, triflumuron+SX, trimethacarb+SX, vamidothion+SX, XMC (3,5-dimethylphenya N-methylcarbamate)+SX, xylylcarb+SX, zeta-cypermethrin+SX, zinc phosphide+SX, (E)-N-{1-[(6-chloropyridin-3-yl)methyl]pyridin-2(1H)-ylidene}-2,2, trifluoroacetamide (1689566-03-7)+SX, 3-bromo-N-[2,4-dichloro-6-(methylcarbamoyl)phenyl]-1-(3,5-dichloropyridin-2-yl)-1H-pyrazole-5-carboxamide (1104384-14-6)+SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-N-ethyl-3-(3,3,3-trifluoropropylsulfanyl)propanamide (1477919-27-9)+SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-N-ethyl-3-(3,3,3-trifluorapropanesulfinyl)propanamide (1477923-37-7)+SX, 2-[(ethanesulfonyl)pyridin-2-yl]-5-(trifluoromethanesulfonyl)benzoxazole (1616678-32-0)+SX, 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothiethan-3-yl)benzamide (1241050-20-3)+SX, 3-methoxy-N-(5-{5-(trifluoromethyl)-5-[[3-(trifluoromethyl)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}indan-1-yl) propanamide (1118626-57-5)+SX, N-[2-bromo-6-chloro-4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)phenyl]-3-{ethyl[(pyridin-4-yl)carbonyl]amino}-2-methoxybenzamide (1429513-53-0)+SX, N-[2-bromo-6-chloro-4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)phenyl]-3-[ethyl(4-cyanobenzoyl)amino]-2-methoxybenzamide (1609007-65-9)+SX, N-[2-bromo-6-difluoromethoxy-4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)phenyl]-3-{methyl[(pyridin-4-yl)carbonyl]amino}-2-methoxybenzamide (1630969-78-6)+SX, 1-{2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}-3-(trifluoromethyl)-1H-1,2,4-triazole-5-amine (885026-50-6)+SX, BT crop protein Cry1Ab+SX, BT crop protein Cry1Ac+SX, BT crop protein Cry1Fa+SX, BT crop protein Cry1A.105+SX, BT crop protein Cry2Ab+SX, BT crop protein Vip3A+SX, BT crop protein Cry3A+SX, BT crop protein Cry3Ab+SX, BT crop protein Cry3Bb+SX, BT crop protein Cry34Ab1/Cry35Ab1+SX, Adoxophyes orana granulosis virus+SX, Anticarsia gemmatalis mNPV+SX, Autographa californica mNPV FV#11+SX, Cydia pomonella GV V15+SX, Cydia pomonella GV V22+SX, Cryptophlebia leucotreta GV+SX, Dendrolimus punctatus cypovirus+SX Helicorerpa armigera NPV BV-0003+SX, Helicoverpa zea NPV+SX, Lymantria dispar NPV+SX, Mamestra brassicae NPV+SX, Mamestra configurator NPV+SX, Neodiprion abietis NPV+SX, Neodiprion lecontei NPV+SX, Neodiprion sertifer NPV+SX, Nosema locustae+SX, Orgyia pseudotsugata NPV+SX, Pieris rapae GV+SX, Plodia interpunctella GV+SX, Spodoptera exigua mNPV+SX, Spodoptera littoralis mNPV+SX, Spodoptera litura NPV+SX, Arthrobotrys dactyloides+SX, Bacillus firmus GB-126+SX, Bacillus firmus I-1582+SX, Bacillus megaterium+SX, Bacillus sp. AQ175+SX, Bacillus sp. AQ177+SX, Bacillus sp. AQ178+SX, Bacillus sphaericus 2362+SX, Bacillus sphaericus ABTS1743+SX, Bacillus sphaericus Serotype H-5a5b+SX, Bacillus thuringiensis AQ52+SX, Bacillus thuringiensis BD#32+SX, Bacillus thuringiensis CR-371+SX, Bacillus thuringiensis subsp. Aizawai BTS-1857+SX, Bacillus thuringiensis subsp. Aizawai AM65-52+SX, Bacillus thuringiensis subsp. Aizawai GC-91+SX, Bacillus thuringiensis subsp. Aizawai Serotype H-7+SX, Bacillus thuringiensis subsp. Kurstaki ABTS351+SX, Bacillus thuringiensis subsp. Kurstaki BMP123+SX, Bacillus thuringiensis subsp. Kurstaki EG234+SX, Bacillus thuringiensis subsp. Kurstaki EG7841+SX, Bacillus thuringiensis subsp. Kurstaki EVB113-19+SX, Bacillus thuringiensis subsp. Kurstaki F10+SX, Bacillus thuringiensis subsp. Kurstaki HD-1+SX, Bacillus thuringiensis subsp. Kurstaki PB54+SX, Bacillus thuringiensis subsp. Kurstaki SA-11+SX, Bacillus thuringiensis subsp. Kurstaki SA-12+SX, Bacillus thuringiensis subsp. Tenebriosis NB176+SX, Bacillus thuringiensis subsp. Thuringiensis MPPL002+SX, Bacillus thuringiensis subsp. morrisoni+SX, Bacillus thuringiensis var. colmeri+SX, Bacillus thuringiensis var. darmstadiensis 24-91+SX, Bacillus thuringiensis var. dendrolimus+SX, Bacillus thuringiensis var. galleriae+SX, Bacillus thuringiensis var. israelensis BMP144+SX, Bacillus thuringiensis var. israelensis serotype H-11+SX, Bacillus thuringiensis var. japonensis buibui+SX, Bacillus thuringiensis var. san diego M-7+SX, Bacillus thuringiensis var. 7216+SX, Bacillus thuringiensis var. aegypti+SX, Bacillus thuringiensis var. T36+SX, Beauveria bassiana ANT-03+SX, Beauveria bassiana ATCC74040+SX, Beauveria bassisana GHA+SX, Beauveria brongniartii+SX, Burkholderia rinojensis A396+SX, Chromobacterium subtsugae PRAA4-1T+SX, Dactyllela ellipsospora+SX, Dectylaria thaumasia+SX, Hirsutella minnesotensis+SX, Hirsutella rhossiliensis+SX, Hirsutella thompsonii+SX, Lagenidium giganteum+SX, Lecanicillium lecanii KV01+SX, Lecanicillium lecanii conidia of strain DAOM198499+SX, Lecanicillium lecanii conidia of strain DAOM216596+SX, Metarhizium anisopliae F52+SX, Metarhizium anisopliae var. acridum+SX, Metarhizium flavoviride+SX, Monacrosporium phymatopagum+SX, Paecilomyces fumosoroseus Apopka97+SX, Paecilomyces lilacinus 251+SX, Paecilomyces tenuipes T1+SX, Paenibacillus popilliae+SX, Pasteuria nishizawae Pn1+SX, Pasteuria penetrans+SX, Pasteuria usgae+SX, Pasteuria thoynei+SX, Serratia entomophila+SX, Verticillium chlamydosporium+SX, Verticillium lecani NCIM1312+SX, lenoremycin+SX, concanamycin A+SX

Combination of the Present ingredient of the above Group (b) and the Present compound Z:

acibenzolar-S-methyl+SX, aldimorph+SX, ametoctradin+SX, aminopyrifen+SX, amisulbrom+SX, anilazine+SX, azaconazole+SX, azoxystrobin+SX, basic copper sulfate+SX, benalaxyl+SX, benalaxyl-M+SX, benodanil+SX, benomyl+SX, benthiavalicarb+SX, benthivalicarb-isopropyl+SX, benzovindiflupyr+SX, binapacryl+SX, biphenyl+SX, bitertanol+SX, bixafen+SX, blasticidin-S+SX, Bordeaux mixture+SX, boscalid+SX, bromothalonil+SX, bromuconazole+SX, bupirimate+SX, captafol+SX, captan+SX, carbendazim+SX, carboxin+SX, carpropamid+SX, chinomethionat+SX, chitin+SX, chioroneb+SX, chlorothalonil+SX, chlozolinate+SX, colletochlorin B+SX, copper(II) acetate+SX, copper(II) hydroxide+SX, copper oxychloride SX, copper(II) sulfate+SX, coumoxystrobin+SX, cyazofamid+SX, cyflufenamid+SX, cymoxanil+SX, cyproconazole+SX, cyprodinil+SX, dichlobentiazox+SX, dichlofluanid+SX, diclocymet+SX, diclomezine+SX, dicloran+SX, diethofencarb+SX, difenoconazole+SX, diflumetorim+SX, imethachlone+SX, dimethirimol+SX, dimethomorph+SX, dimoxystrobin+SX, diniconazole+SX, diniconazole-M+SX, dinocap SX, dipotassium hydrogenphosphite+SX, dipymetitrone+SX, dithianon+SX, dodecylbenzenesulphonic acid bisethylenediamine copper(II) salt+SX, dodemorph+SX, iodine+SX, edifenphos+SX, enoxastrobin+SX, epoxiconazole+SX, etaconazole+SX, ethaboxam+SX, ethirimol+SX, etridiazole+SX, extract from Melaleuca alternifolia+SX, extract from Reynoutria sachalinensis+SX, extract from the cotyledons of lupine plantlets(“BLAD”)+SX, extract of Allium sativum+SX, extract of Eauisetum arvense+SX, extract of Tropaeolum majus+SX, famoxadone+SX, fenamidone+SX, fenaminstrobin+SX, fenarimol+SX, fenbuconazole+SX, fenfuram SX, fenhexamid+SX, fenoxanil+SX, fenpiclonil+SX, fenpicoxamid+SX, fenpropidin+SX, fenpropimorph+SX, fenpyrazamine+SX, fentin acetate+SX, fentin chloride+SX, fentin hydroxide+SX, ferbam+SX, ferimzone+SX, florylpicoxamid+SX, fluazinam+SX, fludioxonil+SX, flufenoxystrobin+SX, fluindapyr+SX, flumorph+SX, fluopicolide+SX, fluopimomide+SX, fluoroimide+SX, fluoxastrobin+SX, fluquinconazole+SX, flusilazole+SX, flusulfamide+SX, flutianil+SX, flutolanil+SX, flutriafol+SX, fluxapyroxad+SX, folpet+SX, fosetyl+SX, fosetyl-aluminium+SX, fuberidazole+SX, furalaxyl+SX, furametpyr+SX, guazatine+SX, hexaconazole°SX, hyinexazole+SX, imazalil+SX, imibenconazole+SX, iminoctadine+SX, iminoctadine triacetate+SX, inpyrfluxam+SX, iodocarb+SX, ipconazole+SX, ipfentrifluconazole+SX, ipflufenoquin+SX, iprobenfos+SX, iprodione+SX, iprovalicarb+SX, isofetamid+SX, sofiucypram+SX, isoprothiolane+SX, isopyrazam+SX, isotianil+SX, kasugamycin+SX, kresoxim-methyl+SX, laminarin+SX, leaves and bark of Quercus+SX, mancozeb+SX, mandestrobin+SX, mandipropamid+SX, maneb+SX, mefentrifluconazole+SX, mepanipyrim+SX, mepronil+SX, meptyldinocap+SX, metalaxyl+SX, metalaxyl-M+SX, metconazole+SX, methasulfocarb+SX, metiram+SX, metominostrobin+SX, metrafenone+SX, mineral oils+SX, myclobutanil+SX, naftifine+SX, nuarimol+SX, octhilinone+SX, ofurace+SX, orysastrobin+SX, oxadixyl+SX, oxathiapiprolin+SX, oxine-copper+SX, oxolinic acid+SX, oxpoconazole+SX, oxpoconazole fumarate+SX, oxycarboxin+SX, oxytetracycline+SX, pefurazoate+SX, penconazole+SX, pencycuron+SX, penflufen+SX, penthiopyrad+SX, phenamacril+SX, phosphorous acid+SX, phthalide+SX, picarbutrazox+SX, picoxystrobin+SX, piperalin+SX, polyoxins+SX, potassium hydrogencarbonate+SX, potassium dihydrogenphosphite+SX, probenazole+SX, prochloraz+SX, procymidone+SX, propamidine+SX, propamocarb+SX, propiconazole SX, propineb+SX, proquinazid+SX, prothiocarb+SX, prothioconazole+SX, pydiflumetofen+SX, pyraclostrobin+SX, pyrametostrobin+SX, pyraoxystrobin+SX, pyrapropoyne+SX, pyraziflumid+SX, pyrazophos+SX, pyribencarb+SX, pyributicarb+SX, pyrifenox+SX, pyrimethanil+SX, pyrimorph+SX, pyriofenone+SX, pyrisoxazole+SX, pyroquilon+SX, Quillaja extract+SX, guinconazole+SX, quinofumelin+SX, quinoxyfen+SX, quintozene+SX, Saponins of Chenopodium quinoa+SX, sedaxane+SX, silthiofam+SX, simeconazole+SX, sodium hydrogencarbonate+SX, spiroxamine+SX, streptomycin+SX, sulfur+SX, tebuconazole+SX, tebufloquin+SX, teclofthalam+SX, tecnazene+SX, terbinafine+SX, tetraconazole+SX, thiabendazole+SX, thifluzamide+SX, thiophanate+SX, thiophanate-methyl+SX, thiram+SX, thymol+SX, tiadinil+SX, tolclofos-methyl+SX, tolfenpyrad+SX, tolprocarb+SX, tolylfluanid+SX, triadimefon+SX, triadirnenol+SX, triazoxide+SX, triclopyricarb+SX, tricyclazole+SX, tridemorph+SX, trifloxystrobin+SX, triflumizole+SX, triforine+SX, triticonazole+SX, validamycin+SX, valifenalate+SX, vinclozolin+SX, yellow mustard powder+SX, zinc thiazole+SX, zineb+SX, ziram+SX, zoxamide+SX, 3-difluoromethyl-N-methoxy-1-methyl-N-[(1R)-1-methyl-2-(2,4,6-trichlorophenyl)ethyl]pyrazol-4-carboxamide (1639015-48-7)+SX, 3-difluoromethyl-N-methoxy-1-methyl-N-[(1S)-1-methyl-2-(2,4,6-trichlorophenyl)ethyl]pyrazol-4-carboxamide (1639015-49-8)+SX, 3-difluoromethyl-1-methyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4-carboxamide (141573-94-6)+SX, 3-difluoromethyl-N-[(3R)-7-fluoro-1,1,3-trimethylindan-4-yl]-1-methylpyrazole-4-carboxamide (1513466-73-3)+SX, 3-chloro-5-phenyl-6-methyl-4-(2,6-difluorophenyl)pyridazine (1358061-55-8)+SX, N′-[4-({3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl}oxy-2,5-dimethylphenyl]-N-ethyl-N-methylmethaneimidamide (1202781-91-6+SX, 2-{3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorophenyl=methanesulfonate (1360819-11-9)+SX, 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine (1362477-26-6)+SX, 2,2-dimethyl-9-fluoro-5-(quinolin-3-yl)-2,3-dihydrobenzo[f] [1,4]oxazepine (1207749-50-5+SX, 2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline (1257056-97-5)+SX, 5-fluoro-2-[(4-methylphenyl)methoxy]-4-pyrimidineamine (1174376-25-0)+SX, 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidine-2 1H)-one (1616664-98-2)+SX, N′-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methyl-methaneimidamide (1052688-31-9)+SX, N′-{4-[(4,5-dichlorothiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methyl-methaneimidamide (929908-57-6)+SX, ethyl (2Z)-3-amino-2-cyano-3-phenylacrylate (39491-78-6)+SX, N-{(2-chlorothiazol-5-yl)methyl}-N-ethyl-6-methoxy-3-nitropyridine-2-amine (1446247-98-8)+SX, 1-[2-({[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}methyl)-3-methylphenyl]-4-methyl-5-oxo-4,5-dihydro-1H-tetrazole (1472649-01-6)+SX, α-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-4-isoxazolyl]-1-3-pyridine methanol (1229605-96-2)+SX, (αS)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-4-isoxazolyl]-3-pyridine methanol (1229606-46-5)+SX, (αS)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-4-isoxazolyl]-3-pyridine methanol (1229606-46-5)+SX), (αR)-[3-(4-chloro-2-f luorophenyl)-5-(2,4-difluorophenyl)-4-isoxazolyl]-3-pyridine methanol (1229606-02-3)+SX), 2-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione (1342260-19-8)+SX, 2-{[(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione (1638897-70-7)+SX, 2-{[(2S,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione (1638897-71-8)+SX, 2-{[(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione (1638897-72-9)+SX, 2-{[(2S,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione (1638897-73-0)+SX, 1-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate (1342260-26-7)+SX, 1-{[(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate (1638897-82-1)+SX, 1-{[(2S,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate (1638897-84-3)+SX, 1-{[(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxian-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate (1638897-86-5)+SX, 1-{[(2S,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate (1638897-89-8)+SX, 5-(4-chlorobenzyl)-2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1394057-11-4)+SX, (1R,2S,5S)-5-(4-chlorobenzyl)-2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopenotanol (1801930-06-2)+SX, (1S,2R ,5R)-(4-chlorobenzyl)-2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1801930-07-3)+SX, (1R,2R,5R)-5-(4-chlorobenzyl)-2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1801919-53-8)+SX, (1S,2S,5S)-5-(4-chlorobenzyl)-2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1801919-54-9)+SX, (1R,2R,5S)-(4-chlorobenzyl)-2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1801919-55-0)+SX, (1S,2R,5R)-5-(4-chlorobenzyl)-2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1801919-56-1)+SX, (1R,2S,5R)-5-(4-chlorobenzyl)-2-chloromethyl-2 -methyl-1-(1H-1,2 4-triazol-1-ylmethyl)cyclopentanol (1801919-57-2)+SX, (1S,2R,5S)-5-(4-chlorobenzyl)-2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1801919-58-3)+SX, Methyl=3-[4-(chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4,-triazol-1 -ylmethyl)cyclopentane carboxylate (1791398-02-1)+SX, Methyl=(1R,2S,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-yl ethyl)cyclopentane carboxylate+SX, Methyl=(1S,2R,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane carboxylate+SX, Methyl=(1R,2R,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane carboxylate+SX, Methyl=(1S,2S, 3S)-3-[(4-chlorophehyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane carboxylate+SX, Methyl=(1R,2R,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane carboxylate+SX, Methyl=(1S,2S,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane carboxylate+SX, Methyl=(1R,2S,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane carboxylate+SX, Methyl=(1S,2R,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane carboxylate+SX, 2-chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1394057-13-6)+SX, (1R,2S,5S)-2-chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1301930-08-4)+SX, (1S, 2R,5R)-2-chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1801930-09-5)+SX, (1R,2R,5R)-2-chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1638898-08-4)+SX, (1S,2S,5S)-2-chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1638898-10-8)+SX, (1R,2R,5S)-2-chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1638898-13-1)+SX, (1S,2S,5R)-2-chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1638898-16-4)+SX, (1R, 2S, 5R)-2-chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1638898-20-0)+SX,

(1S,2R,5S)-2-chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (1638898-24-4)+SX, (R)-2-[2-chloro-4-(4-chlorophenoxy)phenyl]-1-(1,2,4-triazol-1-yl)pent-3-yne-2-ol (1801919-59-4)+SX, (R)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1,2,4-triazol-1-yl)propane-2-ol (1616236-94-2)+SX, (R)-1-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-cyclopropyl-2-(1,2,4-triaz 1-1-yl)ethanol (1801919-60-7)+SX, (R)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-3-methyl-1-(1,2,4-triazol-1-yl)butane-2-ol (1801919-61-8)+SX, 3-[5-(4-chlorophenyl)-2,3-dimethyl-1,2-oxazolydin-3-yl]pyridine (847749-37-5)+SX, Agrobacterium radiobactor K1025+SX, Agrobacterium radiobactor K84+SX, Bacillus amyloliquefaciens AT332+SX, Bacillus amyloliquefaciens B3 +SX, Bacillus amyloliquefaciens D747+SX, Bacillus amyloliquefaciens DB101+SX, Bacillus amyloliquefaciens DB102+SX, Bacillus amyloliquefaciens GB03+SX, Bacillus amyloliquefaciens FZB24+SX, Bacillus amyloliquefaciens FZB42+SX, Bacillus amyloliquefaciens IN937a+SX, Bacillus amyloliquefaciens MBI600+SX, Bacillus amyloliquefaciens QST713+SX, Bacillus amyloliquefaciens isolate B246+SX, Bacillus amyloliquefaciens F727+SX, Bacillus licheniformis HB-2+SX, Bacillus licheniformis SD3086+SX, Bacillus pumilus AQ717+SX, Bacillus pumulis BUF-33+SX, Bacillus pumulis GB34+SX, Bacillus pumulis QST2808+SX, Bacillus simplex CGF2856+SX, Bacillus subtilis AQ153+SX, Bacillus subtilis AQ743+SX, Bacillus subtilis BU1814+SX, Bacillus subtilis D747+SX, Bacillus subtilis DB101+SX, Bacillus subtilis FZB24+SX, Bacillus subtilis GB03+SX, Bacillus subtilis HAI0404+SX, Bacillus subtilis IAB/BS03+SX, Bacillus subtilis MBI600 SX, Bacillus subtilis QST30002/AQ30002+SX, Bacillus subtilis QST30004/AQ30004+SX, Bacillus subtilis QST713+SX, Bacillus subtilis QST714+SX, Bacillus subtilis var. Amyloliquefaciens FZB24+SX, Bacillus subtilis Y1336+SX, Burkholderia cepacia+SX, Burkholderia cepacia type Wisconsin J82+SX, Burkholderia cepacia type Wisconsin M54+SX, Candida oleophilaO+SX, Candida saitoana+SX, Chaetomium cupreum+SX, Clonostayhys rosea+SX, Coniothyrium minitans CGMCC8325+SX, Coniothyrium minitans CON/M/91-8+SX, Cryptococcus albidus+SX, Erwinia carotovora subsp. carotovora CGE234M403+SX, Fusarium oxysporum Fo47+SX, Gliocladium catenulatum J1446+SX, Paenibacillus polymyxa AC-1+SX, Paenibacillus polymyxa BS-0105+SX, Pantoea agglomerans E325+SX, Phlebiopsis gigantea VRA1992+SX, Pseudomonas aureofaciens TX-1+SX, Pseudomonas chlororaphis 63-28+SX, Pseudomonas chlororaphis MA342+SX, Pseudomonas fluorescens 1629RS+SX, Pseudomonas fluorescens A506+SX, Pseudomonas fluorescens CL145A+SX, Pseudomonas fluorescens G7090+SX, Pseudomonas sp. CAB-02+SX, Pseudomonas syringae 742RS+SX, Pseudomonas syringae MA-4+SX, Pseudozyma flocculosa PF-A22UL+SX, Pseudomonas rhodesiae HAI-0604+SX, Pythium oligandrum DV74+SX, Streptomyces griseoviridis K61+SX, Streptomyces lydicus WYCD108US+SX, Streptomyces lydicus WYEC108+SX, Talaromyces flavus SAY-Y-94-01+SX, Talaromyces flavus V117b+SX, Trichoderma asperellum ICC012+SX, Trichoderma asperellum SKT-1+SX, Trichoderma asperellum T34+SX, Trichoderma atroviride CNCM 1-1237+SX, Trichoderma atroviride LC52+SX, Trichoderma atroviride SCI+SX, Trichoderma atroviride SKT-1+SX, Trichoderma gamsii ICC080+SX, Trichoderma harzianum 21+SX, Trichoderma harzianum DB104+SX, Trichoderma harzianum DSM 14944+SX, Trichoderma harzianum ESALQ-1303+SX, Trichoderma harzianum ESALQ-1306+SX, Trichoderma harzianum IIHR-Th-2+SX, Trichoderma harzianum+SX, Trichoderma harzianum MO1+SX, Trichoderma harzianum SF+SX, Trichoderma harzianum T22+SX, Trichoderma harzianum T39+SX, Trichoderma harzianum TEM908+SX, Trichoderma harzianum TH35+SX, Trichoderma polysporm IM1206039+SX, Trichoderma stromaticum+SX, Trichoderma virens G-41+SX, Trichoderma virens GL-21+SX, Trichoderma viride+SX, Variovorax paradoxus CGF4526+SX, and Harpin protein+SX.

Combination of the Present ingredient of the above Group (c) and the Present compound Z:

1-methylcyclopropene+SX, 2,3,5-triiodobenzoic acid+SX, IAA ((1H-indol-3-yl)acetic acid)+SX, IBA (4-(1H-indol-3-yl)butyric acid)+SX, MCPA (2-(4-chloro-2-methylphenoxy)acetic acid)+SX, MCPB (4-(4-chloro-2-methylphenoxy)butyric acid)+SX, 4-CPA (4-chlorophenoxyacetic acid)+SX, 5-aminolevulinic acid hydrochloride+SX, 6-benzylaminopurine+SX, abscisic acid+SX, AVG (aminoethoxyvinylglycine)+SX, ancymidol+SX, butralin+SX, calcium carbonate+SX, calcium chloride+SX, calcium formate+SX, calcium peroxide+SX, calcium polysulfide+SX, calcium sulfate+SX, chlormequat-chloride+SX, chlorpropham+SX, choline chloride+SX, cloprop+SX, cyanamide+SX, cyclanilide+SX, daminozide+SX, decan-1-ol +SX, dichlorprop+SX, dikegulac+SX, dimethipin+SX, diquat+SX, ethephon+SX, ethychlozate+SX, flumetralin+SX, flurprimidol+SX, forchlorfenuron+SX, Gibberellin A+SX, Gibberellin A3+SX, inabenfide+SX, Kinetin+SX, maleic hydrazide+SX, mefluidide+SX, mepiquat-chloride+SX, oxidized glutathione+SX, pacrobutrazol+SX, pendimethalin+SX, prohexandione-calcium+SX, prohydrojasmon+SX, pyraflufen-ethyl+SX, sintofen+SX, sodium 1-naphthaleneacetate+SX, sodium cyanate+SX, streptmycin+SX, thidiazuron+SX, triapenthenol+SX, Tributos+SX, trinexapac-ethyl+SX, uniconazole-P+SX, 2-(naphthalene-1-yl)acetamide+SX, [4-oxo-4-(2phenyethyl)amino]butyric acid+SX, Methyl 5-(trifluoromethyl)benzo[b]thiophen-2-carboxylate+SX, 3-[(6-chloro-4-phenylquinazolin-2-yl)amino]-1-propanol+SX, formononetin+SX, Glomus spp.+SX, Glomus intraradices+SX, Glomus mosseae+SX, Glomus aggregatum+SX, Glomus etunicatum+SX, Bradyrhizobium elkani+SX, Bradyrhizobium japonicum+SX, Bradyrhizobium lupini+SX, Rhizobium leguminosarum bv. trifolii+SX, Rhizobium leguminosarum bv. phaseoli+SX, Rhizobium leguminosarum bv. viciae+SX, Sinorhizobium meliloti+SX, Rhizobium spp.+SX, Rhizobium fredii+SX, Rhizobium loti+SX, Rhizobium trifolii+SX, Rhizobium tropici+SX, 1,3-diphenylurea+SX, Claroideoglomus etunicatum+SX, Funneliformis mosseae+SX, Gigaspora margarita+SX, Gigaspora rosea+SX, Glomus aggregatum+SX, Glomus deserticola+SX, Glomus monosporum+SX, Paraglomus brasillianum+SX, Rhizophagus clarus+SX, Rhizophagus intraradices RTI-801+SX, Rhizophagus irregularis DACM 197198+SX, Azorhizobium caulinodans+SX, Azospirillum amazonense+SX, Azospirillum brasilense XOH+SX, Azospirillum brasilense Ab-V5+SX, Azospirillum brasilense Ab-V6+SX, Azospirillum caulinodans+SX, Azospirillum halopraeferens+SX, Azospirillum irakense+SX, Azospirillum lipoferum+SX, Bradyrhizobium elkanii SEMIA 587+SX, Bradyrhizobium elkanii SEMIA 5019+SX, Bradyrhizobium japonicum TA-11+SX, Bradyrhizobium japonicum USDA 110+SX, Bradyrhizobium liaoningense+SX, Bradyrhizobium lupini+SX, Delftia acidovorans RAY209+SX, Mesorhizobium ciceri+SX, Mesorhizobium huakii+SX, Mesorhizobium loti+SX, Rhizobium etli+SX, Rhizobium galegae+SX, Rhizobium leguminosarum bv. Phaseoli+SX, Rhizobium leguminosarum bv. Trifolii+SX, Rhizobium leguminosarum bv. Viciae+SX, Rhizobium tropici+SX, Sinorhizobium fredii+SX, and Sinorhizobium meliloti+SX

Combination of the Present ingredient of the above Group (d) and the Present compound Z:

allidochlor+SX, benoxacor+SX, cloquintocet+SX, cloquintocet-mexyl+SX, cyometrinil +SX, cyprosulfamide+SX, dichlormid+SX, dicyclonone+SX, dimepiperate+SX, disulfoton+SX, dymron+SX, fenchlorazole+SX, fenchlorazole-ethyl+SX, fenclorim+SX, flurazole+SX, furilazole+SX, fluxofenim+SX, Hexim+SX, isoxadifen+SX, isoxadifen-ethyl+SX, mecoprop+SX, mefenpyr+SX, mefenpyr-ethyl+SX, mefenpyr-diethyl+SX, mephenate+SX, metcamifen+SX, oxabetrinil+SX, 1,8-naphthalic anhydride+SX, 1,8-octamethylene diamine+SX, AD-67 (4-(dicloroacetyl)-1-oxa-4-azaspiro[4.5]decane)+SX, CL-304415 (4-carboxy-3,4-dihydro-2H-1-benzopyran-4-acetic acid)+SX, CSB (1-bromo-4-[(chloromethyl)sulfonyl]benzene)+SX, DKA-24 (2,2-dichloro-N-[2-oxo-2-(2-propenylamino)ethyl]-N-(2-propenyl)aetamide)+SX, MG191 (2-(dichloromethyl)-2-methyl-1,3-dioxolane)+SX, MG-838 (2-propenyl 1-oxa-4-azaspiro[4,5]decane-4-carbodithioate) +SX, PPG-1292 (2,2-dichloro-N-(1,3-dioxan-2-ylmethyl)-N-(2-propenyl)acetamide)+SX, R-28725 (3-(dichloroacetyl)-2,2-dimethyl-1,3-oxazolidine)+SX, R-29148 (3-(dichloroacetyl)-2,2,5-trimethyl-1,3-oxazolidine)+SX, and TI-35 (1-(dichloroacetyl)azepane)+SX.

Combination of the Present ingredient of the above Group (e) and the Present compound Z:

1-dodecyl-1 H-imidazole+SX, N-(2-ethylhexyl)-8,9,10-trinorborn-5-ene-2,3-dicarboximide+SX, bucarpolate+SX, N,N-dibutyl-4-chlorobenzenesulfonamide+SX, dietholate+SX, diethylmaleate+SX, piperonyl butoxide+SX, piperonyl cyclonene+SX, piprotal+SX, propyl isome+SX, safroxan+SX, sesamex+SX, sesamolin+SX, sulfoxide+SX, Verbutin+SX, DMC (1,1-bis(4-chlorophenyl)ethanol)+SX, FDMC (1,1-bis(4-chlorophenyl)-2,2,2-trifluoroethanol)+SX, ETN (1,2-epoxy-1,2,3,4-tetrahydronaphthalene)+SX, ETP (1,1,1-trichloro-2,3-expoxypropane)+SX, PSCP (phenylsaligenin cyclic phosphate)+SX, TBPT (S,S,S-tributyl phosphorotrithioate)+SX, and TPP (triphenyl phosphate)+SX.

Combination of the Present ingredient of the above Group (f) and the Present compound Z:

anthraquinone+SX, chloralose+SX, acrep+SX, butopyronoxyl+SX, camphor+SX, d-camphor+SX, arboxide+SX, dibutyl phthalate+SX, deet+SX, dimethyl carbate+SX, dimethyl phthalate+SX, dibutyl succinate+SX, dibutyl adipate+SX, ethohexadiol+SX, hexamide+SX, icaridin+SX, methoquin-butyl+SX, methylneodecanamide+SX, 2-(octylthio)ethanol+SX, butoxypolypropylene glycol+SX, oxamate+SX, quwenzhi+SX, quyingding+SX, zengxiaon+SX, rebemide+SX, copper naphthenate+SX, and zinc naphthenate+SX.

Combination of the Present ingredient of the above Group (g) and the Present compound Z

bis(tributyltin) oxide+SX, allicin+SX, bromoacetamide+SX, cloethocarb+SX, copper sulfate+SX, fentin+SX, ferric phosphate+SX, metaldehyde+SX, niclosamide+SX, pentachlorophenol+SX, sodium pentachlorophenoxide+SX, tazimcarb+SX, tralopyril+SX, and trifenmorph+SX.

Combination of the Present ingredient of the above Group (h) and the Present compound Z:

(E)-2-hexenal+SX, (E)-2-octadecenal+SX, (E)-4-tridecen-1-yl acetate+SX, (E)-5-decen-1-yl acetate+SX, (E)-5-decen-1-ol+SX, (E)-3,3-dimethylcyclohexylideneacetaldehyde+SX, (E)-7-dodecen-1-yl acetate+SX, (E)-8-dodecen-1-yl acetate+SX, (E)-9-dodecen-1-yl acetate+SX, (E)-10-hexadecenal+SX, (E)-11-hexadecen-1-yl acetate+SX, (E)-11-tetradecen-1-yl acetate +SX, (E)-11-tetradecen-1-ol+SX, (E)-4-tridecen-1-yl acetate+SX, (E)-6-methylhept-2-en-4-ol+SX, (Z)-2-(3,3-dimethylcyclohexylidene)ethanol+SX, (Z)-4-decen-1-yl acetate+SX, (Z)-4-tridecen-1-yl acetate+SX, (Z)-5-decen-1-yl acetate+SX, (Z)-5-decen-1-ol+SX, (Z)-7-tetradecenal+SX, (Z)-7-dodecen 1-yl acetate+SX, (Z)-8-dodecen-1-yl acetate+SX, (Z)-9-dodecen-1-yl acetate+SX, (Z)-8-dodecen-1-ol+SX, (Z)-9-hexadecenal+SX, (Z)-10-hexadecen-1-yl acetate +SX, (Z)-11-hexadecen-1-ol+SX, (Z)-11-hexadecenal+SX, (Z)-11-hexadecen-1-yl acetate+SX, (Z)-11-octadecenal+SX, (Z)-13-octadecenal+SX, (Z)-hexadec-13-en-11-yn-1-yl acetate+SX, (Z)-13-octadecenal+SX, icos13-en-10-one+SX, (Z)-7-tetradecenal+SX, (Z)-tetradec-9-en-1-ol+SX, (Z)-9-tetradecen-1-yl acetate+SX, (Z)-11-tetradecen-1-yl acetate+SX, (Z)-13-icosen-10-one+SX, (Z,E)-7,11-hexadecadien-1-yl acetate+SX, (Z,E)-9,12-tetradecadien-1-yl acetate)+SX, (E,Z)-4,10-tetradecadien-1-yl acetate+SX, (E,E)-10-dodecadien-1-ol+SX, (E,E)-10,12-hexadecadienal+SX, (E,E)-9,11-tetradecadien-1-yl acetate+SX, (E,Z)-2,13-octadecadien-1-ol+SX, (E,Z)-3,13-octadecadien-1-ol+SX, (E,Z)-2,13-octadecadien-1-yl acetate+SX, (E,Z)-3,13-octadecadien-1-yl acetate+SX, (E,Z)-7,9-dodecadien-1-yl acetate+SX, (E,E)-7,8-dodecadien-1-yl acetate+SX, (Z,E)-9,12-tetradecadien-1-yl acetate+SX, (Z,E)-9,11-tetradecadien-1-yl acetate+SX, (Z,E)-7,11-hexadecadien-1-yl acetate+SX, (Z,Z)-3,13-octadecadien-1-ol+SX, (Z,Z)-4,7-decadien-1-yl acetate+SX, (Z,Z)-3,13-octadecadien-1-yl acetate+SX, (Z,Z)-7,11-hexadecadien-1-yl acetate+SX, (Z,Z,E)-7,11,13-hexadecatrienal+SX, (5R)-5-[(1Z)-1-decen-1-yl]dihydro-2(3H)-furanone+SX, (2R,5R)-ethyl-1,6-dioxaspiro[4,4]nonane+SX, (2R,5S)-ethyl-1,6-dioxaspiro[4,4]nonane+SX, (4R,8R)-4,8-dimethyldecanal+SX, (4R,8S)-4,8-dimethyldecanal+SX, 2,4-dimethyl-5-ethyl-6,8-dioxabicyclo[3,2,1]octane+SX, (−)-4-methyl-3-heptanol+SX, 1,7-dioxaspiro[5,5]undecane+SX, 3-carene+SX, methylcyclohex-2-en-1-one+SX, 14-methyloctadec-1-ene+SX, 4-methylnonan-5-ol+SX, 4-methylnonan-5-one+SX, 4-(3-oxobutyl)phenyl acetate+SX, dodecyl acetate+SX, dodeca-8,10-dien-1-yl acetate+SX, ethyl (2E,4Z)-decadienoate+SX, ethyl 4-methyloctanoate+SX, methyl 2,6,10-trimethyldodecanoate+SX, tetradecan-1-ol+SX, tetradec-11-en-1-ol+SX, tetradec-11-en-1-yl acetate+SX, tridec-4-en-1-yl acetate+SX, (3S,6R)-3-methyl-6-isopropenyl-9-decen-1-yl acetate+SX, (3S,6S)-3-methyl-6-isopropenyl-9-decen-1-yl acetate+SX, alpha-multistriatin+SX, alpha-pinine+SX, endo-brevicomin+SX, exo-brevicomin+SX, camphene+SX, codlelure+SX, codlemone+SX, cuelure+SX, disparlure+SX, dominicalure+SX, eugenol+SX, farnesol+SX, ferrolure+SX, frontalin+SX, gossyplure+SX, grandlure+SX, grandlure I+SX, grandlure II+SX, grandlure III+SX, grandlure IV+SX, hexalure+SX, ipsdienol+SX, ipsenol+SX, japonilure+SX, lineatin+SX, litlue+SX, looplure+SX, medlure+SX, megatomoic acid+SX, methyl eugenol+SX, muscalure+SX, nerolidol+SX, orfralure+SX, oryctalure+SX, ostramone+SX, rhyncolure+SX, siglure+SX, sordidin+SX, sulcatol+SX, trimedlure+SX, trimedlure A+SX, trimedlure B1+SX, trimedlure B2+SX, trimedlure C+SX, trunc-call+SX, (E)-verbenol+SX, (Z)-verbenol+SX, trans-verbenol+SX, and (S)-verbenone+SX.

The ratio of the Present compound Z to the Present ingredient includes, but not limited thereto, as a ration by weight (the Present compound Z: the Present ingredient) 1,000:1 to 1:1,000, 500:1 to 1:500, 100:1 to 1:100, 50:1 to 1:50, 20:1 to 1:20, 10:1 to 1:10, 3:1 to 1:3, 1:1 to 1:500, 1:1 to 1:100, 1:1 to 1:50, 1:1 to 1:20, or 1:1 to 1:10, abd the others.

Examples of the pests on which the present compound Z or the present composition has efficacies include harmful arthropods such as harmful insects and harmful mites, harmful nematodes, and harmful molluscs, and specific examples of the harmful arthropods include the followings, but which are not limited thereto.

Hemiptera pests:

Delphacidae (for example, Laodelphax striatellus, Nilaparvata lugens, Sogatella furcifera, Peregrinus maidis, Javesella pellucida, Perkinsiella saccharicida, or Tagosodes orizicolus);

Cicadellidae (for example, Nephotettix cincticeps, Nephotettix virescens, Nephotettix nigropictus, Recilia dorsalis, Empoasca onukii, Empoasca fabae, Dalbulus maidis, or Cofana spectra);

Cercopidae (for example, Mahanarva posticata, or Makanarva fimbriolata);

Aphididae (for example, Aphis fabae, Aphis glycines, Aphis gossypii, Aphis pomi, Aphis spiraecola, Myzus persicae, Brachycaudus helichrysi, Brevicoryne brassicae, Rosy apple aphid (Dysaphis plantaginea), Lipaphis erysimi, Macrosiphum euphozbiae, Aulacorthum solani, Nasonovia ribisnigri, Rhopalosiphum padi, Rhopalosiphum maidis, Toxopteza citricidus, Hyalopterus pruni, Melanaphis sacchari, Tetraneura nigriabdominalis, Ceratovacuna lanigera, or Eriosoma lanigerum);

Phylioxeridae (for example, Daktulosphaira vitifoliae, Pecan phylloxera (Phylloxera devastatrix), Pecan leaf Phylloxera (Phylloxera notabilis), or Southern pecan leaf Phylloxera (Phylloxera russellae));

Adelgidae (for example, Adelges tsugae, Adelgas piceae, or Aphrastatsia pectinatae);

Pentatomidae (for example, Scotinophara lurida, Malayan rice black bug (Scotinophara coarctate) Nezara antennata, Eysarcoris aeneus, Eysarcoris lewisis, Eysarcaris ventralis, Eysarcoris annamita, Halyomorpha halys, Nezara viridula, Brown stink bug (Euschistus heros), Red banded stink bug (Piezodorus guildinii), Oebalus pugnax, Dichelops melacanthus);

Cydnidae (for example, Burrower brown bug (Scaptocoris castanea));

Alydidae (for example, Rilotortus pedestris, Leptocorisa chinensis, or Leptocorisa acuta);

Coreidae (for example, Cletus punctiger, or Leptoglossus australis);

Lygaeidae (for example, Caverelius saccharivorus, Togo hemipterus, or Blissus leucopterus);

Miridae (for example, Trigonotylus caelestialium, Stenotus rubrovittatus, Stenodema calcarata, or Lygus lineolaris);

Aleyrodidae (for example, Trialeurodes vaporariorum, Bemisia tabaci, Dialeurodes citri, Aleuaocanthus spiniferus, Aleurocanthus camelliae, or Pealius euryae);

Diaspididae (for example, Abgrallaspis cyanophylli, Aonidiella aurantii, Diaspidiotus perniciosus, Pseudaulacaspis pentagona, Unaspis yanonensis, or Unaspis citri);

Coccidae (for example, Ceroplastes rubens);

Margarodidae (for example, Icerya purchasi, or Icerya seychellarum);

Pseudococcidae (for example, Phenacoccus solani, Phenacoccus solenopsis, Planococcus kraunhiae, Planococcus comstocki, Planococcus citri, Pseudococcus calceolariae, Pseudococcus longispinus, or Brevennia rehi);

Psyllidae (for example, Diaphorina citri, Trioza erytreae, Cacopsylla pyrisuga, Cacopsylla chinensis, Bactericera cockerelli, or Pear psylla (Cacopsylla pyricole));

Tingidae (for example, Corythucha ciliata, Corythucha marmorata, Stephanitis nashi, or Stephanitis pyrioides);

Cimicidae (for example, Cimex lectulerius);

Cicadidae (for example, Giant Cicada (Quesada gigas)); and

Triatoma spp. (for example, Triatoma infestans).

Lepidoptera

Crambidae (for example, Chilo suppressalis, Darkheaded stem borer (Chilo polychrysus), White stem borer (Scirpophaga innotata), Scirpophaga incertulas, Rupela albina, Cnaphalocrocis medinalis, Marasmia patnalis, Marasmia exigua, Notarcha derogata, Ostrinia furnacalis, European corn borer (Ostrinia nubilalis), Hellula undalis, Herpetogramma luctuosale, Pediasia teterrellus, Nymphua depunctalis, or Sugarcane borer (Diatraea saccharalis));

Pyralidae (for example, Elasmpalpus lignosellus or Plodia interpunctella);

Noctuidae (for example, Spodoptera litura, Spodoptera exigua, Mythimna separata, Memestra brassicae, Sesamia inferens, Spodoptera mauritia, Narang aenescens, Spodoptera frugiperda, Spodoptera exempta, Agrotis ipsilon, Autographa nigrisigna, Plusia festucae, Soybean looper (Chrysodeixis includens), Trichoplusia spp., Heliothis spp. (for example, Heliothis virescens), Helicoverpa armigera, Helicoverpa spp. (for example, Helicoverpa zea), Velvetbean caterpillar (Antiarsia gemmatalis), Cotton leafworm (Alabama argillacea), or Hop vine borer (Hydraecia immanis)),

Pieridae (for example, Pieris rapae);

Tortricidae (for example, Grapholita molesta, Grapholita dimorphs, Leguminivora glycinivorella, Matsumuraeses azukivora, Adoxophyes orana fasciata, Adoxophyes honmai, Homona magnanima, Archips fuscocupreanus, Cydia pomonella, Tetramoera schistaceana, Bean Shoot Borer (Epinotia aporema), or Citrus fruit borer (Ecdytolopha aurantiana));

Gracillariidae (for example, Caloptilia theivora, or Phyllonorycter ringoniella);

Carposinidae (for example, Carposina sasakii);

Lyonetiidae (for example, Coffee Leaf miner (Leucoptera coffeela), Lyonetia clerkella, or Lyonetia prunifoliella);

Lymantriidae (for example, Lymantria spp. (for example, Lymantria dispar), or Euproctis spp. (for example, Euproctis pseudoconspersa);

Pluteliidae (for example, Plutella xylostella);

Gelechiidae (for example, Anarsia lineatella, Helcystogramma triannulellun, Pectinophora gossypiella, Phthorimaea operculella, or Tuta absolut);

Arctiidae (for example, Hyphantria cunea);

Castniidae (for example, Giant Sugarcane borer (Telchin licus));

Cossidae (for example, Cosus insularis);

Geometridae (for example, Ascotis selenaria);

Limacodidae (for example, Parasa lepida);

Stathmopodidae (for example, Stathmopoda masinissa);

Sphingidae (for example, Acherontic lachesis);

Sesiidae (for example, Nokona feralis);

Hesperiidae (for example, Parnara guttate); and

Tinedae (for example, Tinea translucens or Tineola bisselliella).

Thysanoptera

Thripidae (for example, Frankliniella occidentalis, Thrips palmi, Scirtothrips dorsalis, Thrips tabaci, Frankliniella intonsa, Stenchaetothrips biformis, or Echinothrips americanus); and

Phlaeothripidae (for example, Haplothrips aculeatus).

Diptera

Anthomyiidae (for example, Delia platura or Delia antigua);

Ulidiidae (for example, Tetanops myopaeformis);

Agromyzidae (for example, Agromyza oryzae, Liriomyza sativae, Liriomyza trifolii, or Chromatomyi horticola);

Chloropidae (for example, Chlorops oryzae);

Tephritidae (for example, Bactrocera cucurbitae, Bactrocera dorsalis, Bactrocera latifrons, Bactrocera oleae, Bactrocera tryoni, or Ceratitis capitata);

Ephydridae (for example, Hydrellia griseala, Hydrellia philippina, or Hydrellia sasakii);

Drosophilidae (for example, Drosophila suzukii);

Phoridae (for example, Megaselia spiracularis);

Psychodidae (for example, Clogmia albipunctata);

Salaridae (for example, Bradysia difformis);

Cecidomyiidae (for example, Mayetiola destructor, or Orseolia oryzae);

Diopsidae (for example, Diopsis macrophthalma);

Tipulidae (for example, Tipula aino, Common cranefly (Tipula oleracea), or European cranefly (Tipula paludosa)).

Culicidae (for example, Culex pipiens pallens, Aedes aegypti, Aedes albopicutus, Anopheles hyracanus sinesis, Culex quinquefasciatus, Culex pipiens molestus Forskal, or Culex quinquefasciatus);

Simulidae (for example, Prosimulium yezoensis, or Simulium ornatum);

Tabanidae (for example, Tabanus trigonus);

Muscidae (for example, Musca domestica, Muscina stabulans, Stomoxys calcitrans, or Haematobia irritans);

Calliphoridae;

Sarcophagidae;

Chironomidae (for example, Chironomus plumosus, Chironomus yoshimatsui, or Glyptotendipes tokunagai); and

Fannidae.

Coleoptera

Chrysomelidae (for example, Diabrotica virgifera virgifera, Diabrotica undecimpuictata howardi, Diabrotica barberi, Diabrotica virgifera zeae, Diabrotica balteata, Cucurbit Beetle (Diabrotica speciosa), Cerotoma trifurcate, Oulema melanopus, Aulacophora femoralis, Phyllotreta striolata, Cabbage flea beetle (Phyllotreta cruciferae), Western black flea beetle (Phyllotreta pusilla), Cabbage stem flea beetle (Psylliodes chrysocephala), Leptinotarsa deceralineata, Qulema oryzae, Colaspis brunnea, Chaetocnema pulicaria, Chaetocnena confinis, Epitrix cucumeris, Dicladispa armigera, Grape colaspis (Colaspis brunnea), southern corn leaf beetle (Myochrous denticollis), Laccoptera quadrimacu, or Epitrix hirtipennis);

Carabidae (for example, Seedcorn beetle (Stenolophus lecontei), or Slender seedcorn beetle (Clivina impressifros));

Scarabaeidae (for example, Anomala cuprea, Anomala rufocuprea, Anomala albopilosa, Popillia japonica, Heptophylla picea, European Chafer (Rhizotrogus majalis), Tomarus gibbosus, Holotrichia spp., Phyllophaga spp. (for example, Phyllophaga crinita), or Diloboderus spp. (for example, Diloboderus abderus);

Curculionidae (for example, Araecerus coffeae, Cylas formicarius, Euscepes post fasciatus, Hypera postica, Sitophilus zeamais, Echinocmemus squameus, Lissorhoptrus oryzophilus, Rhabdoscelus lineatocollis, Anthonomus grandis, Sphenophorus latus, Southern Corn Bilibug (Sphenophorus callosus), Soybean stalk weevil (Sternechus subsignatus), Sgarcane wiivil (Sphenophorus levis), Scepticus griseus, Scepticus uniformis, Zabrotes subfasciatus, Tomicus piniperda, Coffee Berry Borer (Hypothenemus hampei), Aracanthus spp. (for example, Aracanthus mourei), or Curculionidae (for example, cottox root borer (Eutinobothrus brasiliensis)

Tenebrionidae (for example, Tribolium castaneum, or Tribolium confusum);

Coccinellidae (for example, Epilachna vigintioctopunctata);

Bostrychidae (for example, Lyctus brunneus);

Ptinidae;

Cerambycidae (for example, Anoplophora malasiaca, or Migdolus fryanus);

Elateridae (for example, Melanotus okinawensis, Agriotes fuscicollis, Melanotus legatus, Anchastus spp., Conoderusspp., Ctenicera spp., Limonius spp., or Aeolus spp.);

Staphylinidae (for example, Paederus fuscipes);

Dermestidae (for example, Anthrenus verbasci, or Dermestes maculate);

Anobidae (for example, Lasioderma serricorne, or Stegobium paniceum).

Orthoptera

Acrididae (for example, Locusta migratoria, Dociostaurus marcccanus, Chortoicetes terminifera, Nomadacris septemfasciata, Brown Locust (Locustana pardalina), Tree Locust (Anacridium melanorhodon), Italian Locust (Calliptamus italicus), Differential grasshopper (Melanoplus differentialis), Two striped grasshopper (Melanoplus bivittatus), Migratory grasshopper (Melanoplus sanguinipes), Red-Legged grasshopper (Melanoplus femurrubrum), Clearwinged grasshopper (Camnula pellucida), Schistocerca gregaria, Yellow-winged locust (Gastrimargus musicus), Spur-throated locust (Austracris guttulosa), Oxya yezoensis, Qxya japonica, or Patanga succincta);

Grvilotalpidae (for example, Gryllotalpa orientalis);

Gryllidae (for example, Acheta domestica, or Teleogryllus emma); and

Tettigoniidae (for example, Mormon cricket (Anabrus simplex)).

Hymenoptera

Tenthredinidae (for example, Athalia rosae, or Athalia japonica);

Formicidae (for example, Solenopsis spp. (for example, Solenopsis invicta, or Solenop geminata), Atta spp. (for example, Brown leaf-cutting ant (Atta capiquara)), Acromyrmex spp., Camponotus spp. (for example, Paraponera clavata, Ochetellus glaber, Monomorium phareonis, Linepithema humile, Formica fusca japonica, Pristomyrmex punctutus), Pheidole node, Pheidole megacephala, Camponotus japonicus, or Camponotus obscuripes), Pogonomyrmex spp. (for example, Pogonomyrmex occidentalis), Wasmania spp. (for example, Wasmania auropunctata), or Anopiolepis gracilipes)

Vespidae (for example, Vespa mandarinia japonica, Vespa simillima, Vespa analis Fabriciusi, Vespa velutina, Polistes jokahamae);

Siricidae (for example, Urooerus gigas); and Bethylidae.

Blattodea

Blattellidae (for example, Blattella germanica);

Blattidae (for example, Periplaneta fuliginosa, Periplaneta americana, Periplaneta brunnea, or Blatta orientalis);

Termitidae (for example, Reticulitermes speratus, Coptotermes formosanus, Incisitermes minor, Cryptotermes domesticus, Odontotermes formosanus, Neotermes koshunensis, Glyptotermes satsumensis, Glyptotermes nakajimai, Glyptotermes fuscus, Hodotermopsis sjostedti, Coptotermes guanqzhouensis, Reticulitermes amamianus, Reticulitermes miyatakei, Reticulitermes kanmonensis, Nasutitermes takasagoensis, Pericapritermes nitobei, Sinocapritermes mushae, or Cornitermes cumulans).

Siphonaptera

Ctenocephalidae felis, Ctenocephalides canis, Pulex irritans, Xenopsylla cheopis, Tunga penetrans, Echidnophaga gallinacea, and Nosopsyllus fasciatus.

Anoplura

Haematopinus suis, Haematopinus eurysternus, Dalmalinia ovis, Linognathus seypsus, Pediculus humanis, Pediculuc humanus corporis, Pediculus humanus humanus, and Phthirus pubis.

Mallophagida

Menoponidae such as Bovicola spp. (for example, Dalmalinia bovis, or Dalmalinia avis), Trichodectes spp. (for example, Trichodectes canis), Felocola spp. (for example, Felicola subrostrata), Lipeurus spp, (for example, Lipeurus caponis), Trimenopon spp., and Menopon spp.

Acari

Tetranychidae (for example, Tetranychus urticae, Tetranychus kanzawai, Tetranychus evansi, Panonychus citri, Panonychus ulmi, or Oligonychus spp.);

Eriophyidae (for example, Aculops pelekassi, Phyllocoptruta citri, Aculops lycopersici, Calacarus carinatus, Acaphylla theavagrans, Eriophyes chibaensi Aculus schlechtendali, Aceria diospyri, Aceria tosicheila, or Shevtchenkella sp.);

Tarsonemidae (for example, Polyphagot sonemus latus);

Tenuipalpidae (for example, Brevipalpus phoenicis);

Tuckerellidae;

Ixodidae (for example, Haemaphysalis longicornis, Haemaphysalis flava, Dermacentor taiwanensis, Dermacentor variabilis, Dermacentor andersoni, Ixodes ovatus, Ixodes persulcatus, Ixodes ricinus, Ixodes scapularis, Amblyomma americanum, Ambryomma maculatum, Boophilus microplus, Boophilus annulatus, or Rhipicephalus sanguineus);

Acaridae (for example, Tyrophagus putrescentiae, or Tyrophagus similius);

Pyroglyphidae (for example, Dermatophagoides farinae, or Dermatophagoides pteronyssinus);

Cheyletidae (for example, Cheyletus eruditus, Cheyletus malaccensis, Cheyletus moorei, or Cheyletiella yasguri);

Sarcoptidae (for example, Otodectes cynotis, or Sarcoptes scabiei);

Demodicidae (for example, Demodex canis);

Listrophoridae;

Haplochthoniidae;

Macronyssidae (for example, Ornithonyssus bacoti, or Ornithonyssus sylviarum);

Dermanyssidae (for example, Dermanyssus gallinae); and

Trombiculidae (for example, Leptotrombidium akamushi).

Araneae

Eutichuridae (for example, Cheiracanthium japonicum); and Theridiidae (for example, Latrodectus hasseltii).

Polydesmida

Paradoxosomatidae (for example, Oxidus gracilis and Nedyopus tambanus);

Isopoda

Armadillidiidae (for example, Armadillidium vulgare).

Chilopoda

Scutigeridae (for example, Thereuonema hilgendorfi); Scolopendridae (for example, Scolopendra subspinipes) and Ethopolidae (for example, Bohropolys rugosus).

Gastropoda

Limacidae (for example, Limax marginatus, or Limax flavus); Philomycidae (for example, Meghimatium bilineatum); Ampullariidae (for example, Pomacea canaliculata); and Lymnaeidae (for example, Austropeplea ollula).

Nematoda

Aphelenchoididae (for example, Aphelenchoides besseyi); Pratylenchidae (for example, Pratylenchus coffeae, Pratylenchus brachyurus, Pratylenchus neglectus, or Radopholus similis); Heteroderidae (for example, Meloidogyne javanica, Meloidogyne incognita, Meloidogyne hapla, Heterodera glycines, Globodera rostochiensis, or Globodera pallida): Hoplolaimidae (for example, Rotydenchulus reniformis); Anguinidae (for example, Nothotylenchus auris, or Ditydenchus dipsaci); Tylenchulidae (for example, Tylenchulus semipenetrans); Longidoridae (for example, Xiphinema index); Trichodoridae; and Parasitaphelenchidae (for example, Bursaphelenehus xylophilus).

The harmful insects and harmful mites to be targeted may be insects and mites whose sensitivity to the insecticides and miticides. However, when the sensitivity to chemicals is largely reduced or the resistance against chemicals is largely developed, it is desirable to use the position of the present invention comprising any insecticides and miticides other than the insecticides and the miticides to be targeted.

The present compound Z or the present composition may be used to protect plants from the plant diseases csused by insect-mediated viruses or insect-mediated bacteria.

Examples of the insect-mediated viruses are included the followings.

Rice tungro spherical virus, Rice tungro bacilliform virus, Rice grassy stunt virus, Rice ragged stunt virus, Rice stripe virus, Rice black streaked dwarf virus, Southern rice black-streaked dwarf virus, Rice gall dwarf virus, Rice hoja blanca virus, Rice yellow stunt virus, Rice yellow mottle virus, Rice dwarf virus, Northern cereal mosaic virus, Barley yellow dwarf virus, Barley mild mosaic virus, Barley yellow dwarf virus-PAV, Cereal yellow dwarf virus-RPS, Wheat yellow leaf virus, Oat sterile dwarf virus, Wheat streak mosaic virus, Maize dwarf mosaic virus, Maize stripe virus, Maize chlorotic mottle virus, Maize chlorotic dwarf virus, Maize rayado fino virus, Sugarcane mosaic virus, Fiji disease virus, Sugarcane yellow leaf virus, Soybean, mild mosaic virus, Cycas necrotic stunt, Soybean dwarf virus, Milk vetch dwarf virus, Soybean mosaic virus, Alfalfa mosaic virus, Bean yellow mosaic virus, Bean common mosaic virus, Southern bean mosaic virus, Peanut stunt virus, Broad bean wilt virus 1, Broad bean wilt virus 2, Broad bean necrosis virus, Broad bean yellow vein virus, Clover yellow vein virus, Peanut mottle virus, Tobacco streak virus, Bean pod mottle virus, Cowpea chlorotic mottle virus, Mung bean yellow mosaic virus, Soybean crinkle leaf virus, Tomato chlorosis virus, Tomato spotted wilt virus, Tomato yellow leaf curl virus, Tomato aspermy virus, Tomato infectious chlorosis virus, Potato leafroll virus, Potato virus Y, Melon yellow spot virus, Melon necrotic spot virus, Watermelon mosaic virus, Cucumber mosaic virus, Zucchini yellow mosaic virus, Turnip mosaic virus, Turnip yellow mosaic virus, Cauliflower mosaic virus, Lettuce mosaic virus, Celery mosaic virus, Beet mosaic virus, Cucurbit chlorotic yellows virus, Capsicum chlorosis virus, Beet pseudo yellows virus, Leak yellow stripe virus, Onion yellow dwarf virus, Sweet potato feathery mottle virus, Sweet potato shukuyo mosaic virus, Strawberry mottle virus, Strawberry mild yellow edge virus, Strawberry pseudo mild yellow edge virus, Strawberry crinkle virus, Strawberry vein banding virus, plum pox virus, Chrysanthemum stem necrosis virus, Impatiens necrotic spot virus, Iris yellow spot virus, Lily mottle cirus, Lilly symptomless virus, Tulip mosaic virus, and the like.

Examples of the insect-mediated bacetria are included the followings.

Candidatus Phytoplasma oryzae, Candidatus Phytoplasma asteris, Maize bushy stunt phytoplasma, Candidatus Liberbacter asiaticus, Candidatus Liberbacter africanus, Candidatus Liberbacter amer canus, and the like.

When the present ingredient is a fungicide active ingredient, the composition of the present invention can be used to control plant diseases. Examples of the plant disease include the following., Here the descriptions in a parenthesis indicates an academic name of phytopathogenic microorganism that causes the disease.

Rice diseases: blast (Magnaporthe grisea), brown spot (Cochliobolus miyabeanus), sheath blight (Rhizoctonia solani), bakanae disease (Gibberella fujikuroi), and downy mildew (Sclerophthora macrospora);

Wheat diseases: powdery mildew (Erysiphe graminis), fusarium blight (Fusarium graminearum, F. avenaceum, F. culmorum, Microdochium nivale), stem rust (Puccinia striiforruis, P. graminis, P. recondita), snow mould (Microdochium nivale, M. majus), typhulasnow snow blight (Typhula sp.), loose smut (Ustilago tritici), stinking smut (Tilletia caries, T. controversa), eyespot (Pseudocercosporella herpotrichoides), septoria leaf blotch (Septoria tritici), glume blotch (Stagonospora nodorum), tan spot (Pyrenophora tritici-repentis), Rhizoctonia seeding blight (Rhizoctonia solani), and take-all disease (Gaeumannomyces graminis);

Barley diseases: owdery mildew (Erysiphe graminis), Fusarium blight (Fusarium graminearum, F. avenaceum, F. culmorum, Microdochium nivale), stem rust (Puccinia striiformis, P. graminis, P. hordei), loose smut (Ustilago nuda), scald (Rhynchosporium secalis), scald (Rhynchosporium secalis), net blotch (Pyrenophora teres), spot blotch (Cochliobolus sativus), stripe (Pyrenophora graminea), Ramularia disease (Ramularia collo-cygni), stripe rust. (Puccinia striiformis), stun rust (Puccinia graminis), dwarf leaf rust (Puccinia hordei), loose smut (Ustilago nuda), scald (Rhynchosporium secalis), net blotch (Pyrenophora teres), spot blotch (Cochliobolus sativus), stripe (Pyrenophora graminea), Ramularia disease (Ramularia colllo-cygni), and Rrhizoctonia seeding blight (Rhizoctonia solani);

Corn diseases: rust (Puccinia sorghi), southern rust (Puccinia polysora), northern leaf blight (Setosphaeria turcica), tropical rust (Physopella zeae), southern leaf blight (Cochliobolus heterostrophus), anthracnose (Colletotrichum graminicola), gray leaf spot (Cercospora zeae-maydis), eyespot (Kabatiella zeae), phaeosphaeria leaf spot (Phaeosphaeria maydis), diplodia rot (Stenocarpella maydis, Stenocarpella macrospora), stalk rot (Fusarlum graminearum, Fusarium verticilioides, Colletotrichum graminicola), smut (Ustilgo maydis);

Cotton diseases: anthracnose (Colletotrichum gossypii), grey mildew (Ramularia areola), alternaria leaf spot (Alternaria macrospore, A. gossypii), and black root rot (Thielaviopsis brasicola);

Coffee diseases: rust (Hemileia vastatrix), and leaf spot (Cercospora coffeicola);

Rape seed diseases: Sclerotinia rot (Sclerotinia sclerotiorum), gray leaf spot (Alternaria brassicae), and root rot (Phoma lingam);

Sugar cane diseases: rust (Puccinia melanocephela, Puccinia kuehnii), and smut (Ustilago scitaminea);

Sunflower diseases; rust (Puccinia heliathi), and downy mildew (Plasmopara halstedii);

Citrus diseases: melanose (Diaporthe citri), scab (Elsinoe fawcetti), mold (Penicillium digitatum, Penicillium italicum), and Phytophthora rot (Phytophthora parasitica, Phytophthora citrophthora);

Apple diseases: blossom blight (Monilinia mali), valsa canker (Valsa ceratosperma), powdery mildew (Podosphaera leucotricha), alternaria leaf spot (Alternaria alternata apple pathotype), scab (Venturia inaequalis), bitter rot (Glomerella cingulata), blotch (Diplocarpon mali), ring rut (Botryosphaeria berengeriana), crown rot (Phytophtora cactorum);

Pear diseases: scab (Venturia nashicola, V. pirina), black spot (Alternaria alternata Japanese pear pathotype), rust (Gymnosporangium haraeanum);

Peach diseases: brown rot (Monilinia fructicola), scab (Cladosporium carpophilum), Phomopsis rot (Phomopsis sp.), and leaf curl (Taphriria deformans);

Grapes diseases: anthracnose (Elsinoe ampelina), ripe rot (Glomerella cingulata), powdery mildew (Uncinula necator), rust (Phakopsora ampelopsidis), black rot (Guignardia bidwellii), and downy mildew (Plasmopara viticola);

Japanese persimmon diseases: anthracnose (Gloeosporium kaki, Colletotrichum acutatum), and leaf spot (Cercospora kaki, Mycosphaerella nawae);

Diseases of gourd family: anthracnose (Colletotrichum lagenarium), powdery mildew (Sphaerotheca fuliginea), gummy stem blight (Didymella bryoniae), Corynespora leaf spot (Corynespora cassiicola), Fusarium wilt (Fusarium oxysporum), downy mildew (Pseudoperonospora cubensis), Phytophthora rot (Phytophthora sp.), and damping-off (Pythium sp.);

Tomato diseases: early blight (Alternaria solani), leaf mold (Cladosporium fulvum), CercosPora leaf mold (Pseudocercospora fuligena), late blight (Phytophthora infestans), and powdery mildew (Leveillula taurica);

Eggplant diseases: brown spot (Phomopsis vexans), and powdery mildew (Erysiphe cichoracearum);

Cruciferous vegetables diseases: Alternaria leaf spot (Alternaria japonica), white spot (Cercosporelia brassicae), clubroot (Plasmodiophora brassicae), downy mildew (Peronospora parasitica);

Welsh onion disease: rust (Puccinia allii);

Soybean diseases: purple stain (Cercospora kikuchii), sphaceloma scab (Elsinoe glycines), pod and stem blight (Diaporthe phaseolorum var. sojae), rust (Phakopsora pachyrhizi), target spot (Corynespora cassiicola), anthracnose (Colletotrichum glycines, C. truncatum), Rhizoctonia rot (Rhizoctonia solani), Septoria brown spot (Septoria glycines), Cercospora leaf spot (Cercospora sojina), stem rot (Sclerotinia sclerotiorum), powdery mildew (Microsphaera diffusa), Phytophthora stem and root rot (Phytophthora sojae), downy mildew (Peronospora manshurica), sudden death syndrome (Fusarium virguliforme),

Kidney bean diseases: stem rot (Sclerotinia sclerotiorum), rust (Uromyces appendiculatus), angular leaf spot (Phaeoisariopsis griseola), and anthracnose (Colletotrichum lindemuthianum);

Peanut diseases: leaf spot (Cercospora personata), brown leaf spot (Cercospora arachidicola), and southern blight (Sclerotium rolfsii);

Garden pea disease: powdery mildew (Erysaphe pisi);

Potato diseases: early blight (Alternaria solani), late blight (Phytophthora infestans), Pink rot (Phytophthora erythroseptica), powdery scab (Spongospora subterraneaf. sp. subterranea), and Verticillium wilt (Verticillium alto-atzum, Verticillium dahliae, Verticillium nigrescens;

Strawberry disease: powdery mildew (Sphaerotheca humuli);

Tea diseases: net blister blight (Exobasidium reticulatum), white scab (Elsinoe leucospila), gray blight (Pestalotiopsis sp.), and anthracnose (Colletotrichum theae-sinensis); Tobacco diseases: brown spot (Alternaria longipes), anthracnose (Collectotrichum tabacum), blue mold (Peronospora tabacina), and black shank (Phytophthora nicotianae);

Sugar beet diseases: Cercospora leaf spot (Cercospora beticola), leaf blight (Thanatephorus cucumeris), root rot (Thanatephorus cucumeris), and Aphanomyces root rot (Aphanomyces cochlioides), and rust (Uromyces betae);

Rose diseases: black spot (Diplocarpon rosae), and powdery mildew (Sphaerotheca pannosa);

Chrysanthemum diseases: leaf blight (Septoria chrysanthemi-indici), and white rust (Puccinia horiana);

Onion diseases: Botrytis leaf blight (Botrytis cinerea, B. byssoidea, B. squamosa), gray-mold neck rot (Botrytis allii), and small sclerotial neck rot (Botrytis squamosa);

Various crops diseases: Botrytis rot (Botrytis cinerea), and Sclerotinia rot (Sclerotinia sclerotiorum);

Japanese radish disease: Alternaria leaf spot (Alternaria brassicicola);

Turfgras:s diseases: dollar spot (Sclerotinia homoeocarpa), and brown pate and large patch (Rhizoctonia solani); as well as

Banana disease: Sigatoka disease (Mycosphaerella fijiensis, Myrosphaerella musicola).

Seed diseases or diseases in the early stages of the growth of various plants caused by Aspergillus spp., Penicillium spp, Fusarium spp., Gibberella spp., Tricoderma spp., Thielaviopsis spp., Rhizopus spp., Mucor spp., Corticium spp., Phoma spp., Rhizoctonia spp. or Diplodia spp.; and the like;

Viral diseases: viral diseases of several crops transmitted by Polymixa spp. or Olpidium spp.

Bacterial seedling blight of rice (Burkholderia plantarii), bacterial spot cucumber (Pseudomonas syringae pv. Lachrymans), bacterial wilt of eggplant (Ralstonia solanacearum), canker of citrus (Xanthomonas citri), and bacterial soft rot of Chinese cabbage (Erwinia carotovora).

The harmful arthropods, harmful nematodes and phytopathogenic fungus may be harmful arthropods, harmful nematodes or phytopathogenic fungus whose the sensitivity to any of the present ingredient is lowered or whose the resistance against the present ingredient is developed.

The composition for controlling harmful arthropods of the present invention comprises the compound Z of the present invention or the composition of the present invention and an inert carrier. The composition for controlling harmful arthropods of the present invention is usually prepared by mixing the compound Z of the present invention or the composition of the present invention with an inert carrier such as solid carrier, liquid carrier or gaseous carrier, and if necessary, adding surfactants and the other auxiliary agents for formulation, to formulate into emulsifiable concentrates, oil solutions, dust formulations, granules, wettable powders, flowables, microcapsules, aerosols, smoking agents, poison baits, resin formulations, shampoo formulations, paste-like formulations, foams, carbon dioxide formulations, and tablets and the others. Such formulations may be processed into mosquito repellent coils, electric mosquito repellent mats, liquid mosquito formulations, smoking agents, fumigants, sheet formulations, spot-on formulations or formulations for oral treatment. Also, the composition for controlling harmful arthropods of the present invention comprises usually 0.0001 to 95% by weight of the compound Z of the present invention or the composition of the present invention.

Examples of the solid carrier to be used in the formulation include fine powders or granules of clays (for example, kaolin clay, diatomaceous earth, bentonite, Fubasami clay, or acid white clay), dry silica, wet silica talcs, ceramics, other inorganic minerals (for example, sericite, quartz, sulfur, active carbon, or calcium carbonate) or chemical fertilizers (for example, ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, or ammonium chloride) and the others; as well as synthetic resins (for example, polyester resins such as polypropylene, polyacrylonitrile, polymethyl methacrylate or polyethylene terephthalate; nylon resins (for example, nylon-6, nylon-11, or nylon-66); polyamide resins; polyvinyl chloride, polyvinylidene chloride, vinyl chlor propylene copolymers, and the others).

Examples of the liquid carriers include water; alcohols (for example, methanol, ethanol, isopropyl alcohol, butanol, hexanol, benzyl alcohol, ethylene glycol, propylene glycol, or phenoxy ethanol); ketones (for example, acetone, methyl ethyl ketone, or cyclohexanone); aromatic hydrocarbons (for example, toluene, xylene, ethyl benzene, dodecyl benzene, phenyl xylyl ethane, or methylnaphthalere); aliphatic hydrocarbons (for example, hexane, cyclohexane, kerosene, or light oil); esters (for example, ethyl acetate, butyl acetate, isopropyl myristate, ethyl oleate, diisopropyl adipate, diisobutyl adipate, or propylene glycol monomethyl ether acetate); nitriles (for example, acetonitrile, or isobutyronitrile); ethers (for example, diisopropyl ether, 1,4-dioxane, 1,2-dimethoxyethane, diethyleneglycol dimethyl ether, diethylene glycol monomethyl ether, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, or 3-methyoxy-3-methyl-1-butanol); amides (for example, DMF, or N,N-dimethylacetamide); sulfoxides (for example, dimethyl sulfoxide); propylene carbonate; and vegetable oils (for example, soybean oil or cottonseedoil).

Examples of gaseous carrier include fluorocarbon, butane gas, liquefied petroleum was (LPG), dimethyl ether, and carbon dioxide gas.

Examples of the surfactants include nonionic surfactants such as polyoxyethylenated alkyl ethers, polyoxyethylenated alkyl aryl ethers, and polyethylene glycol fatty acid esters; and anionic surfactants such as alkyl sulfonates, alkylbenzene sulfonates and alkyl sulfates.

Examples of the other auxiliary agents for formulation include a binder, a dispersant, a colorant and a stabilizer. Specific examples include casein, gelatin, polysaccharides (for example, starch, gum arabic, cellulose derivatives and alginic acid), lignin derivatives, bentonite, water-soluble synthetic polymers (for example, polyvinyl alcohol, polyvinyl pyrrolidone and polyacrylic acids), acidic isopropyl phosphate, 2,6-di-tert-butyl-4-methylphenol, and a mixture of 2-tert-butyl-4-methoxyphenol and 3-tert-butyl-4-methoxyphenol.

Examples of base material of the resin formulation include polyvinyl chloride polymers, polyurethane and the others, and a plasticizer such as phthalate esters (for example, dimethyl phthalate, dioctyl phthalate), adipic acid esters and stearic acid may be added to these base materials, if necessary. The resin formulation can be prepared by mixing the compound of the present invention with the above-mentioned base material, kneading the mixture, followed by molding it by injection molding, extrusion molding or pressure molding and the like. The resultant resin formulation can be subjected to further molding or cutting procedure and the like, if necessary, to be processed into shapes such as a plate, film, tape, net or string shape. These resin formulations can be processed into animal collars, animal ear tags, sheet products, trap strings, gardening supports and other products.

Examples of a base material for the poison baits include bait ingredients such as grain powder, vegetable oil, saccharide and crystalline cellulose, and if necessary, with addition of antioxidants such as dibutylhydroxytoluene and nordihydroguaiaretic acid, preservatives such as dehydroacetic acid, accidental ingestion inhibitors for children and pets such as a chili powder, insect attraction fragrances such as cheese flavor, onion flavor and peanut oil.

The method for controlling harmful arthropods of the present invention is carried out by applying an effective amount of the compound Z of the present invention or the composition of the present invention to a harmful arthropod directly and/or a habitat thereof (for example, plant bodies, soil, an interior of a house, animal bodies). Also, the method for controlling harmful arthropods of the present invention may be applied to seeds. In the method for controlling harmful arthropods of the present invention, the Present compound is usually used in the form of a harmful arthropod controlling composition.

When a composition for controlling harmful arthropods of the present invention is used for controlling harmful arthropods in an agricultural field, the application dose as an amount sf the compound Z of the present invention is usually within a range from 1 to 10,000 g per 10,000 m². In the case of being applied to seeds, the application dose as an amount of the compound of the present invention is usually within a range of 0.001 to 100 g per 1 Kg seeds. When the composition for controlling harmful arthropods of the present invention is formulated into emulsifiable concentrate, wettable powder, or flowable formulation, the composition of the present invention is usually applied by diluting it with water in such a way that a concentration of the concentration of the active ingredient is within a range from 0.01 to 10,000 ppm. The granular formulation, or the dust formulation etc., is usually applied as itself without diluting it.

These formulations or an aqueous dilution thereof may be sparged directly to harmful arthropods or plants (such as crops) to be protected from harmful arthropods, and also may be applied to the soil of crop land in order to control harmful arthropods which live there.

Also, the resin preparation which is processed into a sheet or a string may be applied by winding a plant with a sheet or a string of the resin preparation, putting a string of the resin preparation around a crop so that the plant is surrounded by the string, or laying a sheet of the resin preparation on the soil surface near the root of a plant.

When the composition for controlling harmful arthropods of the present invention is used to control harmful arthropods that live inside a house, the application dose as an amount of the Present compound Z is usually within a range from 0.01 to 1,000 mg per 1 m² of an area to be treated, in the case of using it on a planar area. In the case of using it spatially, the application dose as an amount of the Present compound Z is usually within a range from 0.01 to 500 mg per 1 m³ of the space to be treated. When the composition for controlling harmful arthropods of the present invention is formulated into emulsifiable concentrates, wettable powders, flowables or the others, such formulations are usually applied after diluting it with water in such a way that a concentration of the active ingredient is within a range from 0.1 to 10,000 ppm, and then sparging it. In the case of being formulated into oil solutions, aerosols, smoking agents, poison baits and the others, such formulations are used as itself without diluting it.

When the composition for controlling harmful arthropods of the present invention is used for controlling external parasites of livestock such as cows, horses, pigs, sheep, goats and chickens and small animals such as dogs, cats, rats and mice, the agent of the present invention may be applied to the animals by a known method in the veterinary field. Specifically, when systemic control is intended, the agent of the present invention is administered to the animals as a tablet, a mixture with feed or a suppository, or by injection (including intramuscular, subcutaneous, intravenous and intraperitoneal injections). On the other hand, when non-systemic control is intended, the agent of the present invention is applied to the animals by means of spraying of the oil solution or aqueous solution, pour-on or spot-on treatment, or washing of the animal with a shampoo formulation, or by putting a collar or tag made of the resin formulations to the animal. In the case of being administered to an animal body, the dose of rhe Present compound usually within a range from 0.1 to 1,000 mg per 1 kg of an animal body weight.

Also, the Present compound Z or the Present composition may be used as an agent for controlling harmful arthropods in agricultural lands such as paddy fields, fields, turfs, and orchards. The Present compound Z or the Present composition may be controlled the harmful arthropods where lives in agricultural lands where the following plants etc., are grown.

Crops:

corn, rice, wheat, barley, rye, oat, sorghum, cotton, soybean, peanut, buckwheat, beet, rapeseed, sunflower, sugar cane, tobacco, and the others;

Vegetables:

solanaceous vegetables (for example, eggplant, tomato, pimento, pepper, or potato),

cucurbitaceous vegetables (for example, cucumber, pumpkin, zucchini, water melon, or melon),

cruciferous vegetables (for example, Japanese radish, white turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, leaf mustard, broccoli, or cauliflower),

asteraceous vegetables (for example, burdock, crown daisy, artichoke, or lettuce),

liliaceous vegetables (for example, green onion, onion, garlic, or asparagus),

ammiaceous vegetables (for example, carrot, parsley, celery, or parsnip),

chenopoddaceous vegetables (for example, spinach, or Swiss chard),

lamiaceous vegetables (for example, Perilla frutescens, mint, or basil),

strawberry, sweet potato, Dioscorea japonica, colocasia, or the others;

Flowers:

Ornamental foliage plants:

Lawn:

Fruits:

pomaceous fruits (for example, apple, pear, Japanese pear, Chinese quince, or quince),

stone fleshy fruits (for example, peach, plum, nectarine, Prunus mume, cherry fruit, apricot., or prune)

citrus fruits (for example, Citrus unshiu, orange, lemon, lime, or grapefruit),

nuts (for example, chestnut, walnuts, hazelnuts, almond, pistachio, cashew nuts, or macadamia nuts), berry fruits (for example, blueberry, cranberry, blackberry or raspberry),

grape, kaki persimmon, olive, Japanese plum, banana, coffee, date palm, coconuts, and the others;

Trees other than fruit trees:

tea, mulberry, flowering plant, roadside trees (for example, ash, birch, dogwood, Eucalyptus, Ginkgo biloba, lilac, maple, Quercus, poplar, Judas tree, Liquidambar formosana, plane tree, zelkova, Japanese arborvitae, fir wood, hemlock, juniper, Pinus, Picea, and Taxus cuspidate); and the others.

The above plants also include a plant that can be generated by a natural crossbreeding, a plant that can be generated by mutations, an F1 hybrid plant, and a genetically modified crop. Examples of the genetically modified crop include a plant modified to have the resistance to HPPD (4-hydroxyphenylpyruvate dioxygenase) inhibitors such as isoxaflutole, ALS (acetolactate synthase) inhibitors such as imazethapyr and thifensulfuron-methyl, EPSP (5-enolpyruvoylshikimate-3-phosphate synthase) inhibitors, glutamine synthetase inhibitors, PPO (protoporphyrinogen oxidase) inhibitors, or herbicides such as bromoxynil and dicamba; a plant modified to synthesize a selective toxin known to be produced in Bacillus such as Bacillus thuringiensis; and a plant modified to have a specific insecticidal activity by synthesizing a gene fragment partially corresponding to an endogenous gene derived from a harmful insect to induce the gene silencing (RNAi; RNA inerference) in the target harmful insect.

Examples of applying an effective amount of the compound Z of the present invention or the composition of the present invention to plant or soils for cultivating plants include a method of applying an effective amount of the compound Z of the present invention or the composition of the present invention to a stem and leaf, a flower, a seedling, an ear of a plant; a method of applying an effective amount of the compound Z of the present invention or the composition of the present invention to a seed or a bulb such as seed tuber (for example, a seed disinfection , a seed soaking, or a seed coating), or a method of applying an effective amount of the compound Z of the present invention or the composition of the present invention to soils before planting plants or soils after planting plants.

Specific examples of applying an effective amount of the compound Z of the present invention or the composition of the present invention to a stem and leaf, a flower, fruit, an ear of a plant include a method for applying an effective amount of the compound Z of the present invention or the composition of the present invention to a surface of plant (for example, foliage application, and trunk application), a method for applying an effective amount of the compound Z of the present invention or the composition of the present invention to a flower or a whole plant at flowering times including before flowering, during flowering, and after flowering, and a method for applying an effective amount of the compound Z of the present invention or the composition of the present invention to an ear or a whole grain at sprouting season of grain.

Also, examples a method of controlling harmful arthropods by applying an effective amount of the compound. Z of the present invention or the composition of the present invention soils before planting plants or after planting plants include a method of applying an effective amount of the compound Z of the present invention or the composition of the present invention to a root part of a crop to be protected from damage such as ingestion by harmful arthropods, and a method controlling harmful arthropods that ingest a plant by permeating and transferring an effective amount of the compound Z of the present invention or the composition of the present invention from a root into the interior of the plant body. More specifically, examples of the method of applying an effective amount of the compound of the present invention or the composition of the present invention to soils before planting plants or after planting plants include planting hole treatment (spraying into planting holes, soil mixing after planting hole treatment), plant foot treatment (plant foot spraying, soil mixing after plant foot treatment, irrigation at plant foot, plant foot treatment at a later seeding raising stage), planting furrow treatment (planting furrow spraying, soil mixing after planting furrow treatment), planting row treatment (planting row spraying, soil mixing after planting row treatment, planting row spraying at a growing stage), planting row treatment at the time of soaring (planting row spraying at the time of sowing, soil mixing after planting row treatment at the time of sowing), broadcast treatment (overall soil surface spraying, soil mixing after broadcast t eatment), side-article treatment, treatment of water surface (application to water surface, application to water surface after flooding), other soil spraying treatment (spraying of a granular formulation on leaves at a growing stage, spraying under a canopy or around a tree stem, spraying on the soil surface, mixing with surface soil, spraying into seed holes, spraying on the ground surfaces of furrows, spraying between plants), other irrigation treatment (soil irrigation, irrigation at seedling raising stage, drug solution injection treatment, irrigation of a plant part just above the ground, drug solution drip irrigation, chemigation), seedling raising box treatment (spraying into a seedling raising box, irrigation of a seedling raising box, flooding into a seedling raising box with drug solution), seedling raising tray treatment (spraying on a seedling raising tray, irrigation of a seedling raising tray, flooding into a seedling raising tray with drug solution), seedbed treatment (spraying on a seedbed, irrigation of a seedbed, spraying on a lowland rice nursery, immersion of seedlings), seedbed soil incorporation treatment (mixing with seedbed soil, mixing with seedbed soil before sowing, spraying at sowing before covering with soils, spraying at sowing after covering with soils, mixing with covering soil, and other treatment (mixing with culture soil, plowing under, mixing with surface soil, mixing with soil at the place where raindrops fall from a canopy, treatment at a planting position, spraying of a granule formulation on flower clusters, mixing with a paste fertilizer).

A bulb described herein represents discoid stems, corms, rhizomes, tubers, tuberous, seed tubers, and tuberous roots. A method for controlling harmful arthropods by applying an effective amount of the compound Z of the present invention or the composition of the present invention into a seed or a bulb include a method of applying an effective amount of the compound Z of the present invention or the composition of the present invention directly into a seed or a bulb a plant to be protected from damage such as ingestion by harmful arthropods; and a method for controlling harmful arthropods that ingest a seed by applying an effective amount of the compound Z of the present invention or the composition of the present invention in the vicinity of a seed or a bulb; and a method for controlling harmful arthropods that ingest a plant by permeating and transferring an effective amount of the compound Z of the present invention or the composition of the present invention from a seed or a bulb into the interior of the plant body. More specifically, spraying treatment, spray coating treatment, immersion treatment, impregnation treatment, coating treatment, film coating treatment, and pellet coating treatment are included. These methods can provide a preparation of a seed or a bulb that retain an effective amount of the compound. Z of the present invention or the composition of the present invention on the surface and/or into the interior thereof.

When the compound Z of the present invention or the composition of the present invention are applied to a seed or a bulb, an effective amount of the compound Z of the present invention is usually within a range of 0.001 to 100 g, preferably within a range of 0.02 to 20 g, based on 1 kg of the seed or the bulb. Also an effective amount of the composition of the present invention is usually within a range of 0.000001 to 50 g, preferably within a range of 0.0001 to 30 g of a total amount of the compound Z of the present invention and the active ingredient of the present invention, based on 1 kg of the seed or the bulb.

The plants described above are not limited specifically, as long as they are breeds that are usually cultivated.

EXAMPLES

Hereinafter, the present invention is explained in more detail by using Preparation Example, Formulation Example, and Test Example and the like, however, the present invention should not be limited to these examples.

In the below-mentioned Examples, when “present compound” is described, the term encompasses the “Present compound” and the “Present compound Z”. First, the Preparation Examples of the present compound Z are shown.

Reference Preparation Example 1-1

The mixture of 6-chloro-2-fluoropyridin-3-yl boronic acid 3.75 g, 2-bromo-3-(ethylsulfanyl)pyridine 4.66 g, [1,1-bis(diphenylphosphino)ferrocene]palladium dichloride 0.77 g, tripotassium phosphate 13.5 g, DMF 20 mL, and water 2 mL were stirred at 80° C. under argon atmosphere for 9 hours. The reaction mixtures were cooled to room temperature, and water was added to the mixtures, and the mixtures were extracted with ethyl acetate. The resulting organic layers were dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography to obtain the intermediate compound A-1 shown below 2.9 g.

Intermediate compound A-1: ¹H-NMR (CDCl₂) δ: 8.50 (1H, dd), 7.85 (1H, dd), 7.75 (1H, dd), 7.35-7.31 (2H, , 2.88 (2H, q), 1.26 (3H, t).

Reference Preparation Example 1-2

The process was carried out by using 6-chloro-4-fluoropyridin-3-yl boronic acid pinacol ester in place of 6-chloro-2-fluoropyridin-3-yl boronic acid according to the method described in Reference Preparation obtain the intermediate compound B-1 shown below.

Intermediate compound B-1: ¹H-NMR (CDCl₃) δ: 8.53 (1H, dd), 8.46 (1H, d), 7.76 (1H, dd), 7.34 (1H, dd), 7.20 (1H, d), 2.87 (2H, q), 1,25 (3H, t).

Reference Preparation Example 2-1

To the mixtures of the intermediate compound A-1 2.9 g, sodium hydride (60% in oil) 0.43 g and DMF 10 mL were added dropwise benzyl alcohol 1.1 mL under ice-cooling, and the reaction mixtures were stirred at 0° C. for 5 h. Water was added to the mixtures, and the mixtures were extracted with ethyl acetate. The resulting organic layers were dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography to obtain the intermediate compound A-2 shown below 3.31 g.

Intermediate compound A-2: ¹H-NMR (CDCl₃) δ: 8.47 (1H, dd), 7.69 (1H, dd), 7.59 (1H, d), 7.31-7.26 (6H, m), 7.04 (1H, d), 5.42 (2H, s), 2.78 (2H, q), 1.17 (3H, t).

Reference Preparation Example 2-2

The compound which was prepared according to the method described in Reference Preparation Example 2-1 and its physical property value are shown below.

Intermediate compound B-2: ¹H-NMR. (CDCl₃) ϵ: 8.50 (1H, dd), 8.22 (1H, s), 7.71 (1H, dd), 7.31-7.29 (6H, m), 6.96 (1H, s), 5.14 (2H, s), 2.81 (2H, q), 1.20 (3H, t).

Reference Preparation Example 2-

To the mixtures of the intermediate compound B-2 0.53 g and chloroform 15 mL was added mCPBA (purity 70%) 0.8 g under ice-cooling, and the mixtures were stirred at 0° C. to room temperature for 5 hours. To the mixtures was added aqueous sodium thiosulfate solution, and the mixtures were extracted with chloroform. The resulting organic layers were washed with saturated aqueous sodium bicarbonate solution, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography to obtain the intermediate compound B-3 shown below 0.35 g.

Intermediate compound B-3: ¹ H-NMR (CDCl₃) δ: 8.92 (1H, dd), 8.42 (1H, dd), 8.19 (1H, , 7.57 (1H, dd), 7.31-7.29 (3H, m), 7.23-7.21 (2H, m), 7.01 (1H, s), 5.10 (2H, s), 2.90 (2H, q), 1.10 (3H, t).

Reference Preparation Example 2-4

The compound which was prepared according to the method described in Reference Preparation Example 2-3 and its physical property value are shown below.

Intermediate compound A-6: ¹H-NMR (CDCl₃) δ: 8.91 (1H, dd), 8.40 (1H, dd), 7.63 (1H, d), 7.55 (1H, dd), 7.30-7.24 (5H, m), 7.08 (1H, d), 5.50-5.28 (2H, m), 2.78-2.71 (2H, m), 0.92 (3H, t).

Reference Preparation Example 3-1

The mixtures of the intermediate compound A-2 3.31 g and concentrated hydrochloric acid 10 mL was stirred at 80° C. for 1.5 hours. The mixtures were cooled to room temperature, and then to the mixtures was added 2M aqueous sodium hydroxide solution to adjust the pH 4. The precipitated solids were collected by filtration to obtain the intermediate compound A-3 shown below 2.03 g.

Intermediate compound A-3: ¹H-NMR (CDCl₃) δ: 8.44 (1H, d), 8.39 (1H, dd), 7.85 (1H, dd, J=8.1, 1.5 Hz), 7.30 (1H, dd), 6.94 (1H, d), 2.94 (2H, q), 1.29 (3H, t).

Reference preparation Example 3-1 A

The compounds which were prepared according to the method described in Reference Preparation Example 3-1 and their physical property values are shown below.

Intermediate compound A-7: ¹H-NMR (CDCl₃) δ: 8.91 (1H, dd), 8.41 (1H, dd), 7.64 (1H, d), 7.58 (1H, dd), 6.68 (1H, d), 3.37 (2H, q), 1.30 (3H, t).

Intermediate compound A-21: ¹H-NMR (CDCl₃) δ: 8.84 (1H, d), 8.37 (1H, d), 7.59 (1H, d), 6.64 (1H, d), 3.40 (2H, q), 1.33 (3H, t).

Intermediate compound A-25: ¹H-NMR (CDCl₃) δ: 9.13 (1H, s), 8.61 (1H, s), 7.62 (1H, d), 6,64 (1H, d), 3.46-3.43 (2H, m), 1.35 (3H, t).

Reference Preparation Example 3-2

A mixture of the intermediate compound A-38 10 g and concentrated hydrochloric acid 30 mL was stirred under reflux for 16 hours. The mixture was cooled to room temperature, and thereto was added toluene, and the mixture was concentrated under reduced pressure. The resulting solids were washed with hexane to obtain the intermediate compound A-39 shown below 8 g.

Intermediate compound A-39: ¹H-NMR (CDCl₃) δ: 8.63 (1H, d), 7.87-7.85 (1H, m), 7.73-7.68 (2H, m), 7.04 (1H, d), 3.18-3.02 (2H, m), 1.07 (3H, t).

Reference Preparation Example 3-2A

The compounds which were prepared according to the method described in Reference Preparation Example 3-2 and their physical property values are shown below.

Intermediate compound B-16: ¹H-NMR (CDCl₃) δ: 8.87 (1H, s), 8.34 (1H, s), 8.26 (1H, s), 7.89 (1H, s), 3.24-3.18 (2H, m), 1.30 (3H, t).

Intermediate compound B-20: ¹H-NMR (CDCl₃) δ: 9.16 (1H, s), 8.60 (1H, s), 8.29 (1H, s), 7.66 (1H, s), 3.25-3.19 (2H, m), 1.32-1.26

Intermediate Compound A-44

Intermediate Compound A-47

Reference Preparation Example B-3

The mixtures of the intermediate compound B-3 0.35 g, 10% palladium-carbon 100 mg, and ethyl acetate 5 mL were stirred under hydrogen atmosphere for 3 hours. The reaction mixtures were filtered through Celite (Registered Trademark), concentrated under reduced pressure to obtain the intermediate compound B-4 shown below 0.11 g.

Intermediate compound B-4: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.61 (1H, d), 8.54 (1H, s), 7.62 (1H, dd), 6.94 (1H, s), 3.08 (2H, q), 1.18 (3H, t).

Reference Preparation Example 4-1

The mixtures of the intermediate compound A-3 1.0 g, methyl iodide 0.28 mL, cesium carbonate 1.82 g, and DMF 10 mL were stirred at 0° C. for 3.5 hours. Water was added to the mixtures, and the mixtures were extracted with ethyl acetate. The resulting organic layers were dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography to obtain the intermediate compound A-4 shown below 0.55 g.

Intermediate compound A-4: ¹H-NMR (CDCl₃) δ: 8.45 (1H, dd), 7.69 (1H, dd), 7.42 (1H, d, J=7.5 Hz), 7.24 (1H, dd), 6.43 (1H, d), 3.76 (3H, s), 2.88 (2H, q), 1.26 (3H, t).

Reference Preparation Example 4-2

The compounds which were prepared according to the method described in Reference Preparation Example 4-1 and their physical property values are shown below.

Intermediate compound A-5: ¹H-NMR (CDCl₃) δ: 8.45 (1H, d), 7.70 (1H, d), 7.40 (1H, d), 7.23 (1H, dd), 6.40 (1H, d), 4.39-4.38 (2H, m), 2.91-2.85 (2H, m), 1.37 )3H, t), 1.25 (3H, t)

Intermediate compound B-5: ¹H-NMR (CDCl₃) δ: 8.93 (1H, dd), 8.45 (1H, dd), 8.16 (1H, 7.60 (1H, dd), 6.95 (1H, s), 3.83 (3H, s), 2.93 (2H, q), 1.19 (3H, t).

Intermediate Compound A-40

The compounds represented by formula (MA-1):

wherein the combination of R⁵, A¹, R³ and n represents any combinations indicated in Table 17.

TABLE 17 Intermediate compound R⁵ A¹ R³ n A-8 Pr N H 2 A-9 i-Pr N H 2 A-10 Bu N H 2 A-11 CH₂CH═CH₂ N H 2 A-12 CH₂C≡CH N H 2 A-13 CH₂c-Pr N H 2 A-14 CH₂CF₂CF₃ N H 2 A-15 Bn N H 2 A-16

N H 2 A-22 Me N Cl 2 A-26 Me N CF₃ 2 A-37 Me N H 2 A-42 Et N CF₃ 2

Intermediate compound A-8: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.34 (1H, dd), 7.52 (1H, dd), 7.39 (1H, d), 6.46 (1H, d), 4.25 (2H, m), 3.53-3.42 (2H, m), 1.85-1.74 (2H, 1.33 (3H, t), 1.01 (3H, t).

Intermediate compound A-9: ¹H-NMR (CDCl₃) δ: 8.86 (1H, dd), 8.33 (1H, dd), 7,51 (1H, dd), 7.33 (1H, t), 6.42 (1H, q), 5.18-5.14 (1H, m), 3.55-3.41 (2H, m), 1.65-1.61 (6H, m), 1.33 (3H, t).

Intermediate compound A-10: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.34 (1H, dd), 7.52 (1H, dd), 7.39 (1H, d), 6.46 (1H, d), 4.28 (2H, t), 3.48 (2H, q), 1.78-1.69 (2H, m), 1.45-1.42 (2H, m), 1.33 (3H, t), 0.97 (3H, t).

Intermediate compound A-11: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.33 (1H, dd), 7.52 (1H, dd), 7.43 (1H, d), 6.49 (1H, d), 5.98-5.89 (1H, m), 5.27-5.20 (2H, m), 4.95-4.89 (2H, m), 3.47 (2H, q), 1.32 (3H, t).

Intermediate compound A-12: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.35 (1H, dd), 7.53 (1H, dd), 7.45 (1H, d), 6.51 (1H, d), 5.11-5.00 (2H, m), 3.47 (2H, q), 2.27 (1H, t), 1.33 (3H, t).

Intermediate compound A-13: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.35 (1H, dd), 7.52 (1H, dd), 7.40 (1H, d), 6.47 (1H, d), 4.23-4.20 (2H, m), 3.48-3.44 (2H, m), 1.33 (4H, t), 0.56-0.52 (4H, m).

Intermediate compound A-14: ¹H-NMR (CDCl₃) δ: 8.88 (1H, dd), 8.35 (1H, dd), 7.55 (1H, dd), 7.47 (1H, d), 6.56 (1H, d), 5.03 (2H, br s), 3.40 (2H, q), 1.32 (3H, t).

Intermediate compound A-15: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.33 (1H, dd), 7.52 (1H, dd), 7,45 (1H, d), 7.33-7.27 (5H, m), 6.51 (1H, d), 5.64-5.42 (2H, m), 3.40-3.37 (2H, m), 1.25 (3H, t).

Intermediate compound A-16: ¹H-NMR (CDCl₃) δ: 8.88 (1H, dd), 8.36 (1H, dd), 7.66 (1H, s), 7.55 (1H, dd), 7.44 (1H, d), 6.52 (1H, d), 5.57-5.47 (2H, m), 3.54-3.37 (2H, m), 1.36 (3H, t).

Intermediate compound A-22: ¹H-NMR (CDCl₃) δ: 8.81 (1H, d), 8.33 (1H, d), 7.41 (1H, d), 6.50 (1H, d), 3.74 (3H, s), 3.50-3.46 (2H, m), 1.35 (3H, t).

Intermediate compound A-26: ¹H-NMR (CDCl₃) δ: 9.10 (1H, s), 8.57 (1H, s), 7.46 (1H, d), 6.53 (1H, d), 3.75 (3H, s), 3.52 (2H, q), 1.36 (3H, t).

Intermediate compound A-37: ¹H-NMR (CDCl₃) δ: 8.86 (1H, d), 8.34 (1H, d), 7.52-7.4 (1H, m), 7.40 (1H, d), 6.48 (1H, d), 3.72 (3H, s), 3.43 (2H, q), 1.31 (3H, t).

Intermediate compound. A-42: ¹H-NMR (CDCl₃) δ: 9.10 (1H, d), 8.55 (1H, d), 7.44 (1H, d), 6.50 (1H, d), 4.38 (2H, q), 3.61-3.54 (2H, m), 1.38 (3H, t), 1.37 (3H, t).

Intermediate compound A-45: ¹H-NMR (CDCl₃) δ: 7.93 (1H, d), 7.30 (1H, d), 6.52-6.40 (2H, m), 3.70 (3H, s), 3.37-3.30 (2H, m), 3.13 (6H, s), 1.27 (3H, t).

Intermediate compound A-48

The compounds represented by formula (MB-1):

wherein the combination of R⁵, A¹, R³ and n represents any combinations indicated in Table 18.

TABLE 18 Intermediate compound R⁵ A¹ R³ n B-9 Et N H 2 B-10 Pr N H 2 B-11 Bu N H 2 B-12 CH₂CH═CH₂ N H 2 B-13 CH₂c-Pr N H 2 B-17 Me N Cl 2 B-21 Me N CF₃ 2 B-22 i-Pr N H 2 B-23 Bn N H 2 B-24 CH₂CH₂CF₃ N H 2

Intermediate compound B-9: ¹H-NMR (CDCl₃) δ: 8.88 (1H, dd), 8.38 (1H, dd), 7.56 (1H, s), 7,53 (1H, dd), 6.62 (1H, s), 4.15-4.09 (2H, m), 3.49-3.39 (2H, m), 1,48 (3H, t), 1.30 (3H, t).

Intermediate compound B-10: ¹H-NMR (CDCl₃) δ: 8.88 (1H, dd), 8.38 (1H, dd), 7.53 (1H, s), 7.52 (1H, dd), 6.61 (1H, s), 4.10-3.92 (2H, m), 3.51-3.36 (2H, m), 1.93-1.84 (2H, m), 1.30 (3H, t), 1.01 (3H, t).

Intermediate compound B-11: ¹H-NMR (CDCl₃) δ: 8.88 (1H, dd), 8.38 (1H, dd), 7.52 (2H, dd), 6.62 (1H, s), 4.07 (2H, s), 3.44 (2H, s), 1.84-1.81 (2H, m), 1.43-1.40 (2H, m), 1.30 (3H, t), 0.98 (3H, t).

Intermediate compound B-12: ¹H-NMR (CDCl₃) δ: 8.88 (1H, dd), 8.37 (1H, dd), 7.54-7.52 (2H, m), 6.63 (1H, s), 6.00-5.90 (1H, m), 5.39 (1H, d), 5.27 (1H, d), 4.70-4.64 (2H, m), 3.49-3.44 (2H, m), 1.31 (3H, t).

Intermediate compound B-13: ¹H-NMR (CDCl₃) δ: 8.89 (1H, dd), 8.39 (1H, dd), 7.63 (1H, s), 7.53 (1H, dd), 6.63 (1H, s), 4.01-3.88 (2H, m), 3.50-3.37 (2H, m), 1.33-1.28 (4H, m), 0.74-0.70 (2H, m), 0.45 (2H, m).

Intermediate compound B-17: ¹H-NMR (CDCl₃) δ: 8.80 (1H, d), 8.34 (1H, d), 7.53 (1H, s), 6.63 (1H, s), 3.77 (3H, s), 3.57-3.49 (2H, m), 1.35 (3H, t).

Intermediate compound B-21: ¹H-NMR (CDCl₃) δ: 9.16 (1H, d), 8.68 (1H, d), 8.17 (1H, s), 6.98 (1H, s), 3.85 (3H, 2.96 (2H, q), 1.22 (3H, t).

Intermediate compound B-21: ¹H-NMR (CDCl₃) δ: 8.90 (1H, dd), 8.41 (1H, dd), 7.64 (1H, s), 7.53 (1H, dd), 6.62 (1H, s), 5.02-4.96 (1H, m), 3.41-3.29 (2H, m), 1.49 (6H, d), 1.29-1.25 (3H, m).

Intermediate compound B-23: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.37 (1H, dd), 7.62 (1H, s), 7.52 (1H, dd), 7.43-7.33 (3H, m), 7.26-7.22 (2H, m), 6.65 (1H, s), 5.27-5.23 (2H, m), 3.52-3.41 (2H, m), 1.32 (3H, t).

Intermediate compound B-24: ¹H-NMR (CDCl₃) δ: 8.89 (1H, dd), 8.38 (1H, dd), 7.54 (1H, dd), 7,53 (1H, s), 6.64 (1H, s), 4.41-4.22 (2H, m), 3.44-3.37 (2H, m), 2.77-2.63 (2H, m), 1.30 (3H, t).

Reference Preparation Example 5

The mixtures of the intermediate compound A-7 0.4 g, copper(II) acetate 0.48 g, cesium carbonate 0.43 g, cyclopropyl boronic acid 0.23 g, pyridine 0.3 mL, and xylene 2.7 mL were stirred at 110° C. for 20 hours. The resulting mitures were cooled to room temperature, and the mixtures were filtered through Celite (Registered trademark) and the filtrates were concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography to obtain the intermediate compound A-17 shown below 37 mg.

Intermediate compound A-17: ¹H-NMR (CDCl₃) δ: 8.86 (1H, dd), 8.32 (1H, dd), 7.51 (1H, dd), 7.38 (1H, d), 6.43 (1H, d), 3.52 (2H, q), 2.99-2.95 (1H, m), 1.36 (3H, t), 1.32-1.31 (2H, m), 1.03-1.00 (2H, m).

Reference Preparation Example 6-1

To the mixtures of methyl 6-chloro-2-methoxy nicotinic acid 0.5 g, ethyl methyl sulfone 5 mL and THF 12 mL was added dropwise lithium hexamethyl disilazide (1.1 M THF solution) 5 mL at −10° C. The resulting mixtures were stirred for 20 minutes, and thereto was added 6N hydrochloric acid 1 mL.

Water was added to the resulting mixtures, and the mixtures were extracted with ethyl acetate. The resulting organic layers were dried. over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography to obtain the intermediate compound A-18 shown below 0.6 cf.

Intermediate compound A-18: ¹H-NMR (CDCl₃) δ: 8.14 (1H, d), 7.06 (1H, d), 4.74 (2H, s), 4.13 (3H, s), 3.28 (2H, q), 1.44 (3H, t).

Reference Preparation Example 6-2

The compound which was prepared according to the method described in Reference Preparation Example 6-1 and its physical property value are shown below.

Intermediate compound B-6: ¹H-NMR (CDCl₃) δ: 8.69 (1H, s), 6.98 (1H, s), 4.67 (2H, s), 4.06 (3H, s)3.26 (2H, q), 1.44 (3H, t).

Intermediate compound C-2: ¹H-NMR (CDCl₃) δ: 8.81 (1H, s), 4.68 (2H, s), 4.17 (3H, s), 3.26 (2H, q), 2.61 (3H, s), 1.44 (5H, t).

Reference Preparation Example 7-1

The mixtures of theintermediate compound A-18 2.96 g, ammonium acetate 5.0 g, acetic acid 0.15 mL, and methanol 13 mL were stirred at 65° C. for 6 hours. The resulting mixtures were cooled to room temperature, and thereto was added aqueous sodium hydroxide solution. The precipitated solids were filtered, and the obtained solids were washed with water, concentrated under reduced pressure to obtain the intermediate compound A-19 shown below 2.7 g.

Intermediate compound A-19: ¹H-NMR (CDCl₃) δ: 7.67 (1H, d), 6.98 (1H, d), 6.11 (2H, br s), 4.83 (1H, s), 4.02 (3H s), 3.07 (2H, q), 1.41 (3H, t).

Reference Preparation Example 7-2

The compound which was prepared according to the method described in Reference Preparation Example 7-1 and its physical property value are shown below.

Intermediate compound B-14: ¹H-NMR (CDCl₃) δ: 8.28 (1H, s), 6.91 (1H, s), 5.95 (2H, 4.81 (1H, s), 3.95 (3H, s), 3.08 (2H, q), 1.42 (3H, t).

Intermediate compound C-3: ¹H-NMR (CDCl₃) δ: 8.38 (1H, s), 6.08 (2H, br), 4.87 (1H, s), 4.06 (3H, s), 3.08 (2H, q), 2.58 (3H, s), 1.41 (3H, t).

Reference Preparation Example 8-1

The mixtures of sodium hydride (60% in oil) 0.90 g and DMF 25 mL were cooled to 0° C., and thereto was added dropwise the intermediate compound A-19 2.71 g that was dissolved in DMF 5 mL. The resulting mixtures were stirred at 0° C. for 30 minutes, and thereto was then added 2-chloro-1,3bis(dimethylamino)trimethinium hexafluorophoshate 6.60 g, and the mixtures were stirred at 60° C. for 2 hours. The resulting mixtures were cooled to room temperature, and, water was added thereto, and the mixtures were extracted with ethyl acetate. The resulting organic layers were dried over anhydrous sodium sulfate and concentrated under reduced pressure. The esulting residue was subjected to a silica gel column chromatography to obtain the intermediate compound A-20 shown below 2.48 g Here 2-chloro-1,3-bis(dimethylamino)trimethinium hexafluo ophosphate was prepared according to the method described in J. Org. chem., 2000, 65, 4571.

Intermediate compound A-20: ¹H-NMR (CDCl₃) δ: 8.84 (1H, d), 8.43 (1H, d), 7.60 (1H, d), 7.06 (1H, d), 3.91 (3H, s), 2.97-2.87 (2H, m), 1.21 (3H, t).

Reference Preparation Example 8-2

The compound which was prepared according to the method described in Reference Preparation Example 8-1 and its physical property value are shown below.

Intermediate compound B-15: ¹H-NMR (CDCl₃) δ: 8.86 (1H, d), 8.43 (1H, d), 8.14 (1H, s), 6.95 (1H, s), 3.83 (3H, s), 2.93 (2H, q), 1.21 (3H, t).

Reference Preparation Example 8-3

The compounds which were prepared by using 2-trifluoromethyl-1,3-bis(dimethylamino)trimethinium hexafluorophosphate in place of 2-chloro-1,3-bis(dimethylamino)trimethinium hexafluorophosphate according to the method described in Reference Preparation Example 8-1 and their physical property values are shown below.

Intermediate compound A-24: ¹H-NMR (CDCl₃) δ: 9.14 (1H, d), 8.69 (1H, d), 7.62 (1H, d), 7.09 (1H, d), 3.92 (3H, s), 2.98-2.93 (2H, m), 1.22 (3H, t).

Intermediate compound B-19: ¹H-NMR (CDCl₃) δ: 9.16 (1H, d), 8.68 (1H, d), 8.17 (1H, s), 6.98 (1H, s), 3.85 (3H, s), 2.96 (2H, q), 1.22 (3H, t).

Intermediate compound C-4: ¹H-NMR (CDCl₃) δ: 9.15 (1H, 8.67 (1H, d), 8.29 (1H, s), 3.97 (3H, s), 3.02-2.99 (2H, m), 2.62 (3H, s), 1.23 (3H, t).

Reference Preparation Example 9-1

To the mixtures of DMF 0.84 mL and chloroform 24 mL was added dropwise oxalyl chloride 0.92 mL under ice-cooling. The resulting mixtures were stirred for 15 minutes under ice-cooling, and then stirred at room temperature for 2 hours. The resulting mixtures were cooled again under ice-cooling, and thereto was added butyl vinyl ether 2.8 mL, and the mixtures were stirred for 1 hour. The resulting mixtures were warmed to room temperature, and stirred for 2 hours. To the resulting mixtures were added the intermediate compound B-6 1.00 g and triethyl amine 3.5 mL successively under ice-cooling. The resulting mixtures were stirred at room temperature for 3 hours, and thereto was added saturated aqueous ammonium chloride solution, and the mixtures were extracted with chloroform. The resulting organic layers were dried over sodium sulfate, filtered and concentrated under reduced pressure. To the resulting residues were added ethanol 13 mL and 30% ammonia water 1.4 mL successively. The resulting mixtures were stirred at 60° C. for 9 hours, and concentrated under reduced pressure. Water was added to the resulting residues, and the mixtures were extracted with ethyl acetate. The resulting organic layers were washed with saturated brine, dried over anhydrous sodium sulfate, filtered, and concentrated under reduced pressure. To resulting residue were added to ethanol 13 mL and 30 aqueous ammonia 1.4 mL successively. The resulting mixture was stirred at 60° C. for 9 hours, and concentrated under reduced pressure. Water was added to the resulting residue, and the mixture was extracted with ethyl acetate. The resulting organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, filtered, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography to obtain the intermediate compound B-7 shown below 0.87 g.

Intermediate compound B-7: ¹H-NMR (CDCl₃) δ: 8.93 (1H, dd), 8.45 (1H, dd), 8.16 (1H, s), 7.59 (1H, dd), 6.95 (1H, s), 3.83 (3H, s), 2.93 (2H, q), 1.19 (3H, t).

Reference preparation Example 9-2

The compound which was prepared according to the method described in Reference Preparation Example 9-1 and its physical property value are shown below,

Intermediate compound A-27: ¹H-NMR (CDCl₃) δ: 8.91 (1H, dd), 8.45 (1H, dd), 7.61 (1H, d), 7.57 (1H, dd), 7.06 (1H, d), 3.91 (3H, s), 2.96-2.88 (2H, m), 1.19 (3H, t).

Reference Preparation Example 10-1

The mixtures of the Present compound A-18 (described in Preparation Example0.45 g, bis(pinacolato)diboron 0.37 g, tris(dibenzylideneacetone)dipalladium(0) 0.09 g, 2-dicyclohpxylphosphino-2′,4′,6′-triisopropylbiphenyl 0.14 g, potassium acetate 0.29 g, and 1,2-dimethoxyethane 9 mL were stirred at 70° C. under nitrogen atmosphere for 30 minutes. Water was added to the resulting mixtures at room temperature, and the mixtures were extracted with ethyl acetate. The resulting organic layers were washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting solids were washed with hexane to obtain the intermediate compound A-23 shown below 0.52 g.

Intermediate compound A-23: ¹H-NMR (CDCl₃) δ: 9.13 (1H, d), 8.69 (1H, d), 7.51 (1H, d), 5.67 (1H, d), 4.51 (2H, t), 3.52 (3H, s), 3.49-3.43 (2H, m), 1.37 (12H, s), 1.34 (3H, t).

Reference Preparation Example 10-2

The compound which was prepared according to the method described in Reference Preparation Example 10-1 and its physical property value are shown below.

Intermediate compound B-18: ¹H-NMR (CDCl₃) δ: 9.12 (1H, d), 8.69 (1H, d), 7.36 (1H,), 5.86 (1H, s), 4.47 (2H, t), 3.59-3.55 (5H, m), 1.35-1.26 (15H, m).

Intermediate Compound A-30

Intermediate compound B-26: ¹H-NMR (CDCl₃) δ: 7.66 (1H, s), 3.42 (3H, s), 3.33 (3H, s), 1.32 (12H, s).

Reference Preparation Example 11-1

To the mixtures of 3-bromo-6-chloro-1-methylpyridin-2(1H)-one 27.28 g, cesium carbonate 47.94 g, and DMF 100 mL was added dropwise 2,2,3,3,3-pentafluoro-1-propanol 19.32 g under ice-cooling, and the mixtures were stirred at room temperature for 3 hours. Water was added to the resulting mixtures, and the mixtures were extracted with ethyl acetate. The resulting organic layers were dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residues were washed with water and hexane successively to obtain the intermediate compound A-28 shown below 39.41 g.

Intermediate compound A-28: ¹H-NMR (CDCl₃) δ: 7.68 (1H, d), 5.46 (1H, d), 4.46 (2H, t), 3.55 (3H, s).

Reference Preparation Example 11-2

The compounds which were prepared according to the method described. in Reference Preparation Example 11-1 and their physical property values are shown below.

Intermediate compound A-29: ¹HMR (CDCl₃) δ: 7.93 (1H, s), 4.85 (2H, t), 3.52 (3H, s).

Intermediate compound A-41: ¹H-NMR (CDCl₃) δ: 8.46 (1H, d), 7.91 (1H, d), 7.54 (1H, d), 7.43 (1H, t), 5.72 (1H, d), 4.52 (2H, t), 3.53 (3H, s), 3.11-3.06 (2H, m), 1.23 (3H, t).

Reference Preparation Example 12-1

The mixtures of the intermediate compound A-28 2.0 g, 2-fluoro-4-(trifluoromethyl)phenyl boronic acid 1.24 g, [1,1′-bis(diphenylphosphino)ferrocene]palladium(II) dichloride additive 0.44 g, tripotassium phosphate 3.79 g, 1,2-dimethoxyethane 15 mL and water 1.5 mL were stirred at 80° C. for 3 hours. The resulting mixtures were stood to cool to room temperature, and water was then added thereto, and the mixtures were extracted with ethyl acetate. The resulting organic layers were dried over anhydrous sodium sulfate, and concentrated under reduce pressure. The resulting residue was subjected to a silica gel column chromatography to obtain the intermediate compound A-31 shown below 0.53 g.

Intermediate compound A-31: ¹H-NMR (CDCl₃) δ: 7.69 (1H, t), 7.51 (1H, dd), 7.44 (1H, d), 7.38 (1H, d), 5.65 (1H, d), 4.53 (2H, t), (3H, s).

Reference Preparation Example 12-2

The compound which was prepared according to the method described in Reference Preparation Example 12-1 and its physical property value are shown below.

Intermediate compound A-34: ¹H-NMR (CDCl₃) δ: 7.84 (1H, d), 7.64 (1H, t), 7.47 (1H, d), 7.42 (1H, d), 4.93 (2H, t), 3.54 (3H, s).

Reference Preparation Example 13-1

To the mixtures of the intermediate compound A-31 1.13 g, sodium hydride (60%, in oil) 0.23 g, and DMF 10 mL was added dropwise ethanethiol 0.39 mL under ice-cooling, and the mixtures were stirred at 60° C. for 9 hours. Water was added to the resulting mixtures, and the mixtures were extracted with ethyl acetate. The resulting organic layers were dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue waw subjected to a silica gel column chromatography to obtain the intermediate compound A-32 shown below 0.65 g.

Intermediate compound A-32: ¹H-NMR (CDCl₃) δ: 7.54 (1H, s), 7.41 (1H, dd), 7.36 (1H, d), 7.28 (1H, d), 6.12 (1H, d), 3.69 (3H, s), 3.03 (2H, q), 2.92 (2H, q), 1.46 (3H, t), 1.28 (3H, t).

Reference Preparation Example 13-2

The compound which was prepared according to the method described Ln Reference Preparation Example 13-1 and its physical property value are shown below.

Intermediate compound A-35: ¹H-NMR (CDCl₃) δ: 7.79 (1H, s), 7.57 (1H, s), 7.44 (1H, d), 7.34 (1H, d), 3.53 (3H, s), 3.26 (2H, q), 2.94 (2H, q), 1.44 (3H, t), 1.29 (3H, t).

Reference Preparation Example 14-1

To the mixtures of the intermediate compound A-32 0.61 g and chloroform 30 mL was added mCPBA (purity 70%, containing 30% water) 1.63 g, and the mixtures were stirred at 0° C. room temperature for 25 hours. To the resulting mixtures was added aqueous sodium thiosulfate solution and the mixtures ere extracted with chloroform. The resulting organic layers were washed with saturated aqueous sodium bicarbonate solution, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography to obtain the intermediate compound A-33 shower below 0.65 g.

Intermediate compound. A-33: ¹H-NMR (CDCl₃) δ: 8.30 (1H, d), 7.94 (1H, dd), 7.46 (1H, 7.42 (1H, d), 7.24 (1H, d), 3.90 (3H, s), 3.40-3.34 (4H, m), 1,42 (3H, t), 1.34 (3H, t).

Reference Preparation Example 14-2

The compound which was prepared according to the method described in Reference Preparation Example 14-1 and its physical property value are shown below.

Intermediate compound A-36: ¹H-NMR (CDCl₃) δ: 9.25 (1H, s), 8.36 (1H, d), 7.92 (1H, dd), 7.51 (1H, d), 7.34 (1H, d), 3.40 (3H, s), 3.25 (2H, q), 1.29 (3H, t).

Reference Preparation Example 15

The compound which was prepared by using hydroxylamine in place of 30% ammonia water according to the method described in Reference Preparation Example 9-1 and its physical property value are shown below.

Intermediate compound A-38: ¹H-NMR (CDCl₃) δ: 8.46 (1H, d), 7.96 (1H, d), 7.62 (1H, d), 7.48 (1H, t), 7.10 (1H, d), 3.93 (3H, s), 2.87-2.72 (2H, m), 1.17 (3H, t).

Reference Preparation Example 16

To a mixture of 4-methoxy-2-(methylthio)pyrimidine-5-carboxylic acid 8.38 g and methanol 90 mL was added thionyl chloride 9 mL under ice cooling, and the mixture was stirred at 85° C. for 3 hours. The resulting mixture was cooled to room temperature, and concentrated. To the resulting residue was added aqueous saturated sodium hydrogen cardonate solution, and the mixture was extracted with ethyl acetate. The resulting organic layer was dried over anhydrous sodium sulfate, and concentrated to obtain intermediate compound C-1 shown below 4.18 g.

Intermediate compound C-1: ¹H-NMR (CDCl₃) δ: 8.82 (1H, s), 4.10 (3H, s), 3.89 (3H, s), 2.59 (3H, s).

Reference Preparation Example 17

To a mixture of the intermediate compound C-4 0.51 g and acetonitrile 26 mL was added dropwise a mixture of sulfuryl chloride 0.52 mL and chloroform 32 mL over 30 minutes under ice-cooling. The resulting mixture was stirred under ice-cooling for 1 hour, and the mixture was warmed to room temperature and stirred for 6 hours. To the resulting mixture was added aqueous saturated sodium hydrogen carbonate solution, and the mixture was extracted with ethyl acetate. The resulting organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated. The resulting residue was subjected to a silica gel column chromatography to obtain the intermediate compound C-5 shown below 0.50 g.

Intermediate compound. C-5: ¹H-NMR (CDCl₃) δ: 9.17 (1H, d), 8.66 (1H, d), 8.34 (1H, s), 4.01 (3H, s), 3.05-2.98 (2H, m), 1.26 (3H, t).

Preparation Example 1

To the mixtures of the intermediate compound A-4 0.65 g, sodium hydride (60% in oil) 0.11 g, and DMF 10 mL y added dropwise 2,3,3,3-pentafluoro-1-propanol 0.28 mL under ice-cooling, and the mixtures were stirred at room temperature for 3.5 hours. Water was added to the mixtures, and the mixtures were extracted with ethyl acetate. The resulting organic layers were dried over anhydrous sodiu 1 sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography (methanol:ethyl acetate=1:19) to obtain the present compound A-2 shown below 0.73 g.

Present compound A-2: ¹H-NMR (CDCl₃) δ: 8.44 (1H, dd), 7.68 (1H, dd), 7.51 (1H, d), 7.22 (1H, dd), 5.63 (1H, d), 4.51 (2H, t), 3.55 (3H, 2.88 (2H, q), 1.26 (3H, t).

Preparation Example A

The compounds which were prepared according to the method described in Preparation Example 1 and their physical property values are shown below.

The compounds represented by formula (A-1)

wherein the combination of T, R⁵,A¹, R³ and n represents any combinations indicated in Table 19.

TABLE 19 Present com- pound T R⁵ A¹ R³ n A-4 OCH₂CF₂CF₃ Et N H 0 A-6 OCH₂CF₂CHF₂ Me N H 2 A-7 OCH₂CF₂CHFCF₃ Me N H 2 A-8 OCH₂CF₂CF₂CF₃ Me N H 2 A-9 OCH₂CF₂CF₂CF₂CF₃ Me N H 2 A-10 OCH₂CF₃ Me N H 2 A-11 OCH(CH₃)CF₃ Me N H 2 A-17

Me N H 2 A-18 OCH₂CF₂CF₃ Me N Cl 2 A-19 OCH₂CF₂CF₃ Pr N H 2 A-20 OCH₂CF₂CF₃ i-Pr N H 2 A-21 OCH₂CF₂CF₃ Bu N H 2 A-22 OCH₂CF₂CF₃ CH₂CH═CH₂ N H 2 A-23 OCH₂CF₂CF₃ Me CH CF₃ 2 A-24 OCH₂CF₂CF₃ CH₂C≡CH N H 2 A-25 OCH₂CF₂CF₃ CH₂c-Pr N H 2 A-27 OCH₂CF₂CF₃ CH₂CF₂CF₃ N H 2 A-32 OCH₂CF₂CF₃ c-Pr N H 2 A-39 OCH₂CF₂CF₃ Me N CF₃ 2 A-41 OCH₂CF₂CF₃

N H 2 A-42 OCH₂CF₂CF₃ Bn N H 2 A-55 OCH₂CF₂CHF₂ Me N CF₃ 2 A-59 OCH₂CF₂CF₃ Et N CF₃ 2 C-1 OCH₂(1-CN—c-Pr) Me N H 2 C-2 OCH₂C(Me)₂CN Me N H 2 C-7 OCH₂C(Me)₂CN Me N Cl 2 C-8 OCH₂(1-CN—c-Pr) Me N Cl 2

Present compound A-4: ¹H-NMR (CDCl₃) δ: 8.44 (1H, dd), 7.68 (1H, dd), 7.49 (1H, d), 7.22 (1H, dd), 5.60 (1H, d), 4.50 (2H, t), 4.22 (2H, q), 2.88 (2H, q), 1.28 (3H, t), 1.26 (3H, t).

Present compound A-6: ¹H-NMR (CDCl₃) δ: 8.86 (1H, d), 8.35 (1H, d), 7.52-7.47 (2H, , 6.12-5.85 (1H, m), 5.70 (1H, d), 4.46 (2H, t), 3.52 (3H, m), 3.40 (2H, t), 1.29 (3H, t).

Present compound A-7: ¹H-NMR (CDCl₃) δ: 8.85 (1H, d), 8.34 (1H, d), 7.51-7.47 (2H, m), 5.69 (1H, d), 5.14-4.97 (1H,m), 4.94-4.38 (2H, m), 3.59-3.39 (5H, m), 1.29 (3H, t).

Present compound A-8: ¹H-NMR (CDCl₃) δ: 8.86 (1H, d), 8.34 (1H, d), 7.52-7.47 (2H, m), 5.68 (1H, d), 4.54 (2H, t), 3.52 (3H, s), 3.42 (2H, s), 1.29 (3H, t).

Present compound A-9: ¹H-NMR (CDCl₃) δ: 8.85 (1H, d), 8.34 (1H, d), 7.51-7.47 (2H, m), 5.67 (1H, d), 4.55 (2H, t), 3.52 (3H, s), 3.47-3.39 (2H, m), 1.29 (3H, t).

Present compound A-10: ¹H-NMR (CDCl₃) δ: 8.85 (1H, d), 8.34 (1H, d), 7.49 (2H, d), 5.66 (1H, d), 4.54 (2H, t), 3.52 (3H, s), 3.47-3.39 (2H, m), 1.29 (3H, t).

Present compound A-11: ¹H-NMR (CDCl₃) δ: 8.85 (1H, d), 8.35 (1H, d), 7.49 (2H, t), 5.71 (1H, d), 4.78 (1H, t), 3.51 (3H, s), 3.44 (2H, s), 1.59 (3H, d), 1.29 (3H, t).

Present compound A-17: ¹H-NMR (CDCl₃) δ: 8.88 (1H, d), 8.36 (1H, d), 7.78 (1H, s), 7.56-7.54 (2H, m), 6.78 (1H, s), 6.41 1H, d), 3.47 (2H, br), 3.35 (3H, s), 1.34 (3H, t).

Present compound A-18: ¹H-NMR (CDCl₃) δ: 8.80 (1H, d), 8.33 (1H, d), 7.50 (1H, d), 5.69 (1H, d), 4.52 (2H, t), 3.53 (3H, s), 3.50-3.44 (2H, m), 1.34 (3H, t).

Present compound A-19: ¹H-NMR (CDCl₃) δ: 8.86 (1H, dd), 8.34 (1H, dd), 7.50 (1H, dd), 7.49 (1H, d), 5.66 (1H, d), 4.50 (2H, dd), 4.09 (2H, t), 3.51-3.44 (2H, m), 1.74-1.65 (2H, m), 1.32 (3H, t), 0.96 (3H, t).

Present compound A-20: ¹H-NMR (CDCl₃) δ: 8.86 (1H, dd), 8.35 (1H, dd), 7.49 (1H, dd), 7.44 (1H, d), 5.62 (2H, d), 4.50 (2H, t), 3.48-3.41 (2H, m), 1.52-1.50 (6H, m), 1.31 (3H, t).

Present compound A-21: ¹H-NMR (CDCl₃) δ: 8.86 (1H, dd), 8.34 (1H, dd), 7.49 (1H, dd), 7.48 (1H, d), 5.65 (1H, d), 4.50 (2H, t), 4.12 (2H, t), 3.47 (2H, ddd), 1.67-1.61 (2H, m), 1.39-1.33 (5H, m), 0.94 (3H, t).

Present compound A-22: ¹H-NMR (CDCl₃) δ: 8.86 (1H, dd), 8.34 (1H, dd), 7.51 (1H, d), 7.50 (1H, dd), 5.88 (1H, dddd), 5.68 (1H, d), 5.21-5.16 (2H, 4.81-4.68 (2H, m), 4.49 (2H, t), 3.50-3.44 (2H, m), 1.30 (3H, t).

Present compound A-23: ¹H-NMR (CDCl₃) δ: 8.35 (1H, d), 7.88 (1H, dd), 7.46 (1H, d), 7.39 (1H, d), 5.67 (1H, d), 4.52 (2H, t), 3.54 (3H, s), 3.30 (2H, , 1.27 (3H, t).

Present compound A-24: ¹H-NMR (CDCl₃) δ: 6.87 (1H, dd), 8.35 (1H, dd), 7.55-7.50 (2H, m), 5.71 (1H, d), 4.89 (2H, dd), 4.56 (2H, t), 3.49-3.47 (2H, m), 2.17-2.15 (1H, m), 1.32 (3H, t).

Present compound A-25: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.35 (1H, dd), 7.52-7.48 (2H, m), 5.67 (1H, d), 4.52 (2H, t), 4.10-3.97 (2H, m), 3.50-3.43 (2H,), 1.32 (3H, t,), 1.26-1.21 (1H, m), 0.53-0.47 (2H, m), 0.44-0.39 (2H, m).

Present compound A-27: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.36 (1H, dd), 7.57 (1H, d), 7.53 (1H, dd), 5.74 (1H, d), 4.85 (2H, br s), 4.54 (2H, t), 3.40 (2H, q), 1.31 (3H, t).

Present compound A-32: ¹H-NMR (CDCl₃) δ: 8.85 (1H, dd), 8.32 (1H, dd), 7.49 (1H, dd), 7.47 (1H, d), 5.60 (1H, d), 4.48 (2H, t), 3.55-3.49 (2H, m), 2.81-2.75 (1H, m), 1.35 (3H, t), 1.24-1.20 (2H, m), 0.94-0.85 (2H, m).

Present compound A-39: ¹H-NMR (CDCl₃) δ: 9.09 (1H, s), 8.57 (1H, s), 7.56 (1H, d), 5.72 (1H, d), 4.54 (2H, t), 3.54 (3H, s), 3.53 (2H, q), 1.36 (3H, t).

Present compound A-41: ¹H-NMR (CDCl₃) δ: 8.88 (1H, dd), 8.36 (1H, dd), 7.55 (1H, s), 7.55-7.52 (2H, m), 5.71 (1H, d), 5.35 (2H, d), 4.55 (2H, t), 3.45 (2H, dt), 1.35 (3H, t).

Present compound A-42: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.34 (1H, dd), 7.53 (1H, d), 7.50 (1H, dd), 7.35-7.23 (5H, m), 5.69 (1H, d), 5.43-5.25 (2H, 1), 4.45 (2H, t), 3.41 (2H, q), 1.27 (3H, t).

Present compound A-55: ¹H-NMR (CDCl₃) δ: 9.09 (1H, d), 8.57 (1H, d), 7.56 (1H, d), 6.01 (1H, tt), 5.74 (1H, d), 4.50 (2H, t), 3.56-3.50 (2H, m), 3.55 (3H, s), 1.35 (3H, t).

Present compound A-59: ¹H-NMR (CDCl₃) δ: 9.09 (1H, d), 8.55 (1H, d), 7.54 (1H, d), 5.70 (1H, d), 4.53 (2H, t), 4.20 (2H, q), 3.58 (2H, q), 1.37 (3H, t), 1.28 (3H, t).

Present compound -1: ¹H-NMR (CDCl₃) δ: 8.84 (1H, d), 8.34 (1H, d), 7.47 (2H, d), 5.57 (1H, d), 4.04 (2H, br), 3.58 (3H, s), 3.42 (2H, br), 1.53 (2H, br), 1.29 (3H, t), 1.17 (2H, br).

Present compound C-2: ¹H-NMR (CDCl₃) δ: 8.85 (1H, d), 8.35 (1H, d), 7.50-7.46 (2H, m), 5.65 (1H, d), 4.00 (2H, s), 3.57 (3H, s), 3.43 (2H, br), 1.58 (3H, s), 1.54 (3H, s), 1.29 (3H, t).

Present compound C-7: ¹H-NMR (CDCl₃) δ: 8.80 (1H, d), 8.34 (1H, d), 7.50 (1H, d), 5.68 (1H, d), 4.02 (2H, s), 3.58 (3H, s), 3.51-3.44 (2H, m), 1.55 (3H, s), 1.55 (3H, s), 1.34 (3H, t).

Present compound C-8: ¹H-NMR (CDCl₃) δ: 8.80 (1H, d), 8.34 (1H, d), 7.48 (1H, d), 5.59 (1H, d), 4.05 (2H, br), 3.59 (3H, s), 3.51-3.43 (2H, m), 1.54 (2H, dd), 1.33 (3H, t), 1.19 (2H, dd).

Present compound A-53: ¹H-NMR (CDCl₃) δ: 7.94 (1H, d), 7.38 (1H, d), 6.79 (1H, d), 5.60 (1H, d), 4.47 (2H, , 3.49 (3H, s), 3.47-3.27 (2H, m), 3.17 (6H, s), 1.26 (3H, t).

Present compound A-50: ¹H-NMR (CDCl₃) δ: 8.42 (1H, d), 7.58 (1H, d), 6.91 (1H, d), 5.60 (1H, d), 4.48 (2H, t), 3.52 (3H, s), 3.27-3.25 (2H, m), 3.05 (6H, s), 1.03 (3H, t).

The compounds represented by formula (B-1):

wherein the combination of T, R⁵, A₁, R³ and n represents any combinations indicated in Table 20.

TABLE 20 Present compound T R⁵ A¹ R³ n B-1 OCH₂CF₂CF₃ Me N H 2 B-2 OCH₂CF₂CF₃ Me N CF₃ 2 B-4 OCH₂CF₂CF₃ Et N H 2 B-5 OCH₂CF₂CF₃ Pr N H 2 B-6 OCH₂CF₂CF₃ Bu N H 2 B-7 OCH₂CF₂CF₃ Me N Cl 2 B-8 OCH₂CF₂CF₃ CH₂CH═CH₂ N H 2 B-9 OCH₂CF₂CF₃ CH₂c-Pr N H 2 B-10 OCH₂CF₂CF₃ i-Pr N H 2 B-11 OCH₂CF₂CF₃ Bn N H 2 B-12 OCH₂CF₂CF₃ CH₂CH₂CF₃ N H 2

Present compound B-1: ¹H-NMR (CDCl₃) δ: 8.86 (1H, dd), 8.36 (1H, dd), 7.51 (1H, dd), 7.36 (1H, s), 5.88 (1H, s), 4.49 (2H, t), 3.60-3.48 (5H, m), 1.33 (3H, t).

Present compound B-2: ¹H-NMR (CDCl₃) δ: 9.09 (1H, d), 8.57 (1H, d), 7.40 (1H, s), 5.89 (1H, s), 4.50 (2H, t), 3.63-3.58 (2H, m) 3.60 (3H, s), 1.37 (3H, t).

Present compound B-4: ¹H-NMR (CDCl₃) δ: 8.88 (1H, dd), 8.38 (1H, dd), 7.51 (1H, dd), 7.38 (1H, s), 5.87 (1H, s), 4.49 (2H, t), 3.94 (2H, q), 3.52-3.42 (2H, m), 1.40 (3H, t), 1.31 (3H, t).

Present compound B-5: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.37 (1H, dd), 7.51 (1H, dd), 7.36 (1H, s), 5.87 (1H, s), 4.48 (2H, t) 3.91-3.79 (2H, m), 3.54-3.40 (2H, m), 1.83-1.74 (2H, m), 1.31 (3H, t), 0.96 (3H, t).

Present compound B-6: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.37 (1H, dd), 7.51 (1H, dd), 7.36 (1H, s), 5.87 (1H, s), 4.49 (2H, t), 3.94-3.80 (2H, m), 3.53-3.39 (2H, m), 1.77-1.70 (2H, m), 1.42-1.34 (2H, m), 1.30 (3H, t), 0.95 (3H, t).

Present compound B-7: ¹H-NMR (CDCl₃) δ: 8.80 (1H, d), 8.34 (1H, d), 7.35 (1H, s), 5.86 (1H, s), 4.48 (2H, t), 3.57 (3H, s), 3.59-3.52 (2H, m), 1.35 (3H, t).

Present compound B-8: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.36 (1H, dd), 7,51 (1H, dd), 7.36 (1H,), 5.90 (1H, ddt), 5.88 (1H, s), 5.32 (1H, d), 5.24 (1H, d), 4.48 (2H, t), 4.48 (2H, d), 3.53-3.44 (2H, m), 1.32 (3H, t).

Present compound B-9: ¹H-NMR (CDCl₃) δ: 8.88 (1H, dd), 8.38 (1H, dd), 7.51 (1H, dd), 7.46 (1H, s), 5.88 (1H, s), 4.49 (2H, t), 3.81-3.69 (2H, m), 3.52-3.40 (2H, m), 1.31 (3H, t), 1.26-1.16 (1H, m), 0.69-0.64 (2H, m), 0.39-0.35 (2H, m).

Present compound B-10: ¹H-NMR (CDCl₃) δ: 8.89 (1H, dd), 8.40 (1H, dd), 7.52 (1H, dd), 7.51 (1H, s), 5.88 (1H, s), 4.81-4.74 (1H, m), 4.50 (2H, t), 3.43-3.35 (2H, m), 1.45 (6H, d), 1.28 (3H, t).

Present compound B-11: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.37 (1H, dd), 7.51 (1H, dd), 7.48 (1H, s), 7.39-7.32 (3H, m), 7.25-7.22 (2H, m), 5.89 (1H, s), 5.05 (2H, s), 4.42 2H, t), 3.53-3.41 (2H, m), 1.31 (3H, t).

Present compound B-12: ¹H-NMR (CDCl₃) δ: 8.88 (1H, dd), 8.37 (1H, dd), 7.53 (1H, dd), 7.37 (1H, s), 5.89 (1H, s), 4.51 (2H, 4.21-4.06 (2H, m), 3.46-3.39 (2H, m), 2.66-2.55 (2H, m), 1.30 (3H, t).

Preparation Example 2

The process was carried out by using the Present compound A-2 place of the international compound B-2 according to the method described in Reference Preparation Example 2-3 to obtain the present compound A-1 shown below.

Present compound A-1: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.36 (1H, dd), 7.51 (1H, dd), 7.51 (1H, d), 5.69 (1H, d), 4.52 (2H, t), 3.53 (3H, s), 3.47-3.41 (2H, m), 1.31 (3H, t).

Preparation Example 2A

The compounds which were prepared according to the method described in Preparation Example 2 and their physical property values are shown below.

Present compound A-5: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.34 (1H, dd), 7.50-7.49 (2H, m), 5.66 (1H, d), 4.51 (2H, t), 4.21-4.18 (2H, m), 3.53-3.45 (2H, m), 1.32 (3H, t), 1.27 (3H, t).

Present compound A-34: ¹H-NMR (CDCl₃) δ: 8.89 (1H, dd), 8.36 (1H, dd), 7.81 (1H, s), 7.55 (1H, dd), 4.92 (2H, d), 3.51 (3H, s), 3.42 (2H, q), 1.33 (3H, t).

Preparation Example 3

To the mixtures of the present compound A-2 0.1 g and chloroform 2 mL was added mCPBA (purity 70%) 0.06 g under ice-cooling, and the mixtures were stirred at 0° C. to room temperature for 3 hours. To the mixtures was added aqueous sodium thiosulfate solution, and the mixtures were extracted with chloroform. The resulting organic layers were washed with aqueous st dium bicarbonate solution, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography (methanol:ethyl acetate=1:19) to obtain the present compound A-3 shown below 0.08 g.

Present compound A-3: ¹H-NMR (CDCl₃) δ: 8.73 (1H, dd), 8.35 (1H, dd), 7.69 (1H, d, J=8.2 Hz), 7.50 (1H, dd), 5.73 (1H, d), 4.55 (2H, t), 3.54 (3H, s), 3.38-3.31 (1H, m), 2.89-2.86 (1H, m), 1.40 (3H, t).

Preparation Example 3A

The compound which was prepared according to the method described in Preparation Example 3 and its physical property value are shown below.

Present compound A-33: ¹H-NMR (CDCl₃) δ: 8.76 (1H, dd), 8.38 (1H, dd), 7.97 (1H, s), 7.55 (1H, dd), 4.99-4.91 (2H, m), 3.52 (3H, s), 3.27-3. (1H, m), 2.87-2.83 (1H, m), 1.37 (3H, t).

Preparation Example 4-1

The mixtures of the Present compound A-18 0.1 q, cyclopropyl boronic acid 56 mg, [1,1′-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane additive 32 mg, tripotassium phosphate 0.23 g, toluene 1.5 mL and water 0.4 mL were stirred at 100° C. for 2 hours. The resulting mixtures were stood to cool to room temperature, and water was then added thereto, and the mixtures were extracted with ethyl acetate. The resulting organic layers were dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography (ethyl acetate:hexane=3:1) to obtain the present compound A-28 shown below 89 mg.

Present compound A-28: ¹H-NMR (CDCl₃) δ: 8.63 (1H, d), 7.94 (1H, d), 7.47 (1H, d), 5.67 (1H, d), 4.54-4.48 (2H, m), 3.52 (3H, s), 3.41-3.35 (2H, m), 2.06-1.99 (1H, m), 1.29 (3H, t), 1.16-1.13 (2H, m), 0.87-0.82 (2H, m).

Preparation Example 4-2

The compounds which were prepared according to the method described in Preparation Example 4-1 and their physical property values are shown below.

Present compound A-29: ¹H-NMR (CDCl₃) δ: 9.03 (1H, d), 8.48 (1H, d), 7.65-7.61 (2H, m), 7.56 (1H, d), 7.23 (2H, dd), 5.71 (1H, d), 4.53 (2H, t), 3.55 (3H, s), 3.50-3.43 (2H, m), 1.34 (3H, t).

Present compound B-3: ¹H-NMR (CDCl₃) δ: 8.62 (1H, d), 7.94 (1H, d), 7.33 (1H, s), 5.89 (1H, s), 4.48 (2H, t), 3.56 (3H, s), 3,48 (2H, q), 2.04-2.00 (1H, m), 1.31 (3H, t), 1.16-1.14 (2H, m), 0.86-0.81 (2H, m).

Present compound A-31: ¹H-NMR (CDCl₃) δ: 9.59 (1H, d), 9.02 (1H, dd), 8.99 (1H, d), 8.13 (1H, dd), 7.99 (1H, dd), 7.59 (1H, d), 5.72 (1H, d), 4.54 (2H, t), 3.56-3.50 (2H, m), 3.55 (3H, s), 1.37 (3H, t).

Preparation Example 4-3

The compounds which were prepared by using the present compound A-47 in lace of the present compound A-18 according to the method described in Preparation Example 4-1 and their physical property values are shown below.

Present compound A-44

Present compound A-45: ¹H-NMR (CDCl₃) δ: 8.34 (1H, d), 8.06-8.02 (2H, m), 7.82 (1H, d), 7.53 (1H, d), 7.14 (2H, t), 5.68 (1H, d), 4.51 (2H, t), 3.53 (3H,m), 3.48-3.44 (2H, m), 1.19 (3H, t).

Preparation Example 5-1

The mixtures of the intermediate compound A-23 1.68 g, sodium acetate 1.87 g, THF 12 mL and 30% hydrogen peroxide solution 0.4 mL, and water 6 mL was stirred at 0° C. for 1 hour. To the resulting ixtures was added saturated aqueous sodium thiosulfate solution 3 mL, and the mixtures were stirred for 1 hour. To the resulting mixtures was added saturated aqueous ammonium chloride solution at room temperature, and the mixtures were extracted with chloroform. The resulting organic layers were washed with. saturated brine, dried over sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography (ethyl acetate) to obtain the present und. A-43 shown below 0.94 g.

Present compound A-43: ¹H-NMR (CDCl₃) δ: 9.35 (1H, s), 8.10 (1H, d), 7.60 (1H, d), 7.55 (1H, d), 5.79 (1H, d), 4.55 (2H, t), 3.62 (3H, s), 3.24-3.14 (2H, m), 1.32 (3H, t).

Preparation Example 6

The mixtures of the present compound A-43 0.25 q, 2-iodopyridine 0.17 g, copper(II) iodide 0.02 g, 1-butyl imidazole 0.04 g, potassium carbonate 0.16 g, and toluene 3 mL were stirred under reflux for 7 hours. The resulting mixtures were stood to cool to room temperature, and the mixtures were filtered through Celite (Registered Trademark) and the filtrates were concentrated. The resulting residue was subjected to a silica gel column chromatography (ethyl acetate:hexane 1:2) to obtain the present compound. A-40 shown below 0.08 g.

Present compound A-40: ¹H-NMR (CDCl₃) δ: 8.75 (1H, d), 8.20 (1H, dd), 8.17-8.16 (1H, m), 7.81-7.76 (1H, m), 7.53 (1H, d), 7.10 (1H, dd), 7.07 (1H, d), 8.68 (1H, d), 4.52 (2H, t), 3.58-3.36 (2H, m), 3.54 (3H, s), 1.33 (3H, t),

Preparation Example 7-1

To the mixtures of the present compound A-43 180 mg, cesium carbonate 199 mg, and DMF 1 mL was added iodo ethane 49 μL at under ice-cooling, and the mixtures were stirred at room temperature for 4 hours. Water was added to the resulting mixtures, and the precipitated solids were filtered, and the obtained solids were washed with wate dried under reduced pressure to obtain the present compound A-35 shown below 150 mg.

Present compound A-35: ¹H-NMR (CDCl₃) δ: 8.53 (1H, d), 7.81 (1H, d), 7.47 (1H, d), 5.66 (1H, d), 4.50 (2H, t), 4.21-4.15 (2H, m), 3.52 (3H, s), 3.43-3.34 (2H, m), 1.49 (3H, t), 1.30 (3H, t).

Preparation Example 7-2

The compounds which were prepared according to the method described in Preparation Example 7-1 and their physical property values are shown below.

Present compound A-36: ¹H-NMR (CDCl₃) δ: 8.53 (1H, d), 7.81 (1H, d), 7.47 (1H, d), 5.65 (1H, d), 4.50 (2H, t), 4.09-4.04 (2H, m), 3.52 (3H,), 3.43-3.35 (2H, m), 1.92-1.83 (2H, m), 1.31 (3H, t), 1.08 (3H, t).

Present compound A-37: ¹H-NMR (CDCl₃) δ: 8.49 (1H, d), 7.79 (1H, d), 7.47 (1H, d), 5.65 (1H, d), 4.72-4.66 (1H, m), 4.50 (2H, t), 3.53 (3H, s), 3.41-3.34 (2H, m), 1.42 (3H, br s), 1.40 (3H, br s), 1.30 (3H, t).

Present compound A-38: ¹H-NMR (CDCl₃) δ: 8.62 (1H, d), 7.90 (1H, d), 7.48 (1H, d), 5.68 (1H, d), 4.59 (2H, t), 4,52 (2H, t), 3.53 (3H, s), 3.42 (2H, q), 1.32 (3H, t).

Preparation Example 8-1

The mixtures of the interuediate compound A-37 700 mg, and copper powder 285 mg, heptafluoropropyl iodide 2.65 g and DMSO 10 mL were stirred at 140° C. for 16 hours and a half hour in a sealed container. The resulting mixtures were cooled to room. temperature, and ethyl acetate was added thereto, and the mixtures were filtered through. Celite (Registered Trademark). The resulting filtrates were extracted with ethyl acetate and water. The resulting organic layers were washed with saturated brine and dried over sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography to obtain the present compound A-12 shown below 437 mg.

Present compound A-12: ¹H-NMR (CDCl₃) δ: 8.88 (1H, d), 8.34 (1H, d), 7.57-7.50 (2H, m), 6.74 (1H, d), 3.64 (3H,s), 3.46-3.37 (2H, m), 1,29 (3H, t).

Preparation Example 8-2

The compound which was prepared according to the method described in P7eparation Example 8-1 and its physical property value are shown below

Present compound A-13: ¹H-NMR (CDCl₃) δ: 8.88 (1H, d), 8.34 d), 7.57-7.51 (2H, m), 6.77 (1H, d), 3.64 (3H,$), 3.46-3.42 (2H, m), 1.33 (3H, t).

Preparation Example 9

The compounds which were prepared by using the intermediate compound A-37 in place of the present compound A-18 according to the method described in Preparation

Example 4-1 and their physical property values are shown below.

Present compound. A-14: ¹H-NMR (CDCl₃) δ: 8.89-8.83 (2H, m), 8.36 (1H, d), 7.97 (1H, d), 7.85 (1H, d), 7.55-7.54 (2H, m), 6.30 (1H, d), 3.58-3.42 (5H, m) 1.35 (3H, t).

Present compound A-15: ¹H-NMR (CDCl₃) δ: 9.02 (1H, s), 8.90 (2H, 8.36 (1H, d), 8.02 (1H, s) 7.54 (2H, d), 6.31 (1H, d), 3.56-3.48 (2H, m), 3.42 (3H, s), 1.33 (3H, t).

Present compound A-16: ¹H-NMR (CDCl₃) δ: 8.88 (1H, d), 8.37 (1H, d), 7.76 (1H, d), 7.69-7.62 (3H, m), 7.54-7.46 (2H, 6,31 (1H, d), 3.56-3.48 (2H, m), 3.42 (3H, s), 1.33 (3H, t).

Preparation Example 10

The process was carried out by using the intermediate compound A-36 in place of the present compound A-43 and using 2,2,3,3,3-pentafluoropropyl triflate in place of iodo ethane according to the method described in Preparation. Examples 7-1 to obtain the present compound A-30 shown below.

Present compound A-30

Preparation Example 11

The process was carried out by using the intermediate compound A-30 in place of 2-fluoro-4-(trifluoromethyl)phenyl boronic acid and using 2-bromo-3-ethylthiopyridine in place of the intermediate compound A-28 according Lo the method described in Reference Preparation 12-1 to obtain the present compound A-26 shown below.

Present compound A-26: ¹H-NMR (CDCl₃) δ: 1H-NMR (CDCl₃) δ: 8.46 (1H, dd), 7.81 (1H, s), 7.70 (1H, dd), 7.26 (1H, dd), 4.92 (2H, t), 3.52 (3H, s), 2.90 (2H, q), 1.27 (3H, t).

Preparation Example 12

The mixtures of the intermediate compound A-41 10 g and acetic anhydride 50 mL were stirred at 150° C. for 16 hours in a sealed container. The resulting mixtures were cooled to room temperature, and acetic anhydride zas removed by concentrating under reduced pressure. To the resulting reaction mixtures were added methanol 70 mL and concentrated hydrochloric acid, and the mixtures were stirred at 60° C. for 16 hours. The resulting mixtures were cooled to room temperature, and methanol was removed by concentrating under reduced pressure. The. resulting reaction mixtures wereextracted with water, saturated aqueous sodium bicarbonate solution, and ethyl acetate successively, to obtain the present compound. A-46 shown below 7 g.

Present compound A-46: ¹H-NMR (CDCl₃) δ: 7.86 (1H, d), 7.63 (1H, d), 6.49 (1H, d), 5.68 (1H, d), 4.53 (2H, t), 3.48 (3H, s), 3.25 (2H, q), 1.24 (3H, t).

Preparation Example 13

To the mixtures of the present compound A-46 4 g, triethylamine 3.7 mL, and dichloromethane 15 ml was added dropwise trifluoromethane sulfonic anhydride 2.5 mL under ice-cooling, and the mixtures were stirred at 0° C. to room temperature for 16 hours. Water was added to the xtures, and the mixtures were extracted with dichloromethane. The resulting organic layers were dried over anhydrous sodium sulfate, and concentrated under reduced pressure to obtain the present compound A-47 4 g.

Present compound A-47: ¹H-NMR (CDCl₃) δ: 8.46 (1H, d), 7.52 (1H, d), 7.27 (1H, m), 5.59 (1H, d), 4.51 (2H, t), 3.62 (2H, m), 3.57 (3H, s) 1.36 (3H, t).

Preparation Example 14

The mixtures of the present compound A-18 100 mg, tert-butyl carbamate 31 mg, 2-dicylohexylphoshino-2′,4′,6′-triisopropyl biphenyl 11 mg, palladium(II) acetate 4 mg, cesium carbonate 99 mg, and dioxane 1.7 mL was stirred at 100° C. for 3 hours under nitrogen atmosphere. Water was added to the resulting mixtures at room temperature, and the mixtures were extracted with ethyl acetate. The resulting organic lavers were washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography (ethyl acetate hexane=1:1) to obtain the present compound A-56 shown below 100 mg.

Present compound A-56: ¹H-NMR (CDCl₃) δ: 8.76 (1H, d), 8.51 (1H, d), 7.47 (1H, d), 6.76 (1H, s), 5.65 (1H, d), 4.50 (2H, t), 3.52 (3H, s), 3.47-3.41 (2H, m), 1.54 (9H, 1.33 (3H, t).

Preparation Example 14-1

The compounds which were prepared according to the method described in Preparation Example 14 and their physical property values are shown below.

Present compound A-57: ¹H-NMR (CDCl₃) δ: 8.83 (1H, d), 8.49 (1H, d), 7.49 (1H, d), 6.99 (1H, s), 5.67 (1H, d), 4.51 (2H, t), 3.84 (3H,), 3.53 (3H, s), 3.49-3.37 (2H, m), 1.33 (3H, t).

Present compound A-58: ¹H-NMR (CDCl₃) δ5: 8.81 (1H, d), 8.50 (1H, d), 7.49 (1H, d), 6.97 (1H, s), 5.66 (1H, d), 4.51 (2H, t), 4.28 (2H, q), 3.53 (3H, s), 3.50-3.37 (2H, m), 1.34 (3H, t), 1.33 (3H, t).

Present compound A-60: ¹H-NNR (CDCl₃) δ: 8.92 (1H, d), 8.59 (1H, d), 8.24 (1H, 7.48 (1H, d), 5.68 (1H, d), 4.51 (2H, t), 3.53 (3H, s), 3.48-3.36 (2H, m), 1.63-1.57 (1H, m), 1.32 (3H, t), 1.15-1.11 (2H, m), 0.94-0.90 (2H, m).

Preparation Exampl 15

The mixtures of the present compound A-56 1.31 g, trifluoroacetic acid 1.8 mL and chloroform 5 mL were stirred at 60° C. for 1 hour. To the resulting mixtures was added 10N aqueous sodium hydroxide solution under ice-cooling, and the mixtures were extracted with chloroform The resulting organic layers were washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to obtain the present compound A-62 shown below 1.08 g.

Present compound A-62 : ¹H-NMR (CDCl₃) δ: 8.29 (1H, d), 7.60 (1H, d), 7.46 (1H, d), 5.63 (1H, d), 4.50 (2H, t), 4.03 (2H, br), 3.53 (3H, s), 3.39-3.32 (2H, m), 1.30 (3H, t).

Preparation Example 16

To the mixtues of the present compound A-62 200 mg, cupper(II)bromide 152 mg, and acetonitrile 1.1 mL was added dropwise tent-butyl nitrite 0.06 mL, and the mixtures were stirred at room temperature for 1 hour. Water was added to the resulting mixtures, and the mixtures were extracted with ethyl acetate. The resulting organic layers were washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography to obtain the present compound A-61 shown below 139 mg.

Present compound A-61: ¹H-NMR (CDCl₃) δ: 8.90 (1H, d), 8.47 (1H, d), 7.51 (1H, d), 5.68 (1H, d), 4.52 (2H, t), 3.53 (3H, s), 3.50-3.44 (2H, m), 1.34 (3H, t).

Preparation Example 17

The mixtures of the present compound. A-18 1.00 g, (trimethylsilyl)acetonitrile 0.7 mL, zinc fluoride 0.27 q, 4,5′-bis(diphenylphoshino)-9,9′-dimethylxanthene 0.25 g, and tris(dibenzylideneacetone)dipalladium (0) 0.2 g, and DMF 7 mL were stirred at 140° C. for 3 hours. The resulting mixtures were cooled to room temperature, and water was added thereto, and the mixtures were extracted with ethyl acetate. The resulting organic layers were washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography (ethyl acetate:hexane=2:1) to obtain the present compound A-48 shown below 0.34 g.

Present compound A-48: ¹H-NMR (CDCl₃) δ: 8.86 (1H, d), 8.33 (1H, d), 7.53 (1H, d), 5.70 (1H, d), 4.52 (2H, t), 3.91 (2H, s), 3.53 (3H, s), 3.47 (2H, q), 1.34 (3H, t).

Preparation Example 18

The mixtures of the present compound A-48 0.24 g, 1,2-dibromoethane 0.13 mL, cesium carbonate 0.50 g, and acetonitrile 4 mL were stirred under reflux for 9 hours. Water was added to the resulting mixtures, and the mixtures were extracted with ethyl acetate. The resulting organic layers were dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography (ethyl acetate) to obtain the present compound A-54 shown below 0.13

Present compound A-54: ¹H-NMR (CDCl₃) δ: 8.88 (1H, d), 8.14 (1H, d), 7.50 (1H, d), 5.69 (1H, d), 4.52 (2H, t), 3.53 (3H, s), 3.44 (2H, q), 1.32 (3H, t), 1.26 (2H, t), 0.88 (2H, t).

Preparation Example 19

The compound which was prepared according to the method described in Preparation Examples 1 to 28 and its physical property value are shown below.

The compounds represented by formula (C-1):

wherein the combination of T, R⁵, A¹, R^(3B) and R^(3c) represents any combinations indicated in Table 21.

TABLE 21 Present compound T R⁵ A³ R^(3b) R^(3c) A-49 OCH₂CF₂CF₃ Me CH H Me A-51 OCH₂CF₂CF₃ Me CH H OEt A-52 OCH₂CF₂CF₃ Me CH H Oi-Pr C-3 OCH₂C(Me)₂CN Me CH c-Pr H C-4 OCH₂C(Me)₂CN Me CH 4-F—Ph H C-5 OCH₂(1-CN-c-Pr) Me CH c-Pr H C-6 OCH₂(1-CN-c-Pr) Me CH 4-F—Ph H A-65 OCH₂CF₂CF₃ Me N CF₃ H A-74 OCH₂CF₂CF₃ CH₂OCH₃ CH H H A-75 OCH₂CF₂CF₃ Me CH CH₃ H A-81 OCH₂CF₂CF₃ Me CBr H H C-9 OCH₂C(Me)₂CN Me CH CF₃ H C-10 OCH₂(1-CN-c-Pr) Me CH CF₃ H

Present compound A-49

Present compound A-51: ¹H-NMR (CDCl₃) δ: 8.12 (1H, d), 7.42 (1H, d), 6.79 (1H, d), 5.63 (1H, d), 4.48 (2H, t), 4.41-4.35 (2H, m), 3.50 (3H, s), 3.22-3.13 (2H, m), 1.36 (3H, t), 1.31-1.24 (3H, m).

Present compound A-52: ¹H-NMR (CDCl₃) δ: 8.10 (1H, d), 7.41 (1H, d), 6.74 (1H, d), 5.63 (1H, d), 5.34-5.30 (1H, m), 4.48 (2H, t), 3.58-3.35 (5H, m), 1.38-1.27 (9H, m).

Present compound C-3: ¹H-NMR (CDCl₃) δ: 8.63 (1H, d), 7.94 (1H, d), 7.47 (1H, d), 5.64 (1H, d), 4.00 (2H, s), 3.58 (3H, s), 3.43-3.34 (2H, m), 2.05-1.99 (1H, m), 1.55 (3H, s), 1.55 (3H, s), 1.29 (3H, t), 1.15-1.13 (2H, m), 0.87-0.82 (2H, m).

Present compound C-4: ¹H-NMR (CDCl₃) δ: 9.03 (1H, d), 8.48 (1H, d), 7.65-7.61 (2H, m), 7.56 (1H, d), 7.25-7.20 (2H, m), 5.69 (1H, d), 4.03 (2H, s), 3.60 (3H, s), 3.51-3.43 (2H, m), 1.56 (3H, s), 1.56 (3H, s), 1.34 (3H, t).

Present compound C-5: ¹H-NMR (CDCl₃) δ: 8.63 (1H, d), 7.94 (1H, d), 7.45 (1H, d), 5.56 (1H, d), 4.04 (2H, d), 3.58 (3H, s), 3.42-3.33 (2H, m), 2.03-2.00 (1H, m) 1.53 (2H, dd), 1.29 (3H, t), 1.18 (2H, dd), 1.15-1.12 (2H, m), 0.87-0.82 (2H, m).

Present compound C-6: ¹H-NMR (CDCl₃) δ: 9.02 (1H, d), 8.48 (1H, d), 7.63 (2H, dd), 7.54 (1H, d), 7.22 (2H, t), 5.61 (1H, d), 4.07 (2H, br), 3.61 (3H, s), 3.50-3.43 (2H, m), 1.55 (2H, dd), 1.34 (3H, t), 1.19 (2H, dd).

Present compound A-65: ¹H-NMR (CDCl₃) δ: 9.13-9.11 (1H, dd), 8.58-8.56 (1H, dd), 7.86 (1H, s), 4.93-4.90 (2H, 3.54-3.48 (2H, m), 3.52 (3H, s), 1.37 (3H, t).

Present compound A-74: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.34 (1H, dd), 7.53-7.49 (2H, m), 5.68 (1H, d), 5.57-5.53 (2H, m), 4.53 (2H, t), 3.50-3.44 (5H, m), 1.32 (3H, t).

Present compound A-75: ¹H-NMR (CDCl₃) δ: 8.68 (1H, d), 8.16 (1H, d), 7.49 (1H, d), 5.67 (1H, d), 4.51 (2H, t), 3.52 (3H, s), 3.43-3.39 (2H, m), 2.48 (3H, s), 1.31 (3H, t).

Present compound A-81: ¹H-NMR (CDCl₃) δ: 8.87 (1H, dd), 8.34 (1H, dd), 7.61 (1H, s), 7.55 (1H, dd), 4.76-4.71 (2H, m), 3.60 (3H, s), 3.53-3.48 (2H, m), 1.35 (3H, t).

Present compound C-9: ¹H-NMR (CDCl₃) δ: 9.09 (1H, d), 8.57 (1H, d), 7.56 (1H, d), 5.70 (1H, d), 4.03 (2H, s), 3.60 (3H, s), 3.54 (2H, q), 1.56 (3H, s), 1.55 (3H, s), 1.36 (3H, t).

Present compound C-10: ¹H-NMR (CDCl₃) δ: 9.08 (1H, d), 8.57 (1H, d), 7.53 (1H, d), 5.62 (1H, d), 4.07 (2H, br), 3.61 (3H, s), 3.53 (2H, q), 1.56-1.54 (2H, m), 1.35 (3H, t), 1.21-1.17 (2H, m).

The compounds represented by formula (D-1)

wherein the combination of T, R⁵, A¹ , A², A⁴, R^(3a), R^(3b) and R^(3c) represents any combinations indicated in Table 22.

TABLE 22 Present compound T R⁵ A¹ A² A⁴ R^(3a) R^(3b) R^(3c) B-13 OCH₂CF₂CF₃ Me N CH CH H OEt H B-14 OCH₂CF₂CF₃ Me N CH CH H OH H B-17 OCH₂CF₂CF₃ Me N N CH H H H

Present compound B-13: ¹H-NMR (CDCl₃) δ: 8.52 (1H, 7.81 (1H, d), 7.32 (1H, s), 5.86 (1H, s), 4.47 (2H, t), 4.21-4.14 (2H, m), 3.55 (3H, s), 3.52-3.45 (2H, m), 1.48 (3H, t), 1.32 (3H, t).

Present compound B-14: ¹H-NMR (CDCl₃) δ: 8.08 (1H, d), 7.59 (1H, d), 7.44 (1H, s), 6.08 (1H, s), 4.55 (2H, t), 3.62 (3H, s), 3.31-3.20 (2H, m), 1.34 (3H, t).

Present compound B-17: ¹H-NMR (CDCl₃) δ: 8.94 (1H, dd), 8.33 (1H, dd), 7.61 (1H, dd), 6.04 (1H, s), 4.54 (2H, t), 3.83 (3H, s), 3.49 (2H, q), 1.36 (3H, t).

Present compound E-15: ¹H-NMR (CDCl₃) δ: 8.54 (1H, dd), 7.79 (1H, dd), 7.32 (1H, dd), 6.07 (lH, s), 4.53 (2H, t), 3.84 (3H, s), 2.91 (2H, q), 1.26 (3H, t).

Present compound B-16: ¹H-NMR (CDCl₃) δ: 8.64 (1H, dd), 8.42 (1H, dd), 7.61 (1H, dd), 6.13 (1H, s), 4.57 (2H, t), 3.87 (3H, s), 3.29-3.21 (1H, m), 2.91-2.87 (1H 1.37 (3H, t).

Reference Process Example 18

A mixture of the intermediate compound A-19 8 g and DMF 50 mL was cooled to 0° C., and thereto was added sodium hydride (60%, in oil) 2.8 g. The resulting mixture was stirred at 0° C. for 30 minutes, and thereto was added the compound of formula (D):

9 g, and the mixture was stirred at 0° C. for 3 hours. Water was added to the resulting mixture, and the mixture was extracted with ethyl acetate. The resulting organic layer was dried over anhydrous sodium sulfate, and Concentrated under reduced pressure. The resulting residue was subjected to a silica gel colUmn chromatography to obtain the intermediate compound A-43 shown below 0.5 g and the intermediate compound A-46 shown below 0.4 g.

Intermediate compound A-43: ¹H-NMR (CDCl₃) δ: 8.01 (1H, d), 7.50 (1H, d), 6.98 (1H, d), 6.53 (1H, d), 3.89 (3H, s), 3.13 (6H, s), 2.96-2.86 (2H, m), 1.16 (3H, t).

Intermediate compound A-46: ¹H-NMR (CDCl₃) δ: 8.47 (1H, d), 7.69 (1H, d), 7.00-6.98 (2H, m), 3.95 (3H, s), 3.21-3.13 (2H, m), 3.05 (6H, , 0.99 (3H, t).

Preparation Example 20

To a mixture of the present compound A-18 2.50 g, 4,5-bis(diphenylphosphino)-9,9-dimethylxantene 629 mg, palladium (II) acetate 122 mg, N,N-diisopropylethylamine 2.8 mL, and toluene 19 mL were added dropwise mixture Of 2,4,6-trichlorophenyl formate 3.67 g and toluene 17 mL over 6 hours at 100° C. under nitrogen atmosphere. The resulting mixture was stirred at 100° C. for 2 hours, and the mixture was then cooled to room temperature. Water was added to the resulting mixture and the mixture was extracted with ethyl acetate. The resulting organic layer was washed with saturatedbrine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography (ethyl acetate:hexane=1:1) to obtain the present compound A-63 shown below 1.61 g.

Present compound A-63: ¹H-NMR (CDCl₃) δ: 9.58 (1H, d), 9.07 (1H, d), 7.62 (1H, d), 7.47 (2H, s), 5.74 (1H, d), 4.54 (2H, t), 3.62-3.55 (2H, m), 3.55 (3H, , 1.40 (3H, t).

Preparation Example 21

To a mixture of the present compound A-63 1.31 g, THF 11 mL and water 5.5 mL was added lithium hydroxide monohydrate 169 mg under ice-cooling, and the mixture was stirred at room temperature for 30 minutes. Water was added to the resulting mixture, and the mixture was extracted with ethyl acetate. The resulting aqueous layer was acidified with 6N hydrochloric acid, and the mixture was extracted with ethyl acetate. The resulting organic layer was dried over anhydrous sodium sulfate, concentrated under reduced pressure to obtain the present compound A-64 shown below 0.5 g

Present compound A-64: ¹H-NMR (CDCl₃) δ: 9.28 (1H, d), 8.83 (1H, d), 7.66 (1H, d), 5.83 (1H, d), 4.57 (2H, t), 3.61 (3H, s), 3.53-3.45 (2H, m), 1.41 (3H, t).

Preparation Example 22

To a mixture of the present compound A-64 126 mg, chloroform 2 mL and DMF 16 μL was added oxalyl chloride 46 pL under ice-cooling, and the mixture was stirred at room temperature for 1 hour. Methanol 0.5 mL was added to the resulting mixture under ice-cooling, and the mixture was stirred at room temperature for 2 hours. Aqueous saturated hydrogen carbonate solution was added to the resulting mixture, and the mixture was extracted with ethyl acetate. The resulting organic layer was dried over anhydrous sodium sulfate, concentrated under reduced pressure to obtain the present compound A-66 shown below 0.12 g.

Present comp A-66: ¹H-NMR (CDCl₃) δ: 9.40 (1H, d), 8.89 (1H, d), 7.57 (1H, d), 5.71 (1H, d), 4.52 (2H, t), 4.01 (3H, s), 3.56-3.52 (2H, m), 3.5., (3H, s), 1.36 (3H, t).

Preparation Example 22-1

The compound which was prepared according to the method described in Preparation Example 22 and its physical property value are shown below.

Present compound A-67: 1H-NMR (CDCl₃) δ: 9.40 (1H, d), 8.88 (1H, d), 7.56 (1H, d), 5.71 (1H, d), 4.53 (2H, t), 4.47 (2H, q), 3.54 (2H, q), 3.53 (3H, s), 1.44 (3H, t), 1.36 (3H, t).

Present compound A-68: ¹H-NMR (CDCl₃) δ: 9.38 (2H, d), 8.86 (1H, d), 7.55 (1H, d), 5.71 (1H, d), 5.37-5.31 (1H, m), 4.53 (2H, t), 3.54-3.52 (5H, m), 1.42 (6H, d), 1.36 (3H, t).

Present compound A-71: ¹H-NMR (CDCl₃) δ: 9.22 (1H, d), 8.64 (1H, d), 7.54 (1H, d), 6.27 (1H, br), 5.70 (1H, d), 4.52 (2H, t), 3.53 (3H, s), 3.50 (2H, q), 3.08 (3H, d), 1.34 (3H, t).

Present compound A-70: ¹H-NMR (CDCl₃) δ: 9.26 (1H, d), 8.71 (1H, d), 7.55 (1H, d), 6.31 (1H, br), 5.84 (1H, br), 5.71 (1H, d), 4.53 (2H, t), 3.51 (2H, q), 3.54 (3H, s), 1.34 (3H, t).

Present compound A-72: ¹H-NMR (CDCl₃) δ: 8.93 (1H, d), 8.39 (1H, d), 7.53 (1H, d), 5.69 (1H, d), 4.52 (2H, t), 3.54-3.45 (2H, m), 3.54 (3H, s), 3.17 (3H, , 3.08 (3H, s), 1.33 (3H, t).

Present compound A-73: ¹H-NMR (CDCl₃) δ: 9.20 (1H, d), 8.58 (1H, d), 7.53 (1H, d), 6.41 (1H, br), 5.70 (1H, d), 4.52 (2H, t), 3.53-3.46 (2H, m), 3.53 (3H, s), 2.98-2.92 (1H, m), 1.33 (3H, t), 0.96-0.91 (2H, m), 0.71-0.67 (2H, m).

Preparation Example 23

A mixture of the present compound A-61 200 mg, sodium iodide 178 mg, copper (i) iodide 15 mg, trans-N,N′-dimethylcyclohexane-1,2-diamine 22 mg, and dioxane 13 was stirred at 130° C. for 2 hours. Water was added to the resulting mixture at room temperature, and the mixture was extracted with ethyl acetate. The resulting organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography to obtain the present compound A-69 shown below 160 mg.

Present compound A-69: ¹H-NMR (CDCl₃) δ: 9.04 (1H, d), 8.63 (1H, d), 7.51 (1H, d), 5.68 (1H, d), 4.51 (2H, , 3.52 (3H, s), 3.46 (2H, q), 1.33 (3H, t).

Preparation Example 24

To a mixture of the present compound A-61 0.5 g, tert-butyl carbazate 0.2 g, 2-(dicyclohexylphoshino)-3.6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl 54 mg, cesium carbonate 0.97 g, and dioxane 6.6 mL was added tris(dibenzylideneacetone)dipalladium (0) 90 mg, and the mixture was stirred at 100° C. for 1.5 hours. Water was added. to the resulting mixture at room temperature, and the mixture was extracted with ethyl acetate. The resulting organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography (ethyl acetate:hexane=1:1) to obtain the present compound A-76 shown below 0.21 g.

Present compound A-76: ¹H-NMR (CDCl₃) δ: 9.14 (1H, d), 8.58 (1H, d), 7.50 (1H, d), 5.66 (1H, d), 4.50 (2H, t), 4.45 (2H, s), 3.52 (3H, s), 3.45 (2H, q), 1.57 (9H, s), 1.33 (3H, t).

Preparation Example 25

A mixture of the present compound A-76 0.27 g, trifluoro cetic acid 0.18 mL, and chloroform 1.5 mL was stirred at 60° C. for 5 hours. The resulting mixture was cooled to room temper ure, and concentrated under reduced pressure to obtain the present compound A-77 as crude product shown below.

Present compound A-77: ¹H-NMR (CDCl₃) δ: 8.45 (1H, d), 7.92 (1H, d), 7.59 (1H, d), 5.84 (1H, d), 5.39 (2H, br), 4.57 (2H, t), 3.56 (3H, s), 3.25 (2H, q), 1.27 (3H, t).

Preparation Example 26

To the present compound A-77 were added ammonium formate 0.15 g and ethyl orthoformate 1 mL, and the mixture was stirred under reflux for 6 hours. Water was added to the resulting mixture at room temperature, and the mixture was extracted with ethyl acetate. The resulting organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to a silica gel column chromatography (ethyl acetate) to obtain the present compound A-78 shown below 35 mg and the present compound A-79 shown below 0.13 g.

Present compound A-78: ¹H-NMR (CDCl₃) δ: 9.26 (1H, d), 8.78 (1H, s), 8.68 (1H, d), 7.59 (1H, d), 5.73 (1H, d), 4.55 (2H, t), 3.60-3. (5H, m), 1.38 (3H, t).

Present compound A-79: ¹H-NMR (CDCl₃) δ: 9.26 (1H, d), 8.74 (1H, s), 8.57 (1H, d), 8.22 (1H, s), 7.57 (1H, d), 5.73 (1H, d), 4.54 (2H, t), 3.58-3.50 (5H, m), 1.37 (3H, t).

Preparation Example 27

A mixture of the present compound A-2 1.0 g, N-bromosuccinimide 0.45 g, and DMF 10 mL was stirred for 2 hours at room temperature. Aqueous saturated hydrogen carbonate solution was added to the resulting mixture, and the mixture was extracted with ethyl acetate. The resulting organic layer was washed. with saturated brine, dried over anhydrous sodium sulfate, and concentrated. The resulting residue was subjected to a silica gel column chromatography (methanol:chloroform=1:9) to obtain the present compound A-80 shown below 0.74 g.

Present compound A-80: ¹H-NMR (CDCl₃) δ: 8.44 (1H, dd), 7.71 (1H, dd), 7.63 (1H, s), 7.26 (1H, dd), 4.70 (2H, t), 3.62 (3H, s), 2.90 (2H, q), 1.27 (3H, t).

Preparation Example 28

A mixture of the present compound A-2 1.5 g, N-bromosuccinimide 1.02 g, tert-butoxide potassium 0.55 g, and cyanamide 0.21 g, and methanol 30 mL was stirred at room temperature for 5 hours. Water was added to the resulting mixture, and the mixture was extracted with ethyl acetate. The resulting organic layer was concentrated under reduced pressure to obtain the present compound A-83 shown below 0.93 g.

Present compound A-83: ¹H-NMR (CDCl₃) δ: 8.80 (1H, dd), 8.46 (1H, dd), 7.97 (1H, d), 7.52 (1H, dd), 5.86 (1H, d), 4.60 (2H, t), 3.77-3.69 (1H, m), 3.57 (3H, s), 3.44-3.39 (1H, m), 1.61 (3H, t).

Preparation Example 29

Examples of the compounds that can be prepared according to the methods described in the Preparation Examples 1 to 28 are indicated below.

The compounds represented by formula (E-1):

wherein the combination of T, A², A³, Q⁵, Q⁶, R^(3b) and R³c represents any combinations indicated in Table 23.

TABLE 23 Present compound T A² A³ Q⁵ Q⁶ R^(3b) R^(3c) A-82 OCH₂CF₂CF₃ CH CMe O O H H A-84 OCH₂CF₂CF₃ CH CH O N—CN H H A-85 OCH₂CF₂CF₃ CH CH O NH H H A-86 OCH₂CF₂CF₃ CH CH O NMe H H A-87 OCH₂CF₂CF₃ N CH — — H H A-88 OCH₂CF₂CF₃ N CH O — H H A-89 OCH₂CF₂CF₃ N CH O O H H A-90 OCH₂CF₂CHF₂ N CH O O H H A-91 OCH₂CF₂CF₃ N CH O O CF₃ H A-92 OCH₂CF₂CF₃ N CH O O c-Pr H A-93 OCH₂CF₂CF₃ N CH O O 4-F—Ph H A-94 OCH₂CF₂CF₃ N CH O O OEt H A-95 OCH₂CF₂CF₃ N CH O O H CF₃ A-96 OCH₂CF₂CF₃ N CH O O H c-Pr A-97 OCH₂CF₂CF₃ N CH O O H 4-F—Ph A-98 OCH₂CF₂CF₃ N CH O O H OEt

The compounds represented by formula (F-1):

wherein the combination of T, A², A⁴, Q⁵, Q⁶, R^(3b) and R^(3c) represents any combinations indicated in Table 24.

TABLE 24 Present compound T A² A⁴ Q⁵ Q⁶ R^(3b) R^(3c) B-18 OCH₂CF₂CF₃ CH N — — H H B-19 OCH₂CF₂CF₃ CH N O — H H B-20 OCH₂CF₂CF₃ CH N O O H H B-21 OCH₂CF₂CF₃ CH N O O CF₃ H B-22 OCH₂CF₂CHF₂ CH N O O c-Pr H B-23 OCH₂CF₂CF₃ CH N O O 4-F—Ph H B-24 OCH₂CF₂CF₃ CH N O O OEt H B-25 OCH₂CF₂CF₃ N CH O O CF₃ H B-26 OCH₂CF₂CF₃ N CH O O OEt H B-27 OCH₂CF₂CHF₂ N CH O O H 4-F—Ph B-28 OCH₂CF₂CF₃ N CH O O H c-Pr

Next, the formulation Examples of the Present compound Z is described. The “parts” represents “part by weight” unless otherwise specified.

Formulation Example 1

Into a mixture of 35 parts of xylene and 35 parts of DMF, ten parts of any one of the Present compounds A-1 to A-98, B-1 to B-28, and C-1 to C-10 is added, followed by mixing, and then 14 parts of polyoxyethylene styryl phenyl ether and parts of calcium dodecylbenzene sulfonate are added, followed by mixing them to obtain each formulation.

Formulation Example 2

Four (4) parts of sodium lauryi sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic hydrated silicon oxide fine powder and 54 parts of diatomaceous earth are mixed, and further 20 parts of any one of the Present compounds A-1 to A-98, B-1 to B-28, and C-1 to C-10 is added, followed by mixing them to obtain each formulation.

Formulation Example 3

To 2 parts of any one of the Present compounds A-1 to A-98, B-1 to B-28, and C-1 to 0-10, 1 part of synthetic hydrated silicon oxide fine powder, 2 parts of calcium lignin sulfonate, 30 parts of bentonite and 65 parts of kaolin clay are added, followed by mixing. Then the mixtures are stirred, granulated with a granulator, and forced-air dried to obtain each formulation.

Formulation Example 4

Into an appropriate amount of acetone, 1 part of any one of the Present compoulds A-1 to A-98, B-1 to B-28, and C-1 to C-10 is added, followed by mixing, and then 5 parts of hydrous silica, 0.3 parts of isopropyl acid phosphate and 93.7 parts of kaolin clay are added, followed by mixing 2) with stirring thoroughly and removal of acetone from the mixtures by evaporation to obtain each formulation.

Formulation Example 5

Thirty five (35) parts of a mixture of polyoxyethylene alkyl ether sulfate ammonium salt and hydrous silica (weight ratio of 1:1), 20 parts of any one of the Present. compounds A-1 to A-98, B-1 to B-28, and C-1 to C-10, and 45 parts of water are mixed thoroughly to obtain each formulation.

Formulation Example 6

Into a mixture of 5 parts of xylene and 5 parts of trichloroethane, 0.1 parts of any one of the Present compounds A-1 to A-98, B-1 to B-28, and C-1 to C-10 is added, followed by mixing, and the resulting mixture is then mixed with 89.9 parts of kerosene to obtain each formulation.

Formulation Example 7

Into 0.5 mL of acetone, 10 mg of any one of the Present compounds A-1 to A-98 , B-1 to B-28, and C-1 to C-10 is added, followed by mixing, and the solution is added dropwise to 5 g of a solid feed powder for an animal (solid feed powder for rearing and breeding CE-2, manufactured by CLEA Japan, Inc.), followed by mixing the resulting mixture uniformly, and then by drying them by evaporation of acetone to obtain each poison bait.

Formulation Example A

Into an aerosol can, 0.1 part of any one of the Present compounds A-1 to A-98, B-1 to B-28, and C-1 to C-10, and 49.9 parts of Neothiozole (Chuo Kasei Co., Ltd.) are placed. After mounting an aerosol valve, 25 parts of dimethyl ether and 25 parts of LPG are filled, followed by shaking and further mounting an actuator to obtain each oily aerosol.

Formulation Example 9

A mixture of 0.6 part of any one of the Present compounds A-1 to A-98, B-1 to B-28,and C-1 to C-10, 0.01 part of BHT (2,6-di-vert-butyl-4-methylphenol), 5 parts of xylene, 3.39 parts of deodorized kerosine and 1 part of an emulsifier {Rheodol MO-60 (registered trademark of Kao Corporation)} and 50 parts of distilled water are filled into an aerosol container, and a valve part is attached. Then, 40 parts of a propellant (LPG) is filled therein through the valve under pressure to obtain each aqueous aerosol.

Formulation Example 10

0.1 parts of any one of the Present compounds A-1 to A-98, B-1 to B-28, and C-1 to C-10 are mixed into 2 mL of propylene glycol, and the resulting solution is impregnated into a ceramic plate having a size of 4.0 cm×4,0 cm and a thickness of 1.2 cm, to obtain each thermal fumigant.

Preparation Example 11

5 parts of any one of the Present compounds A-1 to A-98, B-1 to B-28, and C-1 to C-10, and 95 parts of ethylene-methyl methacrylate copolymer (the ratio of the methyl methacrylate in the copolymer: 10 weight %), Acryft (registered by trademark) WD 301, manufactured by Sumitomo Chemical Co. Ltd.) are melted and kneaded with a closed type pressure kneader (manufactured by Moriyama Manufacturing Co. Ltd.), and the resulting kneaded product is extruded from an extrusion molding machine through a molding die to obtain each rod-shaped molded product having a length of 15 cm and a diameter of 3 mm.

Formulation Example 12

5 parts of any one of the Present compounds A-1 wo A-98, B-1 to B-28, and C-1 to C-10, and 95 parts of plasticized polyvinyl chloride resin are melted and kneaded with a closed type pressure kneader (manufactured by Moriyama Manufacturing Co. Ltd.), and the resulting kneaded product is extruded from an extrusion molding machine through a molding die to obtain each rod-shaped molded product having a length of 15 cm and a diameter of 3 mm.

Formulation Example 13

One hundred (100) mg of any one of the Present compounds A-1 to A-98, B-1 to B-28, and C-1 to C-10, 68.75 mg of lactose, 237.5 mg of corn starch, 43.75 mg of microcrystalline cellulose, 18.75 mg of polyvinylpyrrolidone, 28.75 mg of sodium carbomethyl starch and 2.5 mg of magnesium stearate are mixed, and the resulting mixture was compressed to an appropriate size to obtain each tablet.

Formulation Example 14

Twenty five (25) mg of any one of the Present compounds A-1 to A-98, B-1 to B-28, and C-1 to C-10, 60 mg of lactose, 25 mg of corn starch, 6 mg of carmellose calcium and an appropriate amount of 5% of hydroxypropyl methylcellulose are mixed, and the resulting mixture are filled into a hard shell gelatin capsule or a hydroxypropyl methylcellulose capsule to obtain each capsule.

Formulation Example 15

To 100 mg of any one of the Present compounds A-1 to A-98, B-1 to B-28, and C-1 to C-10, 500 mg of fumaric acid, 2,000 mg of sodium chloride, 150 mg of methyl paraben, 50 mg of propyl paraben, 25,000 mg of granulated sugar, 13,000 mg of sorhitol (70% solution), 100 mg of Veegum K (manufactured by Vanderbilt , 35 mg of perfume and 500 mg of coloring agent, a distilled water is added so that a final volume is set to be 100 mL, followed by mixing them to obtain each suspension for oral administration.

Formulation Example 16

Into a mixture of 5% by weight of.an emulsifier, 3% by weight of benzyl alcohol and 30% by ht of propylene glycol, 5% by weight of any one of the Present compounds A-1 to A-98, B-1 to B-28, and C-1 to C-10 is dissolved, and phosphate buffer is added thereto so that a pH of the solution is set to be 6.0 to 6.5, and water is added as the rest parts to obtain each solution for oral administration.

Formulation Example 17

To a mixture of 57% by weight of fractional di tillated palm oil and 3% by weight of polysorbate 85, 5% by weight of aluminum distearate is added, and heated to disperse it. The resulting mixture is cooled to room temperature, and 25% by weight of saccharin is dispersed in an oil vehicle. Ten (10) % by weight of any one of the Present compounds A-1 to A-98, to B-28, and C-1 to C-10 is divided thereto to obtain each paste for oral administration.

Formulation Example 18

Five (5) % by weight of any one of the Present compounds A-1 to A-98, B-1 to B-28, and C-1 to C-10 is mixed with 95% by weight of limestone filler, followed by a wet granulation of the resulting mixture to obtain each granule for oral administration.

Formulation Example 19

Into 80 parts of diethylene glycol monomethyl ether, 5 parts of any one of the Present compounds A-i to A-98, B-1 to B-28, and C-1 to C-10 is dissolved, and 15 parts of propylene carbonate is added thereto, and the resulting mixture is mixed to obtain each spot-on solution.

Formulation Example 20

Into 70 parts of diethylene glycol monomethyl ether, 10 parts of any one of the Present compounds A-1 to A-98, B-1 to B-28, and C-1 to C-10 is dissolved, and 20 parts of 2-octyldodecanol is added thereto, and the resulting mixture is mixed to obtain a pour-on solution.

Formulation Example 21

To 0.5 parts of any one of the Present compounds A-2 to A-98, B-1 to B-28, and C-1 to C-10, 60 parts of Nikkol (registered by trademark) TEALS-42 (manufactured by Nikko Chemical Co. Ltd.: 42% of aqueous solution of lauryl sulfuric acid triethanol amine) and 20 parts of propylene glycol are added, and the resulting mixture is mixed with stirring thoroughly, and 19.5 parts of water is then added thereto and the resulting mixture is further mixed with stirring thoroughly to obtain each hydrogenous solution of shampoo formulation.

Formulation Example 22

Zero point one five (0.15)% by weight of any one of the Present compounds A-1 to A-98, B-1 to B-28, and C-1 to C-10, 95% by weight of animal feed, as well as 4.85% by weight of a mixture of dibasic calcium phosphate, diatomaceous earth, aerosol and carbonate (or chalk) are mixed with stirring thoroughly to obtain each premix for animal feed.

Formulation Example 23

Seven point two (7.2) g of any one of the Present compounds A-1 to A-96, B-1 to B-28, and C-1 to C-10, and 92.8 g of Hosco (registered trademark) S-55 (manufactured by Maruishi Pharmaceuticals) are melted and mixed at 100° C., and the resulting mixture was poured into a suppository mold, followed by perforling a cooling solidification to obtain each suppository.

Next, Test Examples are used to show an efficacy of the Present compound Z on controlling harmful arthropods.

The following test examples were carried out at 25° C.

Test Example 1

The test compounds is made to a formulation according to a similar method to that described in the Formulation Example 5, and thereto is added water containing 0.03 v/v % of spreader to prepare a diluted solution containing a prescribed concentration of the test compound.

Cucumber (Cucurnis sativus) seedling (on the developmental stage of the second true leaf) is planted in a container and approximately 30 cotton aphids (Aphis ossypii) (all stages of life) are released onto the leaves of the cucumber. After 1 day, the diluted solutions are sprayed into the seedling in a ratio of 10 mL/seedling. Further, after 5 days, the number of the surviving insects is examined and the controlling value is calculated by the following equation.

Controlling value (%)={1−(Cb×Tai)/(Cai×Tb)}×100

wherein the symbols in the formula represent the following descriptions.

Cb: Number of the test insects in untreated group;

Cai: Number of thesurviving insects at the time of the investigation in untreated group;

Tb: Number of the test insects in treated group;

Tai: Number of the surviving insects at the time of the investigation in treated group;

Here the “untreated group” represents a group where the similar treatment procedure to that of the treated group except not using the test compound is done.

The test was conducted by making the prescribed concentration 500 ppm and using the below-mentioned Present compounds as a test compound according to the test example 1. As a result of the test, the below-mentioned Present compounds showed 90% or greater as the controlling value.

Present compound number: Present compounds A-1, A-3, A-6, A-7, A-8, A-9, A-10, A-11, A-12, A-13, A-14, A-15, A-16, A-17, A-18, A-19, A-21, A-23, A-24, A-25, A-26, A-30, A-31, A-33, A-34, A-35, A-36, A-37, A-38, A-39, A-41, A-48, A-53, A-74, A-75, A-80, A80, A-81, A-82, A-83, B-3, , B-9, B-11, B-13, B-17, C-1 and C-2.

The test was conducted by making the prescribed concentration 200 ppm and using the below-mentioned Present compounds as a test compound according to the test example 1. As a result of the test, the below-mentioned Present compounds showed 90% or greater as the controlling value. Present compound number: Present compounds A-1, A-2, A-3, A-6, A-7, A-8, A-:LO, A-11, A-12, A-14, A-15, A-16, A-18, A-19, A-20, A-23, A-24, A-26, A-28, A-29, A-31, A-33, A-34, A-35, A-35, A-37, A-38, A-39, A-40, A-48, A-53, A-54, A-55, A-56, A-57, A-58, A-59, A-60, A-61, A-62, A-66, A-67, A-68, A-69, A-70, A-71, A-72, A-73, A-75, A-79, B-2, 13-3, B-4, B-5, B-6, B-8, B-13, B-15, C-1, C-2, C-3, C-4, C-5, and C-6.

Test Example 2

The test compounds are made to a formulation according to a similar method to that described in the Formulation Example 5, and thereto is added water to prepare a diluted solution containing a prescribed concentration of the test compound.

Cucumber seedling (on the developmental stage of the second true leaf) is planted in a container, and the diluted solutions are the ratio on 5 mL/seedling are irrigated into the plant foot. After 7 days, approximately 30 cotton aphids (all stages of life) are inoculated onto the cucumber leaves. Further, after additional 6 days, the number of the surviving insects is examined, and the controlling value is calculated by the following equation.

Controlling value (%)={1−(Cb×Tai)/(Cai×Tb)}×100

wherein the symbols in the formula represent the following descriptions.

Cb: Number of the test insects in untreated group;

Cai: Number of the surviving insects at the time of the investigation in untreated group;

Tb: Number of the test insects in treated group;

Tai: Number of the surviving insects at the tine of the investigation in treated group;

Here the “untreated group” represents a group where the sirrilar treatment procedure to that of the treated group except not using the test compound is done.

The test was conducted by making the prescribed concentration 1,000 ppm and using the below-mentioned Present compounds as a test compound according to the test example 2. As a result of the test, the below-mentioned. Present compounds showed 90% or greater as the controlling value.

Present compound number: Present compounds A-1, A-2, A-3, A-6, A-7, A-8, A-10, A-11, A-14, A-16, A-17, A-18, A-23, A-24, A-26, A-28, A-29, A-31, A-33, A-34, A-35, A-36, A-37, A-38, A-39, A-40, A-48, _(A-53), A-54, A;-55, A-56, A-57, A-58, A-59, A-60, A-61, A-62, A-67, A-68, A-69, A-70, A-71, A-72, A-73, A-75, A-79, B-2, B-3, B-4, B-13, C-1, C-2, C-3, and C-5.

Test Example 3

The test compounds are made to a formulation according to a similar method to that described in the Formulation Example 5, and thereto is added water containing 0.03 v/v % of a spreader to prepare a diluted solution containing a prescribed concentration of the test compound.

Rice (Oryza sativa) seedling (on the developmental age of the second true leaf) is planted in a container, and the diluted solutions are sprayed into the seedling in a ratio of 10 mL/seedling. Thereafter, 20 3rd instar larvae of brown planthoppers (Nilaparvata lugens) are released onto the rice leaves. After 6 days, the morality is calculated by the following equation.

Morality (%)={1−the number of the surviving insects/20}×100

The test was conducted by making the prescribed concentration 500 ppm and using the below-mentioned Present compounds as a test compound according to the test example 3. As a result of the test, the below-mentioned Present compounds showed 90% or greater as the morality.

Present compound number: Present compounds A-1, A-2, A-3, A-6, A-11, A-12, A-18, A-23, A-26, A-31, A-33, A-34₁ A-39, A-83, B-3, B-17, C-1, and C-2.

Test Example 4

The test compounds are made to a formulation according to a similar method to that described in the Formulation Example 5, and thereto is added water to prepare a diluted solution containing a prescribed concentration of the test compound.

Five (5) mL of the diluted solutions described above are added to a container, and therein is installed Rice seedling (on the developmental stage of the second true leaf) that is planted in a container having a hole in the bottom. After 7 days, 20 3rd instar larvae of brown planthoppe res (Nalaparvata lugens) are released. After 6 days, the number of the surviving insects is examined, and the morality is calculated by the following equation.

Morality (%)={1−the number of the surviving insects 20}×100

The test was conducted by making the prescribed concentration 1,000 ppm and using the below-mentioned Present compounds as a test compound according to the test Example 4. As a result of the test, the below-mentioned Present compounds showed 90% or greater as the morality.

Present compound number: Present compounds A-1, A-2, A-3, A-6, A-7, A-8, A-11, A-12, A-14, A-16, A-17, A-18, A-19, A-20, A-23, A-24, A-28, A-29, A-31, A-33, A-34, A-35, A-36, A-37, A-38, A-39, A-40, A-54, A-55, A-56, A-57, A-58, A -59, A-60, A-66, A-67, A-68, A-69, A-70, A-71, A-72, A-79, B-2, B-3, C-1, C-2, and C-5.

Test Example 5

The test compounds are made to a formulation according to a similar method to that described in the Formulation Example 5, and thereto is added water containing 0.03 v/v % of a spreader to prepare a diluted solution containing a prescribed concentration of the test compound.

The diluted solutions are sprayed into the cabbage (Brassicae oleracea) seedling (on the developmental stage of the second to third true leaf) that is planted in a container in a ratio of 20 mL/seedling. Thereafter, the stem and leaf thereof is cut out and then is installed into the container that is covered. with the filter paper. Five cabbage moths (Plutella xylostella) at the second instar larval stages are released into the cup. After 5 days, the surviving insects are counted, and the mortality of insects is calculated by the following equation.

Morality (%)={1−the number of the surviving insects/5}×100

The test was conducted by making the prescribed concentration 500 ppm and using the below-mentioned Present compounds as a test compound according to the test example 5 As a result of the test, the below-mentioned Present compounds showed 80% or greater as the morality.

Present compound number: Present compounds A-1, A-2, A-3, A-6, A-7, A-8, A-9, A-10, A-11, A-12, A-13, A-14, A-15, A-16, A-17, A-18, A-19, A-21, A-22, A-23, A-24, A-25, A-26, A-27, A-30, A-31, A-33, A-34, A-35, A-36, A-37, A-38, A-39, A-41, A-53, A-63, A-75, A-80, A-81, B-3, B-8, B-9, B-11, and B-13.

Test Example 6

The test compounds are made to a formulation according to a similar method to that described in the Formulation Example 5, and thereto is added water containing 0.03 v/v % of a spreader to prepare a diluted solution containing a prescribed concentration of the test compound.

The diluted solutions are sprayed into the cucumber seedling (on the developmental stage of the third to fourth true leaf) that is planted in a container in a ratio of 20 mL/seedling. Thereafter, 10 cabbage moths (Plutella xylostella) at the third instar larval stages are released into the container. After 5 days, the surviving insects are counted, and the mortality of insects is calculated by the following equation.

Morality (%)={1−the number of the surviving insects/10}×100

The test was conducted by making the prescribed concentration 200 ppm and using the below-mentioned Present compounds as a test compound according to the Test Example 6. As a result of the test, the below-mentioned Present compounds showed 90% or greater as the morality.

Present compound number: Present compounds A-1, A-2, A-3, A-7, A-8, A-9, A-12, A-13, A-18, A-19, A-20, A-21, A-22, A-23, A-24, A-25, A-26, A-27, A-28, A-29, A-31, A-33, A-34, A-35, A-36, A-37, A-38, A-39, A-40, A-41, A-53, A-54, A-56, A-57, A-58, A-59, A-60, A-61, A-66, A-67, A-68, A-69, A-75, A-79, B-2, B-3, B-13, C-2, C-3, and C-4.

Test Example 7

The test compounds are dissolved into a mixed solution of polyoxyethylene sorbitan mono-cocoate and acetone (acetone and polyoxyethylene sorbitan mono-cocoate=5:95 (v/v ratio)) in a ratio of 50 μL of the mixed solution per 1 mg of the test compound. Thereto is added water containing 0.03% by volume of a spreader to prepare a diluted solution containing a prescribed concentration of the test compound.

The young seedling Corns (Zea mays) are immersed into the diluted solution for 30 seconds. Thereafter, two grains of the seedling are installed in a plastic petri dish (90 mm radiue), and 10 western corn rootworms (Diabrotica virgifera virgifera) at the second instar larval stages are released onto the container. After 5 days, the number of the died insects are counted and the mortality of insects is calculated by the following equation,

Morality (%)=(the number of the died insects/10)×100

The test was conducted by making the prescribed concentration 500 ppm and using the below-mentioned Present compounds as a test compound according to the Test Example 7. As a result of the test, the below-mentioned Present compounds showed 80% or greater as the morality.

Present compound number: Present compounds A-1, A-3, A-5, A-7, A-8, A-11, A-13, A-18, A-19, A-20, A-22, A-23, A-26 A-31, A-33, A-34, A-38, A-39, A-40, A-66, and B-3

Test Example 8

The test compounds are made to a formulation according to a similar method to that described in the Formulation Example 5, and thereto is added water containing 0.03 v/v % of a spreader to prepare a diluted solution containing a prescribed concentration of the test compound.

Silverleaf whiteflies (Bemisia tabaci) are released on tomato (Lycopersicon esculentum) seedling that is planted in the container, and then spawn for about 24 hours. The seedling are stored for 8 days, and the larvae of cilverleaf whiteflies are hatched from the laid eggs. The diluted solutions are sprayed into the seedling in a ratio of 10 mL/seedling. After 7 days, the number of the surviving insects is examined, and the controlling value is calculated by the following equation.

Controlling value (%)={1−(Cb×Tai)/(Cai×Tb)}×100

wherein the symbols in the formula represent the following descriptions.

Cb: Number of the insects shortly before the treatment in untreated group;

Cai: Number of the surviving insects at the time of the investigation in untreated group;

Tb: Number of the insects shortly before the treatment in treated group;

Tai: Number of the surviving insects at the time of the investigation in treated group;

Here the “untreated group” represents a group where the similar treatment procedure to that of the treated group except not using the test compound is done.

The test was conducted by making the prescribed. concentration 200 ppm and using the below-mentioned Present compounds as a test compound according to the test example 8. As a result of the test, the below-mentioned Present compounds showed 90% or greater as the morality.

Present compound number: Present compounds A-1, A-2, A-7, A-11, A-12, A-18, A-20, A-23, A-26, A-31, A-33, A-34, A-39, A-54, A-55, A-56, A-59, A-61, A-66, A-67, A-69, and A-79.

Test Example 9

The test compounds are made to a formulation according to a similar method to that described in the Formulation Example 5, and thereto is added water containing 0.03 v/v % of a spreader to prepare a diluted solution containing a prescribed concentration of the test compound.

The diluted solutions are sprayed into the cabbage (Brassicae oleracea) seedling (on the developmental stage of the second to third true leaf) that is planted in a container in a ratio of 20 mLf seedling. Thereafter, the stem and leaf thereof is cut out and then is ins ailed into the container that is covered with the filter paper. Five oriental leaf worm moths (Spodoptera litura) at the second instar larval stages are released into the cup. After 5 days, the surviving insects are counted, and the mortality of insects is calculated by the following equation.

Morality (%)={1−the number of the surviving insects/5}×100

The test was conducted by making the prescribed concentration 500 ppm and using the below-mentioned Present compounds as test compound according to the test example 9. As a result of the test, the below-mentioned Present compounds showed 80% or greater as the morality.

Present compound number: Present compounds A-12, A-13, A-18, A-23, A-26, A-31, A-33, A-34, A-35, A-36, A-37, A-38, A-39, A-81_(v) B-9, B-11, and B-13.

Test Example 10

The present compounds are dissolved into a mixed solution of xylene, DMF and surfactants (xylene, DMF and surfactants=4:4:1 (v/v ratio)) in a ratio of 10 μL of the mixed solution per 1 mg of the present compound. The mixture is diluted with water containing 0.03% by volume of a spreader to prepare a diluted solution A containing a prescribed concentration the present compound.

The present ingredients are dissolved into a mixed solution of xylene, DMF and surfactants (xylene, DMF and surfactants=4:4:1 (v/v ratio)) in a ratio of 10 μL of the mixed solution per 1 mg of the present compound. The mixture is diluted with water containing 0.03% by volume of a spreader to prepare a diluted solution B containing a prescribed concentration of the present ingredient.

The diluted solution A is mixed with the diluted solution B to prepare diluted solution C.

Leaf discs of Cucumber (Cucumber sativus) cotyledon (length 1.5 cm) are placed in each well of 24-well microplate. Two (2) apterous adults and 8 larvae of cotton aphids (Aphis gossypii) per one well are released and the diluted solution C is sprayed at 20 μL per one well. The group is defined as “treated group”. A well that is sprayed with 20 μL of water containing 0.02% by volume of a spreader instead of the diluted solution C is defined as “untreated group”. After drying the diluted solution C, the upper microplate is covered with a film sheet. After 5 days, the number of the surviving insects in each well is examined.

The controlling value is calculated by the following equation.

Controlling value (%)={1−(Tai)/(Cai)}×100

wherein the symbols in the equation represent the following descriptions.

Cai: Number of the surviving insects at the time of the examination in untreated group;

Tai: Number of the surviving insects at the time of the examination in treated group.

Specific examples of the diluted solution C whose efficacies can be confirmed by Test Example 11 include the followings) to 5).

-   1) A diluted solution C comprising any combinations described in the     List. A wherein the concentration of the present compound is 200     ppm, and the concentration of the present ingredient is 2,000 ppm.     Here in the List A, “Comp X” represents a compound selected from any     one of the present compounds A-1 to, A-98, B-1 to B28, and C-1 to     C-10, List A: Comp X+Clot hianidin; Comp X+Thiamethoxam; Comp     X+Imidacloprid; Comp X+Thiacloprid; Comp X+Furupirajituron; Comp     X+Sulfoxaflor; Comp X+Triflumezopyrim; Comp X+Dicloromezotiaz; Comp     X+Beta-cyfluthrin; Comp X+Tefluthrin; Comp X+Fipronil; Comp     X+Chlorantraniliprole; Comp X+Cyantraniliprole; Comp     X+Tetraniliprole; Comp X+Thiodicarb; Comp X+Carbofuran; Comp     X+Fluxametamide; Comp X+Afoxolaner; Comp X+Fluralaner; Comp     X+Broflanilide; Comp X+Avermectin; Comp X+Fluopyram; Comp     X+Fluensulfone; Comp X+Fluazaindolizine; Comp X+Tioxazafen; Comp     X+Flupyrimin; Comp X+Mycorrhizal fungi; Comp X+Bradyrhizobium     japonicum TA-11; Comp X+Bacillus firmus; Comp X+Bacillus firmus     1-1582; Comp X+Bacillus amyloliquefaciens; Comp X+Bacillus     amyloliquefaciens FZE42; COMP X+Pasteuria nishizawae; Comp     X+Pasteuria nishizwae Pn1; Comp X+Pasteuria penetrans; Comp     X+Tebuconazole; Comp X+Prothioconazole; Comp X+Metconazole; Comp     X+Ipconazole; Comp X+Triticonazole; Comp X+Difenoconazole; Comp     X+Imazalil; Comp X+Triadimenol; Comp X+Tetraconazole; Comp     X+Flutriafol; Comp X+Mandestrobin; Comp X+Azoxystrobin; Comp     X+Pyraclostrobin; Comp X +Trifloxystrobin; Comp X+Fluoxastrobin;     Comp X+Picoxystrobin; Comp X+Fenamidone; Comp X+Comp X+Metalaxyl-M;     Comp X+Fludioxonil; Comp X+Sedaxa e; Comp X+Penflufen; Comp     X+Fluxapyroxad; Comp X+Benzovindiflupyr; Comp X+Boscalid; Comp     X+Carboxin; Comp X+Penthiopyrad; Comp X+Flutolanil; Comp X+Captan;     Comp X+thiram; Comp X+Tolclofos-methyl; Comp X+Thiabendazole; Comp     X+Ethaboxam; Comp X+Mancozeb; Comp X+Picarbutrazox; Comp     X+Oxathiapiprolin; Comp X+Silthiofam; Comp X+Inpyrfluxam. -   2) A diluted solution C comprising any combinations described in the     List A wherein the concentration of the present compound is 200 ppm,     and the concentration of the present ingredient is 200 ppm. -   3) A diluted solution C comprising any combinations described in the     List A wherein the concentration of the present compound is 500 ppm,     and the concentration of the present ingredient is 50 ppm. -   4) A diluted solution C comprising any combinations described in the     List A wherein the concentration of the present compound is 500 pm,     and theconcentration of the present ingredient is 5 ppm. -   5) A diluted solution C comprising any combinations described in the     List A wherein the concentration of the present compound is 500 ppm,     and the concentration of the present ingredient is 0.5 ppm.

INDUSTRIAL APPLICABILITY

The present compound Z shows an excellent control effect against a harmful arthropod. 

1. A compound represented by formula (I):

wherein, R² represents a C1-C6 alkyl group optionally having one or more halogen atoms, a cyclopropyl group or a cyclopropylmethyl group, n is 0, 1 or 2, R³ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group B, a C3-C7 cycloalkyl group optionally having one or more substituents selected from group E, a C3-C7 cycloalkenyl group optionally having one or more substituents selected from Group J, a phenyl group optionally having one or more substituents selected from Group H, a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group H, OR¹², NR¹¹R¹², NR^(11a)R^(12a), NR²⁴NR¹¹R¹², NR²⁴ 0R¹¹, NR¹¹C(O)R¹³, NR²⁴NR¹¹C(O)R¹³, NR¹¹C(O)0R¹⁴, NR²⁴NR¹¹C(O)OR¹⁴, NR¹¹C(O)NR¹⁵R¹⁶, NR²⁴NR¹¹C(O)NR¹⁵R¹⁶, N═CHNR¹⁵R¹⁶, N═S(O)_(x)R¹⁵R¹⁶, C(O)R¹⁷, C(O)OR¹⁷, C(O)NR¹⁵R¹⁶, CR^(24═)NOR¹⁷, NR¹¹CR²⁴═NOR¹⁷, a cyano group, a nitro group, or a halogen atom, q is 0, 1, 2 or 3, and when q is 2 or 3, a plurality of R³ may be identical to or different from each other, When two R³ are adjacent to each other, said two R³ may combined together with a carbon atom to which they are attached to form benzene ring, pyrrole ring, furan ring, thiophene ring, pyrazole ring, imidazole ring, triazole ring, oxazole ring, isoxazole ring, thiazole ring, oxadiazole ring, thiadiazole ring, pyridine ring, pyridazine ring, pyrimidine ring, or pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the triazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring, and the pyrazine ring each independently may optionally have one or more substituents selected from Group H}, Het represents a group represented by the following formula Het 1 or a group represented by the following formula Het 2:

A¹ represents a nitrogen atom or CR⁶, A² represents a nitrogen atom or CR^(4a), A³ represents a nitrogen atom or CR^(4b), A⁴ represents a nitrogen atom or CR^(4c), Q¹ represents an oxygen atom or a sulfur atom, Q² represents an oxygen atom, N—CN, N—NO₂, NR²⁰, N—C(O)OR²⁰, or N—C(O)OR¹⁵, and when n is 2, two Q² may be identical to or different from each other, R²⁰ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a hydrogen atom, R⁵ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from group F, a C3-C6 cycloalkyl group optionally having one or more substituents selected from Group J, a phenyl group optionally having one or more substituents selected from Group H, or a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group H, R^(4a), R^(4b), and R^(4c) are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a nitro group, OR¹⁸, NR¹⁸R¹⁹, a cyano group, an amino group, a halogen atom, or a hydrogen atom, R⁶ represents a hydrogen atom or a halogen atom, T represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C1-C5 alkylsulfanyl)C2-C5 alkyl group, the (C1-C5 alkylsulfinyl)C2-C5 alkyl group, and the (C1-C5 alkylsulfonyl)C2-C5 alkyl group each independently have one or more substituents selected from the group consisting of a cyano group and a halogen atom}, a (C3-C7 cycloalkyl)C1-C3 alkyl group, a C3-C7 cycloalkyl group {the (C3-C7 cycloalkyl)C1-C3 alkyl group and the C3-C7 cycloalkyl group each independently have one or more substituents selected from the group consisting of a cyano group, a halogen atom and a C1-C6 haloalkyl group}, OR¹, S(O)_(v)R¹, OS(O)₂R¹, CH₂OR¹, NR¹R²⁹, C(O)R¹, C(O)NR¹R²⁹, NR²⁹C(O)R¹, N═CR¹R³⁰, a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, a group represented by formula T-8, a group represented by formula T-9, a group represented by formula T-10, a group represented by formula T-11, or a group represented by formula T-12:

X¹ represents a nitrogen atom or CR^(1a), X² represents a nitrogen atom or CR^(1b), X³ represents a nitrogen atom or CR^(1c), X⁴ represents a nitrogen atom or CR^(1d), X⁵ represents a nitrogen atom or CR^(1e), R^(1x) represents a C1-C5 chain hydrocarbon group having one or more halogen atoms, OR⁷, OS(O)₂R⁷, S(O)_(m)R⁷, NR⁸S(O)₂R⁷ , or a halogen atom, R^(1a), R^(1b), R^(1c), R^(1d), and R^(1e) are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a halogen atom, or a hydrogen atom, Y¹ represents NR²⁵, an oxygen atom or a sulfur atom, Y² represents a nitrogen atom or CR²⁶, Y³ represents a nitrogen atom or CR²⁷, Y⁴ represents a nitrogen atom or CR²⁸, R²⁵, R²⁶, R²⁷ and R²⁸ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a halogen atom or a hydrogen atom, R^(1y) represents a C1-C5 chain hydrocarbon group having one or more halogen atoms, OR⁷, OS(O)₂R⁷, S(O)_(m)R⁷, NR⁸S(O)₂R⁷, a cyano group, or a halogen atom, R^(1ay) and R⁷ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group having one or more halogen atoms, m and v are identical to or different from each other and each is 0, 1 or 2, R¹ represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C1-C5 alkylsulfanyl)C2-C5 alkyl group, the (C1-C5 alkylsulfinyl)C2-C5 alkyl group, and the (C1-C5 alkylsulfonyl)C2-C5 alkyl group each independently have one or more substituents selected from the group consisting of a cyano group and a halogen atom}, a (C3-C7 cycloalkyl)C1-C3 alkyl group, or a C3-C7 cycloalkyl group {the (C3-C7 cycloalkyl)C1-C3 alkyl group and the C3-C7 cycloalkyl group each independently have one or more substituents selected from the group consisting of a cyano group, a halogen atom and a C1-C6 haloalkyl group}, R³⁰ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a halogen atom, OR³⁵, NR³⁶R³⁷, or a hydrogen atom, R¹⁸ and R³⁵ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, R¹⁷ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a phenyl group optionally having one or more substituents selected from Group D, or a hydrogen atom, R⁸, R¹¹, R¹⁹, R²⁴, R²⁹, R³⁶, and R³⁷ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a hydrogen atom, R¹² represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally having one or more substituents selected from Group J, a C3-C7 cycloalkenyl group optionally having one or more substituents selected from Group J, a phenyl group, a six membered heterocyclic group {the phenyl group, and the six membered heterocyclic group each independently may optionally have one or more substituents selected from Group D}, a hydrogen atom, or a S(O)₂R²³, R²³ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a phenyl group optionally having one or more substituents selected from Group D, R^(11a) and R^(12a) combine together with the nitrogen atom to which they are attached to form a three to seven membered nonaromatic heterocyclic group optionally having one or more substituents selected from group E, R¹³ represents a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally having one or more halogen atoms, a phenyl group optionally having one or more substituents selected from Group D, or a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group D, R¹⁴ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally having one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may optionally have one or more substituents selected from Group D}, R¹⁵ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a hydrogen atom, R¹⁶ represent a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally having one or more substituents selected from Group J, S(O)₂R²³ or a hydrogen atom, x is 0 or 1, Group B: a group consisting of a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom, Group D: a group consisting of a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, an amino group NR⁹R¹⁰, C(O)R¹⁰, OC(O)R⁹, C(O)OR⁹, a cyano group, a nitro group, and a halogen atom, R⁹ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a C3-C6 cycloalkyl group optionally having one or more halogen atoms, R¹⁰ represents a C1-C6 alkyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, or a hydrogen atom, Group E: a group consisting of a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3- C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group; Group F: a group consisting of a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a phenyl group or a six membered aromatic heterocyclic group {the phenyl group and the six membered aromatic heterocyclic group each independently may optionally have one or more substituents selected from Group D}, OR¹⁰, an amino group, NR⁹R¹⁰, a halogen atom, a nitro group, and a cyano group; Group H: a group consisting of a five or six membered aromatic heterocyclic group, a C1-C6 alkyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, OR¹⁰, an amino group NR⁹R¹⁰, C(O)R¹⁰, C(O)NR⁹R¹⁰, OC(O)R⁹, OC(O)0R⁹, NR¹⁰C(O)R⁹, NR¹⁰C(O)OR⁹, C(O)OR¹⁰, a halogen atom, a nitro group, and a cyano group; Group J: a group consisting of a C1-C6 alkyl group optionally having one or more halogen atoms, a halogen atom, a cyano group, a triazolyl group, and NR¹⁰C(O)R⁹.
 2. The compound according to claim 1 wherein T represents a C1-C10 chain hydrocarbon group having one or more halogen atoms, a (C1-C5 alkoxy)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group having one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C3 alkyl group having one or more substituents selected from Group G, a C3-C7 cycloalkyl group having one or more substituents selected from Group G, S(O)R¹, S(O)_(v)R¹, OS(O)₂R¹, CH₂OR¹, NR¹R²⁹, C(O)R¹, C(O)NR¹R²⁹, NR²⁹C(O)R¹, N═CR¹R³⁰, a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, a group represented by formula T-8, a group represented by formula T-9, a group represented by formula T-10, a group represented by formula T-11, or a group represented by formula T-12, and R¹ represents a C1-C 10 chain hydrocarbon group having one or more halogen atoms, a (C1-C5 alkoxy)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5alkylsulfanyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-05 alkylsulfonyl)C2-C5 alkyl group having one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C3 alkyl group having one or more substituents selected from Group G, or a C3-C7 cycloalkyl group having one or more substituents selected from Group G.
 3. The compound according to claim wherein A¹ represents CH.
 4. The compound according to claim wherein A¹ represents a nitrogen atom.
 5. The compound according to claim 1 wherein Het represents Het
 1. 6. The compound according to claim 1 wherein Het represents Het
 2. 7. The compound according to claim 1 wherein Het represents Het 1, A² represents CR^(4a), and A³ represents CR^(4b).
 8. The compound according to claim l wherein Het represents Het 2, A² represents CR^(4a), and A⁴ represents CR^(4c).
 9. The compound according to claim l wherein Q¹ represents an oxygen atom, T represents a C1-C10 chain hydrocarbon group having one or more halogen atoms, OR¹, S(O)_(v)R¹, OS(O)₂R¹, NR¹R²⁹, a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, or a group represented by formula T-8.
 10. The compound according to claim 1 wherein Q₁ represents an oxygen atom, T represents a C1-C5 chain hydrocarbon group having one or more halogen atoms, OR¹, S(O)_(v)R¹, OS(O)₂R¹, NR¹R²⁹, a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, or a group represented by formula T-8, R¹, R^(1x) and R^(1y) are identical to or different from each other and each represents independently a C1-C5 chain hydrocarbon group having one or more halogen atoms, and q is 0 or
 1. 11. The compound according to claim 1 wherein Q₁ represents an oxygen atom, T represents a C1-C5 chain hydrocarbon group having one or more halogen atoms, or OR¹, R¹ represents a C1-C5 chain hydrocarbon group having one or more halogen atoms, and q is 0 or
 1. 12. The compound according to claim 1 wherein R³ represents a C1-C6 alkyl group optionally having one or more substituents selected from Group B, a C3-C7 cycloalkyl group optionally having one or more substituents selected from Group E, a phenyl group, a five aromatic heterocyclic group containing one to four nitrogen atoms, a six aromatic heterocyclic group {the phenyl group, the five aromatic heterocyclic group containing one to four nitrogen atoms, and the six aromatic heterocyclic group each independently may optionally have one or more substituents selected from Group J}, NR¹¹R¹², NR¹¹C(O)OR¹⁴, OR¹², or a halogen atom.
 13. The compound according to claim 1 wherein R² represents an ethyl group.
 14. The compound according to claim 1 wherein Q² represents an oxygen atom.
 15. A composition for controlling harmful arthropod comprising the compound according to claim 1 and an inert carrier.
 16. A method for controlling harmful arthropod which comprises applying an effective amount of the compound according to claim 1 to a harmful arthropod or a habitat where a harmful arthropod lives.
 17. A method for controlling harmful arthropod which comprises applying an effective amount of the compound according to claim l to a plant or a soil where a plant grows.
 18. A method for controlling harmful arthropod which comprises applying an effective amount of the compound according to claim 1 to a seed or a bulb.
 19. A composition comprising one or more ingredients selected from the group consisting of the following Group (a), Group (b), Group (c), Group (d) and Group (e), and the compound according to claim 1, Group (a): one or more ingredients selected from the group consisting of insecticidal ingredients, miticidal ingredients, and nematicidal ingredients; Group (b): fungicidal ingredients; Group (c): plant growth modulating ingredients; Group (d): phytotoxicity-reducing ingredients; and Group (e): synergist ingredients.
 20. A composition for controlling pest comprising the composition according to claim 19 and an inert carrier.
 21. A method for controlling pest which comprises applying an effective amount of the composition according to claim 19 to a pest or a habitat where a pest lives.
 22. A method for controlling pest which comprises applying an effective amount of the composition according to claim 19 to a plant or a soil where a plant grows.
 23. A method for controlling pest which comprises applying an effective amount of the compound according to claim 19 to a seed or a bulb.
 24. A seed or bulb carrying an effective amount of the compound according to claim
 1. 25. A compound represented by formula (II):

[wherein, R² represents a C1-C6 alkyl group optionally having one or more halogen atoms, a cyclopropyl group or a cyclopropylmethyl group, n is 0, 1 or 2, A² represents a nitrogen atom or CR^(4a), a combination of A³ and A⁴ represents a combination where A³ represents a nitrogen atom, A⁴ represents a nitrogen atom or CR', or a combination where A³ represents CR^(4b), and A⁴ represents a nitrogen atom, R^(4a), R^(4b) and R^(4c) are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a nitro group, OR¹⁸, NR¹⁸R¹⁹, a cyano group, an amino group, a halogen atom, or a hydrogen atom, R¹⁹ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a hydrogen atom, R^(w) represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a benzyl group optionally having one or more substituents selected from Group A, a C2-C7 alkylcarbonyl group, a (C1-C3 alkoxy)methyl group, or a hydrogen atom, T^(w) represents a C 1-C 10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C1-C5 alkylsulfanyl)C2-C5 alkyl group, the (C1-C5 alkylsulfinyl)C2-C5 alkyl group, and the (C1-C5 alkylsulfonyl)C2-C5 alkyl group each independently have one or more substituents selected from the group consisting of a cyano group and a halogen atom}, a (C3-C7 cycloalkyl)C1-C3 alkyl group or a C3-C7 cycloalkyl group {the (C3-C7 cycloalkyl)C1-C3 alkyl group and the C3-C7 cycloalkyl group each independently have one or more substituents selected from the group consisting of a cyano group, a halogen atom and a C1-C6 haloalkyl group}, OR¹, S(O)_(v)R¹, OS(O)₂R¹, CH₂OR¹, NR¹R²⁹, C(O)R¹, C(O)NR¹R²⁹, NR²⁹C(O)R¹, N═CR¹R³⁰, a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, a group represented by formula T-8, a group represented by formula T-9, a group represented by formula T-10, a group represented by formula T-11, or a group represented by formula T-12, a halogen atom, a C1-C6 alkylsulfanyl group, a C1-C6 alkylsulfinyl group, a C1-C6 alkylsulfonyl group {the C1-C6 alkylsulfanyl group, the C1-C6 alkylsulfinyl group, and the C1-C6 alkylsulfonyl group each may optionally have a C3-C6 cycloalkyl group}, a C3-C6 cycloalkylsulfanyl group, a C3-C6 cycloalkylsulfinyl group, a C3-C6 cycloalkylsulfonyl group, a benzyloxy group optionally having one or more substituents selected from Group A, a C2-C7 alkylcarbonyloxy group optionally having one or more halogen atoms, a (C1-C3 alkoxy)methoxy group, or a hydroxy group,

X¹ represents a nitrogen atom or CR^(1a), X² represents a nitrogen atom or CR^(1b), X³ represents a nitrogen atom or CR^(1c), X⁴ represents a nitrogen atom or CR^(1d), X⁵ represents a nitrogen atom or CR^(1e), R^(1x) represents a C1-C5 chain hydrocarbon group having one or more halogen atoms, OR⁷, OS(O)₂R⁷, S(O)_(m)R⁷, NR⁸S(O)₂R⁷ , or a halogen atom, R^(1a), R^(1b), R^(1c), R^(1d), and R^(1e) are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a halogen atom, or a hydrogen atom, Y¹ represents NR²⁵, an oxygen atom or a sulfur atom, Y² represents a nitrogen atom or CR²⁶, Y³ represents a nitrogen atom or CR²⁷, Y⁴ represents a nitrogen atom or CR²⁸, R²⁵, R²⁶, R²⁷ and R²⁸ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a halogen atom or a hydrogen atom, R^(1y) represents a C1-C5 chain hydrocarbon group having one or more halogen atoms, OR⁷, OS(O)₂R⁷, S(O)_(m)R⁷, NR⁸S(O)₂R⁷, a cyano group, or a halogen atom, R^(1ay) and R⁷ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group having one or more halogen atoms, m and v are identical to or different from each other and each is 0, 1 or 2, R¹ represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group {the C1-C10 chain hydrocarbon group, the (C1-5 alkoxy)C2-C5 alkyl group, the (C1-C5 alkylsulfanyl)C2-C5 alkyl group, the (C1-05 alkylsulfinyl)C2-C5 alkyl group, and the (C1-C5 alkylsulfonyl)C2-C5 alkyl group each independently have one or more substituents selected from the group consisting of a cyano group and a halogen atom}, a (C3-C7 cycloalkyl)C1-C3 alkyl group, or a C3-C7 cycloalkyl group {the (C3-C7 cycloalkyl)C1- C3 alkyl group and the C3-C7 cycloalkyl group each independently have one or more substituents selected from the group consisting of a cyano group, a halogen atom and a C1-C6 haloalkyl group}, R³⁰ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a halogen atom, OR³⁵, NR³⁶R³⁷, or a hydrogen atom, R¹⁸ and R³⁵ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, R⁸, R²⁹, R³⁶, and R³⁷ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a hydrogen atom, Group A: a group consisting of a C1-C6 alkyl group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, a halogen atom, a cyano group and a nitro group.]
 26. A compound represented by formula (III):

[wherein, R² represents a C1-C6 alkyl group optionally having one or more halogen atoms, a cyclopropyl group or a cyclopropylmethyl group, n is 0, 1 or 2, A¹ represents a nitrogen atom or CR⁶, A² represents a nitrogen atom or CR^(4a), a combination of A³ and A⁴ represents a combination where A³ represents a nitrogen atom, A⁴ represents a nitrogen atom or CR^(4c), or a combination where A³ represents CR^(4b), and A⁴ represents a nitrogen atom, R4a, R^(4b) and R^(4c) are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a nitro group, OR¹⁸, NR¹⁸R¹⁹, a cyano group, an amino group, a halogen atom, or a hydrogen atom, R⁶ represents a hydrogen atom or a halogen atom, R^(w) represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a benzyl group optionally having one or more substituents selected from Group A, a C2-C7 alkylcarbonyl group, a (C1-C3 alkoxy)methyl group, or a hydrogen atom, T^(W2) represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C1-C5 alkylsulfanyl)C2-C5 alkyl group, the (C1-C5 alkylsulfinyl)C2-C5 alkyl group, and the (C1-C5 alkylsulfonyl)C2-C5 alkyl group each independently have one or more substituents selected from the group consisting of a cyano group and a halogen atom}, a (C3-C7 cycloalkyl)C1-C3 alkyl group or a C3-C7 cycloalkyl group {the (C3-C7 cycloalkyl)C1-C3 alkyl group and the C3-C7 cycloalkyl group each independently have one or more substituents selected from the group consisting of a cyano group, a halogen atom and a C1-C6 haloalkyl group}, OR¹, S(O)_(v)R¹, OS(O)₂R¹, CH₂OR¹, NR¹R²⁹, C(O)R¹ , C(O)NR¹R²⁹, NR²⁹C(O)R¹, N═CR¹R³⁰, a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, a group represented by formula T-8, a group represented by formula T-9, a group represented by formula T-10, a group represented by formula T-11, or a group represented by formula T-12, a halogen atom, a C1-C6 alkoxy group, a C1-C6 alkylsulfanyl group, a C1-C6 alkylsulfinyl group, a C1-C6 alkylsulfonyl group {the C1-C6 alkylsulfanyl group, the C1-C6 alkylsulfinyl group, and the C1-C6 alkylsulfonyl group each independently may optionally have a C3-C6 cycloalkyl group}, a C3-C6 cycloalkylsulfanyl group, a C3-C6 cycloalkylsulfinyl group, a C3-C6 cycloalkylsulfonyl group, a benzyloxy group optionally having one or more substituents selected from Group A, a C2-C7 alkylcarbonyloxy group optionally having one or more halogen atoms, a (C1-C3 alkoxy)methoxy group, or a hydroxy group,

X¹ represents a nitrogen atom or CR^(1a), X² represents a nitrogen atom or CR^(1b), X³ represents a nitrogen atom or CR^(1c), X⁴ represents a nitrogen atom or CR^(1d), X⁵ represents a nitrogen atom or CR^(1e), R^(1x) represents a C1-C5 chain hydrocarbon group having one or more halogen atoms, OR⁷, OS(O)₂R⁷, S(O)_(m)R⁷, NR⁸S(O)₂R⁷, or a halogen atom, R^(1a), R^(1b), R^(1c), R^(1d), and R^(1e) are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a halogen atom, or a hydrogen atom, Y¹ represents NR²⁵, an oxygen atom or a sulfur atom, Y² represents a nitrogen atom or CR²⁶, Y³ represents a nitrogen atom or CR²⁷, Y⁴ represents a nitrogen atom or CR²⁸, R²⁵, R²⁶, R²⁷ and R²⁸ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a halogen atom or a hydrogen atom, R^(1y) represents a C1-C5 chain hydrocarbon group having one or more halogen atoms, OR⁷, OS(O)₂R⁷, S(O)_(m)R⁷, NR⁸S(O)₂R⁷, a cyano group, or a halogen atom, R^(1ay) and R⁷ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group having one or more halogen atoms, m and v are identical to or different from each other and each is 0, 1 or 2, R¹represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group {the C1-C10 chain hydrocarbon group, the (C1-05 alkoxy)C2-C5 alkyl group, the (C1-C5 alkylsulfanyl)C2-C5 alkyl group, the (C1-C5 alkylsulfinyl)C2-C5 alkyl group, and the (C1-C5 alkylsulfonyl)C2-C5 alkyl group each independently have one or more substituents selected from the group consisting of a cyano group and a halogen atom}, a (C3-C7 cycloalkyl)C1-C3 alkyl group, or a C3-C7 cycloalkyl group {the (C3-C7 cycloalkyl)C1- C3 alkyl group and the C3-C7 cycloalkyl group each independently have one or more substituents selected from the group consisting of a cyano group, a halogen atom and a C1-C6 haloalkyl group}, R³⁰ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a halogen atom, OR³⁵, NR³⁶R³⁷, or a hydrogen atom, R¹⁸ and R³⁵ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, R³ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group B, a C3-C7 cycloalkyl group optionally having one or more substituents selected from group E, a C3-C7 cycloalkenyl group optionally having one or more substituents selected from Group J, a phenyl group optionally having one or more substituents selected from Group H, a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group H, OR¹², NR¹¹R¹², NR^(11a)R12a, NR²⁴NR¹¹R¹², NR²⁴ 0R¹¹, NR¹¹C(O)R¹³, NR²⁴NR¹¹C(O)R¹³, NR¹¹C(O)OR¹⁴, NR²⁴NR¹¹C(O)OR¹⁴, NR¹¹C(O)NR¹⁵R¹⁶, NR²⁴NR¹¹C(O)NR¹⁵R¹⁶, N═CHNR¹⁵R¹⁶, N═S(O)_(x)R¹⁵R¹⁶, C(O)R¹⁷, C(O)OR¹⁷, C(O)NR¹⁵R¹⁶, CR²⁴═NOR¹⁷, NR¹¹CR²⁴═NOR¹⁷, a cyano group, a nitro group, or a halogen atom, q is 0, 1, 2 or 3, and when q is 2 or 3, a plurality of R³ may be identical to or different from each other, When two R³ are adjacent to each other, said two R³ may combined together with a carbon atom to which they are attached to form benzene ring, pyrrole ring, furan ring, thiophene ring, pyrazole ring, imidazole ring, triazole ring, oxazole ring, isoxazole ring, thiazole ring, oxadiazole ring, thiadiazole ring, pyridine ring, pyridazine ring, pyrimidine ring, or pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the triazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring, and the pyrazine ring each independently may optionally have one or more substituents selected from Group H}, R¹⁷ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a phenyl group optionally having one or more substituents selected from Group D, or a hydrogen atom, R⁸, R¹¹, R¹⁹, R²⁴, R²⁹, R³⁶,and R³⁷ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a hydrogen atom, R¹² represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally having one or more substituents selected from Group J, a C3-C7 cycloalkenyl group optionally having one or more substituents selected from Group J, a phenyl group, a six membered heterocyclic group {the phenyl group, and the six membered heterocyclic group each independently may optionally have one or more substituents selected from Group D}, a hydrogen atom, or a S(O)₂R²³, R²³ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a phenyl group optionally having one or more substituents selected from Group D, R^(11a) and R^(12a) combine together with the nitrogen atom to which they are attached to form a three to seven membered nonaromatic heterocyclic group optionally having one or more substituents selected from group E, R¹³ represents a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally having one or more halogen atoms, a phenyl group optionally having one or more substituents selected from Group D, or a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group D, R¹⁴ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally having one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may optionally have one or more substituents selected from Group D}, R¹⁵ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a hydrogen atom, R¹⁶ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally having one or more substituents selected from Group J, S(O)₂R²³ or a hydrogen atom, x is 0 or 1, Group A: a group consisting of a C1-C6 alkyl group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, a halogen atom, a cyano group and a nitro group, Group B: a group consisting of a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom, Group D: a group consisting of a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, an amino group, NR⁹R¹⁰, C(O)R¹⁰, OC(O)R⁹, C(O)OR⁹, a cyano group, a nitro group, and a halogen atom, R⁹ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a C3-C6 cycloalkyl group optionally having one or more halogen atoms, R¹⁰ represents a C1-C6 alkyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, or a hydrogen atom, Group E: a group consisting of a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3- C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group; Group F: a group consisting of a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a phenyl group or a six membered aromatic heterocyclic group {the phenyl group and the six membered aromatic heterocyclic group each independently may optionally have one or more substituents selected from Group D}, R¹⁰, an amino group, NR⁹R¹⁰, a halogen atom, a nitro group, and a cyano group; Group H: a group consisting of a five or six membered aromatic heterocyclic group, a C1-C6 alkyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, OR¹⁰, an amino group NR⁹R¹⁰, C(O)R¹⁰, C(O)NR⁹R¹⁰, OC(O)R⁹, OC(O)OR⁹, NR¹⁰C(O)R⁹, NR¹⁰C(O)OR⁹, C(O)OR¹⁰, a halogen atom, a nitro group, and a cyano group. Group J: a group consisting of a C1-C6 alkyl group optionally having one or more halogen atoms, a halogen atom, a cyano group, a triazolyl group, and NR¹⁰C(O)R⁹.
 27. A compound represented by formula (IV):

[wherein, R² represents a C1-C6 alkyl group optionally having one or more halogen atoms, a cyclopropyl group or a cyclopropylmethyl group, n is 0, 1 or 2, R³ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group B, a C3-C7 cycloalkyl group optionally having one or more substituents selected from group E, a C3-C7 cycloalkenyl group optionally having one or more substituents selected from Group J, a phenyl group optionally having one or more substituents selected from Group H, a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group H, OR¹², NR¹¹R¹², NR^(11a)R^(12a), NR²⁴NR¹¹R¹², NR²⁴OR¹¹, NR¹¹C(O)R¹³, NR²⁴NR¹¹C(O)R¹³, NR¹¹C(O)OR¹⁴, NR²⁴NR¹¹C(O)OR¹⁴, NR¹¹C(O)NR¹⁵R¹⁶, NR²⁴NR¹¹C(O)NR¹⁵R¹⁶, N═CHNR¹⁵R¹⁶, N═S(O)_(x)R¹⁵R¹⁶, C(O)R¹⁷, C(O)OR¹⁷, C(O)NR¹⁵R¹⁶, CR^(24═)NOR¹⁷, NR^(ll)CR²⁴NOR¹⁷, a cyano group, a nitro group, or a halogen atom, q is 0, 1, 2 or 3, and when q is 2 or 3, a plurality of R³ may be identical to or different from each other, When two R³ are adjacent to each other, said two R³ may combined together with a carbon atom to which they are attached to form benzene ring, pyrrole ring, furan ring, thiophene ring, pyrazole ring, imidazole ring, triazole ring, oxazole ring, isoxazole ring, thiazole ring, oxadiazole ring, thiadiazole ring, pyridine ring, pyridazine ring, pyrimidine ring, or pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the triazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring, and the pyrazine ring each independently may optionally have one or more substituents selected from Group H}, Het^(W) represents a group represented by the following formula Het 3 or a group represented by the following formula Het 4:

A¹ represents a nitrogen atom or CR⁶, A² represents a nitrogen atom or CR^(4a), A³ represents a nitrogen atom or CR^(4b), A⁴ represents a nitrogen atom or CR^(4c), Q¹ represents an oxygen atom or a sulfur atom, R²⁰ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a hydrogen atom, R⁵ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from group F, a C3-C6 cycloalkyl group optionally having one or more substituents selected from Group J, a phenyl group optionally having one or more substituents selected from Group H, or a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group H, R4a, R^(4b) and R^(4c) are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally one or more halogen atoms, a nitro group, OR¹⁸, NR¹⁸R¹⁹, a cyano group, an amino group, a halogen atom, or a hydrogen atom, R⁶ represents a hydrogen atom or a halogen atom, X^(L) represents a halogen atom, a C1-C6 alkoxy group, a C1-C6 alkylsulfanyl group, a C1-C6 alkylsulfinyl group, a C1-C6 alkylsulfonyl group {the C1-C6 alkylsulfanyl group, the C1-C6 alkylsulfinyl group, and the C1-C6 alkylsulfonyl group each independently may optionally have a C3-C6 cycloalkyl group}, a C3-C6 cycloalkylsulfanyl group, a C3-C6 cycloalkylsulfinyl group, a C3-C6 cycloalkylsulfonyl group, a benzyloxy group optionally having one or more substituents selected from Group A, a C2-C7 alkylcarbonyloxy group optionally having one or more halogen atoms, a (C1-C3 alkoxy)methoxy group, or a hydroxy group, R¹⁸ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, R¹⁷ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a phenyl group optionally having one or more substituents selected from Group D, or a hydrogen atom, R¹¹, R¹⁹ and R²⁴ are identical to or different from each other and each represents independently a C1-C6 chain hydrocarbon group optionally one or more halogen atoms, or a hydrogen atom, R¹² represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally having one or more substituents selected from Group J, a C3-C7 cycloalkenyl group optionally having one or more substituents selected from Group J, a phenyl group, or six membered heterocyclic group {the phenylgroup, and the six membered heterocyclic group each independently may have optionally one or more substituents selected from Group D}, a hydrogen atom, or S(O)₂R²³, R²³ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a phenyl group optionally having one or more substituents selected from Group D, R^(11a) and R^(12a) combine together with the nitrogen atom to which they are attached to form a three to seven membered nonaromatic heterocyclic group optionally having one or more substituents selected from group E, R¹³ represents a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally having one or more halogen atoms, a phenyl group optionally having one or more substituents selected from Group D, or a five or six membered aromatic heterocyclic group optionally having one or more substituents selected from Group D, R¹⁴ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally having one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may optionally have one or more substituents selected from Group D}, R¹⁵ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a hydrogen atom, R¹⁶ represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally having one or more substituents selected from Group J, S(O)₂R²³ or a hydrogen atom, x is 0 or 1, Group A: a group consisting of a C1-C6 alkyl group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, a halogen atom, a cyano group and a nitro group, Group B: a group consisting of a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom, Group D: a group consisting of a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, an amino group, NR⁹R¹⁰, C(O)R¹⁰, OC(O)R⁹, C(O)OR⁹, a cyano group, a nitro group, and a halogen atom, R⁹ represents a C1-C6 alkyl group optionally having one or more halogen atoms, or a C3-C6 cycloalkyl group optionally having one or more halogen atoms, R¹⁰ represents a C1-C6 alkyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, or a hydrogen atom, Group E: a group consisting of a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3- C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group; Group F: a group consisting of a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a phenyl group or a six membered aromatic heterocyclic group {the phenyl group and the six membered aromatic heterocyclic group each independently may optionally have one or more substituents selected from Group D}, OR¹⁰, an amino group, NR⁹R¹⁰, a halogen atom, a nitro group, and a cyano group; Group H: a group consisting of a five or six membered aromatic heterocyclic group, a C1-C6 alkyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, OR¹⁰, an amino group NR⁹R¹⁰, C(O)R¹⁰, C(O)NR⁹R¹⁰, OC(O)R⁹, OC(O)OR⁹, NR¹⁰C(O)OR⁹, NR¹⁰C(O)OR⁹, C(O)OR¹⁰, a halogen atom, a nitro group, and a cyano group. Group J: a group consisting of a C1-C6 alkyl group optionally having one or more halogen atoms, a halogen atom, a cyano group, a triazolyl group, and NR¹⁰C(O)R⁹]. 